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2-METHYLDIPHENYLAMINE

Product Name
2-METHYLDIPHENYLAMINE
CAS No.
1205-39-6
Chemical Name
2-METHYLDIPHENYLAMINE
Synonyms
Phenyl o-tolylamine;2-METHYLDIPHENYLAMINE;2-Methyl-N-phenylephrine;N-Phenyl-2-methylaniline;2-Methyl-N-phenylaniline;2-Methyl-N-phenylbenzenamine;N-(2-Methylphenyl)benzenamine;Benzenamine, 2-methyl-N-phenyl-
CBNumber
CB3143689
Molecular Formula
C13H13N
Formula Weight
183.25
MOL File
1205-39-6.mol
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2-METHYLDIPHENYLAMINE Property

Melting point:
130-140 °C
Boiling point:
305 °C(Press: 727 Torr)
Density 
1.066±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
0.65±0.20(Predicted)
Appearance
Yellow to brown Solid
InChI
InChI=1S/C13H13N/c1-11-7-5-6-10-13(11)14-12-8-3-2-4-9-12/h2-10,14H,1H3
InChIKey
JTMODJXOTWYBOZ-UHFFFAOYSA-N
SMILES
C1(NC2=CC=CC=C2)=CC=CC=C1C
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Safety

HS Code 
2921440020
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M3718
Product name
2-Methyl-N-phenylaniline
Purity
min. 98.0 %
Packaging
200MG
Price
$117
Updated
2025/07/31
TCI Chemical
Product number
M3718
Product name
2-Methyl-N-phenylaniline
Purity
min. 98.0 %
Packaging
1G
Price
$351
Updated
2025/07/31
AK Scientific
Product number
2698CS
Product name
2-Methyl-N-phenylaniline
Packaging
5g
Price
$385
Updated
2021/12/16
Apolloscientific
Product number
OR54435
Product name
2-Methyl-N-phenylaniline
Packaging
1g
Price
$163
Updated
2021/12/16
SynQuest Laboratories
Product number
3731-1-17
Product name
2-Methyl-N-phenylaniline
Purity
98%
Packaging
1g
Price
$192
Updated
2021/12/16
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2-METHYLDIPHENYLAMINE Chemical Properties,Usage,Production

Synthesis

16419-60-6

62-53-3

1205-39-6

GENERAL STEPS: In a typical experiment, 2-methylphenylboronic acid (1.22 g, 10 mmol) was added to a flask containing K2CO3 (2.76 g, 20 mmol) and water (2 mL) as solvent. Aniline (0.93 g, 10 mmol) and Cu-Mn catalyst were subsequently added and the reaction mixture was stirred at room temperature. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the base in the reaction mixture was neutralized with 2N HCl solution and the catalyst was removed by filtration. The filtrate was washed thoroughly with water and then extracted with ethyl acetate. The organic layer was separated and concentrated and dried under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: ethyl acetate/petroleum ether, ratio 1:5) to give white crystalline 2-methyldiphenylamine (1.60 g, 95% yield). All reactions were carried out in a similar manner.

References

[1] Tetrahedron Letters, 2013, vol. 54, # 39, p. 5351 - 5354
[2] RSC Advances, 2014, vol. 4, # 90, p. 49273 - 49279
[3] Bulletin of the Korean Chemical Society, 2012, vol. 33, # 5, p. 1785 - 1787
[4] Journal of Organic Chemistry, 2006, vol. 71, # 25, p. 9522 - 9524
[5] Tetrahedron Letters, 2014, vol. 55, # 17, p. 2813 - 2817

2-METHYLDIPHENYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHYLDIPHENYLAMINE Suppliers

China 59 India 1 United Kingdom 1 United States 4 Global 65
Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Synthonix Inc
Tel
--
Fax
--
Email
info@synthonix.com
Country
United States
ProdList
6872
Advantage
58
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Carbocore, Inc.
Tel
--
Fax
--
Email
sales@carbocore.com
Country
United States
ProdList
1436
Advantage
60
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View Lastest Price from 2-METHYLDIPHENYLAMINE manufacturers

Honest Joy Holdings Limited
Product
2-Methyl-N-phenylaniline 1205-39-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
100 tons
Release date
2022-01-17

1205-39-6, 2-METHYLDIPHENYLAMINERelated Search:

N-(2-AMINO-4-CHLOROPHENYL)ANTHRANILIC ACID Flufenamic acid 10-METHYL-9(10H)-ACRIDONE REACTIVE BLUE 4 REACTIVE BLACK 5 ACID BLUE 41 9(10H)-ACRIDONE ACID GREEN 27 (C.I. 61580) Carbamazepine Solvent Green 3 ACID VIOLET 34 ACID BLUE 40 Iminodibenzyl ACID BLUE 80 ACID BLUE 25 10,11-DIHYDROCARBAMAZEPINE Acid Green 25 N-Phenylanthranilic acid

  • 2-Methyl-N-phenylaniline
  • 2-Methyl-N-phenylbenzenamine
  • N-(2-Methylphenyl)benzenamine
  • N-Phenyl-2-methylaniline
  • Phenyl o-tolylamine
  • 2-METHYLDIPHENYLAMINE
  • Benzenamine, 2-methyl-N-phenyl-
  • 2-Methyl-N-phenylephrine
  • 1205-39-6