4-FLUOROPHENYLMAGNESIUM BROMIDE

Product Name: 4-FLUOROPHENYLMAGNESIUM BROMIDE
CAS No.: 352-13-6
Chemical Name: 4-FLUOROPHENYLMAGNESIUM BROMIDE
Synonyms: 4-FL;uorophenyL;4-FluorophenylMagnes;4-FLUOROPHENYLMAGNESIUM BROMIDE;4-flourophenylmagnesium bromide;magnesium,fluorobenzene,bromide;p-Fluoro-phenylmagnesium bromide;Magnesium 4-fluorophenyl bromide;Magnesium, bromo(4-fluorophenyl)-;4-fluorophenylmagnesiumbromidesol.
CBNumber: CB3166792
Molecular Formula: C6H4BrFMg
Formula Weight: 199.3
MOL File: 352-13-6.mol

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4-FLUOROPHENYLMAGNESIUM BROMIDE Property

Melting point:: 5 °C
Boiling point:: 66°C
Density: 1.043 g/mL at 25 °C
Flash point:: −40 °F
storage temp.: Flammables + water-Freezer (-20°C)e area
form: Solution
color: Clear yellow to red-brown
Water Solubility: It reacts violently with water.
Sensitive: Air & Moisture Sensitive
BRN: 636802
InChI: InChI=1S/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1
InChIKey: QYBFFRXNNFXREA-UHFFFAOYSA-M
SMILES: [Mg](C1=CC=C(F)C=C1)Br
CAS DataBase Reference: 352-13-6
EPA Substance Registry System: Magnesium, bromo(4-fluorophenyl)- (352-13-6)

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Safety

Hazard Codes: F+,C,F
Risk Statements: 12-14-22-34-66-67-11-40-37-19
Safety Statements: 16-26-36/37/39-43-45-7/8-33-8-7
RIDADR: UN 2924 3/PG 2
WGK Germany: 1
F: 10-21
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 328820
Product name: 4-Fluorophenylmagnesium bromide solution
Purity: 1.0?M in THF
Packaging: 4X25ML
Price: $103
Updated: 2025/07/31

Sigma-Aldrich

Product number: 245550
Product name: 4-Fluorophenylmagnesium bromide solution
Purity: 2.0M in diethyl ether
Packaging: 100ml
Price: $100
Updated: 2025/07/31

Sigma-Aldrich

Product number: 245550
Product name: 4-Fluorophenylmagnesium bromide solution
Purity: 2.0M in diethyl ether
Packaging: 800ml
Price: $356
Updated: 2025/07/31

TCI Chemical

Product number: F0673
Product name: 4-Fluorophenylmagnesium Bromide (ca. 19% in Tetrahydrofuran, ca. 1.0mol/L)
Packaging: 250g
Price: $103
Updated: 2025/07/31

Sigma-Aldrich

Product number: 328820
Product name: 4-Fluorophenylmagnesium bromide solution
Purity: 1.0 M in THF
Packaging: 100ml
Price: $70.3
Updated: 2025/07/31

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4-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties,Usage,Production

Chemical Properties

clear yellow to red-brown solution

Uses

4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group.

Uses

4-Fluorophenylmagnesium bromide solution (Grignard reagent) can be used as a reagent in the synthesis of:

Useful key intermediate in the synthesis of paroxetine.
Arylsulfides via cross-coupling reaction with thiols.
4-Arylmethyl-1-phenylpyrazole and 4-aryloxy-1-phenylpyrazole derivatives as androgen receptor antagonists.
Grignard intermediate for preparing aprepitant.

reaction suitability

reaction type: Grignard Reaction

4-FLUOROPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-FLUOROPHENYLMAGNESIUM BROMIDE Suppliers

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View Lastest Price from 4-FLUOROPHENYLMAGNESIUM BROMIDE manufacturers

Career Henan Chemical Co

Product: 4-Fluorophenylmagnesium bromide 352-13-6
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-25

352-13-6, 4-FLUOROPHENYLMAGNESIUM BROMIDERelated Search:

O-TOLYLMAGNESIUM BROMIDE 3-FLUOROPHENYLMAGNESIUM BROMIDE,3-FLUOROPHENYLMAGNESIUM BROMIDE, 0.5M SOLU TION IN TETRAHYDROFURAN,3-FLUOROPHENYLMAGNESIUM BROMIDE, 1.0M SO Butylmagnesium chloride ISOBUTYLMAGNESIUM BROMIDE 4-CHLOROPHENYLMAGNESIUM BROMIDE CYCLOHEXYLMAGNESIUM CHLORIDE TERT-BUTYLMAGNESIUM CHLORIDE Benzylmagnesium chloride PROPYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM CHLORIDE 4-PHENOXYPHENYLMAGNESIUM BROMIDE CYCLOPENTYLMAGNESIUM BROMIDE Ethylmagnesium bromide 4-(N,N-DIMETHYL)ANILINEMAGNESIUM BROMIDE 3,4-DIFLUOROPHENYLMAGNESIUM BROMIDE 4-FLUOROPHENYLMAGNESIUM BROMIDE Diethyl ether Phenylmagnesium bromide

