1-NITROHEXANE

Product Name: 1-NITROHEXANE
CAS No.: 646-14-0
Chemical Name: 1-NITROHEXANE
Synonyms: Nitrohexane;1-NITROHEXANE;Hexane, 1-nitro-;1-Nitrohexane 98%;1-NITROHEXANE, STANDARD FOR GC
CBNumber: CB3181450
Molecular Formula: C6H13NO2
Formula Weight: 131.17
MOL File: 646-14-0.mol

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1-NITROHEXANE Property

Melting point:: 23.5°C (estimate)
Boiling point:: 91-92 °C/24 mmHg (lit.)
Density: 0.94 g/mL at 25 °C (lit.)
refractive index: n20/D 1.423(lit.)
Flash point:: 72 °C
storage temp.: -20°C Freezer
solubility: Dichloromethane, Chloroform, Ethyl Acetate, Methanol
form: Clear Colourless Liquid
pka: 8.65±0.29(Predicted)
BRN: 1749466
Stability:: Stable. Incompatible with strong bases, strong oxidizing agents.
EPA Substance Registry System: 1-Nitrohexane (646-14-0)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: 2810
WGK Germany: 3
F: 8
HazardClass: 6.1(b)
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 259497
Product name: 1-Nitrohexane
Purity: 98%
Packaging: 1g
Price: $72.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 259497
Product name: 1-Nitrohexane
Purity: 98%
Packaging: 5g
Price: $170
Updated: 2024/03/01

TRC

Product number: N496125
Product name: 1-Nitrohexane
Packaging: 500mg
Price: $280
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 12560
Product name: 1-Nitrohexane
Packaging: 5G
Price: $845
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0006915
Product name: 1-NITROHEXANE
Purity: 95.00%
Packaging: 2.5G
Price: $869
Updated: 2021/12/16

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1-NITROHEXANE Chemical Properties,Usage,Production

Chemical Properties

Colourless Liquid

Uses

1-Nitrohexane is used in method for preparing amine by reducing nitro compound with pinacolborane under catalysis of cyclic (alkyl) (amino) carbene chromium complex.

Definition

ChEBI: 1-nitrohexane is a primary nitroalkane that is hexane substituted by a nitro group at position 1. It has a role as a human urinary metabolite. It derives from a hydride of a hexane.

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 659, 1979 DOI: 10.1021/jo01318a050
Synthesis, p. 835, 1978 DOI: 10.1055/s-1978-24907

General Description

Clear colorless liquid. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Nitroalkanes, such as 1-NITROHEXANE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water. Flammable/combustible material. May be ignited by heat, sparks or flames.

Fire Hazard

Flash point data for 1-NITROHEXANE are not available. 1-NITROHEXANE is combustible.

1-NITROHEXANE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-NITROHEXANE Suppliers

Canada 1 China 38 France 1 Germany 1 Switzerland 1 United Kingdom 2 United States 7 Global 51

Riedel-de Haen AG

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Country: United States
ProdList: 6773
Advantage: 87

Medical Isotopes

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Email: stohler@medicalisotopes.com
Country: United States
ProdList: 6181
Advantage: 68

3B Scientific Corporation

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Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

United States Biological

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Email: chemicals@usbio.net
Country: United States
ProdList: 6214
Advantage: 80

HONEST JOY HOLDINGS LIMITED

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Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

City Chemicals Corporation

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Country: United States
ProdList: 6460
Advantage: 72

Pfaltz & Bauer, Inc.

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Email: sales@pfaltzandbauer.com
Country: United States
ProdList: 6828
Advantage: 72

646-14-0, 1-NITROHEXANERelated Search:

1-NITROMETHYLCYCLOHEXANOL 1-NITRO-1-CYCLOHEXENE 1-NITROHEXANE NITROCYCLOHEXANE 2,3,5,6-TETRAHYDROXY-1,4-DINITROCYCLOHEXANE DIHYDRATE 1-DEOXY-1-NITRO-D-SORBITOL 6-NITROCAPROIC ACID 1-NITROHEPTANE 2-NITROCYCLODODECANONE 1-DEOXY-1-NITRO-D-GALACTITOL 1-NITRODODECANE 1-DEOXY-1-NITRO-D-MANNITOL 2-NITROCYCLOHEXANONE 1-nitrooctane 1-DEOXY-1-NITRO-L-MANNITOL 1-DEOXY-1-NITRO-L-GALACTITOL 4-Acetoxy-3-nitrohexane,4-Acetoxy-3-nitrohexane (1R-(1A,2B,3A))-(+)-3-ME-2-(NITROMETHYL)-5-OXOCYCLOPENTANEACETIC ACID, 98

1-NITROHEXANE

1-Nitrohexane 98%

1-NITROHEXANE, STANDARD FOR GC

Nitrohexane

Hexane, 1-nitro-

646-14-0

CH3CH25NO2

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