4-FLUOROPHENYLMAGNESIUM BROMIDE

4-FLUOROPHENYLMAGNESIUM BROMIDE, 2M IN DIETHYL ETHER

4-FLUOROPHENYLMAGNESIUM BROMIDE, 2.0M SO LUTION IN DIETHYL ETHER

4-FLUOROPHENYLMAGNESIUM BROMIDE SOL., ~2 .0 M IN DIETHYL ET

4-FLUOROPHENYLMAGNESIUM BROMIDE, 1.0M SO LUTION IN TETRAHYDROFURAN

4-FLUOROPHENYLMAGNESIUM BROMIDE SOL., ~1 M IN THF

4-Fluorophenylmagnesium Bromide 1.0 M In Tetrahydrofuran

4-Fluorophenylmagnesium Bromide 2.0 M In Diethyl Ether

4-FluorophenylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal

4-FluorophenylMagnesiuM broMide, 2.0 M solution in diethyl ether, SpcSeal

4-fluorophenylmagnesiumbromidesol.

4-flourophenylmagnesium bromide

4-Fluorophenylmagnesium bromide solution (1.0M THF)

4-fluorine phenyl magnesium bromide 1M solution in tetrahydrofuran

4-Fluorophenylmagnesium bromide, 1.0 M in THF

4-Fluorophenylmagnesium bromide, 1.0 M in 2-MeTHF

4-Fluorophenylmagnesium bromide solution 2.0M in diethyl ether

4-Fluorophenylmagnesium bromide, 2.0 M solution in 2-MeTHF, J&KSeal

4-Fluorophenylmagnesium bromide, 0.8M solution in THF

4-Fluorophenylmagnesium bromide, 2M solution in diethyl ether

Magnesium, bromo(4-fluorophenyl)-

4-fluorophenylmagnesium bromide solution

4-Fluorophenylmagnesium bromide0.8M solution in THFAcroSeal§3

4-Fluorophenylmagnesium bromide2M solution in diethyl etherAcroSeal§3

4-Fluorophenylmagnesium bromide, 1M in MeTHF

4-Fluorophenylmagnesium bromide solution 1.0 in THF

4-Fluorophenylmagnesium bromide solution 2.0 in diethyl ether

4-Fluorophenylmagnesium bromide, 2M solution in diethyl ether, AcroSeal

4-Fluorophenylmagnesium bromide, 0.8M solution in THF, AcroSeal

4-FluorophenylMagnesiuM BroMide (ca. 18% in Tetrahydrofuran, ca. 0.9Mol/L)

(ca. 18% in Tetrahydrofuran, ca. 0.9Mol/L)

4-FluorophenylMagnesiuM BroMide&nbsp

4-FluorophenylMagnes

4-FluorophenylMagnesiuM BroMide (ca. 19% in Tetrahydrofuran, ca. 1.0Mol/L)

4-Fluorophenylmagnesium bromide 1M solution in THF

4-FluorophenylMagnesiuM broMide, 0.8 M solution in THF, J&KSeal

FluorophenylMagnesiuM broMide soluti

4-FluorophenylMagnesiuM broMide solution 1.0 M in THF

4-FluorophenylMagnesiuM broMide, 2.0 M solution in diethyl ether, J&KSeal

4-Fluorophenylmagnesium bromide solution( 1.0 M solution in THF)

4-FL

uorophenyL

p-Fluoro-phenylmagnesium bromide

magnesium,fluorobenzene,bromide

4-Fluorophenyl Magnesium Bromide 1. M in THF

4-FLUORO PHENYL MAGENSIUM BROMIDE IN THF

4-Fluorophenylmagnesium bromide 1.0

(4-fluorobenzenide)magnesium(1+)bromide

Magnesium 4-fluorophenyl bromide

4-Fluorophenylmagnesium bromide, 1.0 M in THF - [F31733]

4-Fluorophenylmagnesium bromide2.0M in diethyl ether/1.0M in THF

352-13-6

C6H4BrFMg

FC6H4MgBr

Grignard Reagents

FA - FL

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Organometallic Reagents