ChemicalBook > CAS DataBase List > Calcium silicate

Calcium silicate

Product Name
Calcium silicate
CAS No.
1344-95-2
Chemical Name
Calcium silicate
Synonyms
solex;sw400;E 552;calsil;Ecolux;silmost;FM 1000;CALFLO E;floriter;sileneef
CBNumber
CB3189805
Molecular Formula
CaO3Si
Formula Weight
116.16
MOL File
1344-95-2.mol
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Calcium silicate Property

Melting point:
1540℃ [CRC10]
Density 
2.9 g/mL at 25 °C (lit.)
solubility 
Practically insoluble in water; forms a gel with mineral acids. It can absorb up to 2.5 times its weight of liquids and still remain a free-flowing powder.
form 
white monoclinic crystals
Specific Gravity
2.9
color 
white monoclinic crystals, crystalline
Odor
at 100.00?%. odorless
PH
9.5-11.5 (5% in H2O)
Water Solubility 
insoluble H2O [HAW93]
Merck 
13,1707
Stability:
Stable.
LogP
0.651 (est)
CAS DataBase Reference
1344-95-2(CAS DataBase Reference)
EPA Substance Registry System
Calcium silicate (1344-95-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37
Safety Statements 
22-26-37/39
OEB
B
OEL
TWA: 10 mg/m3 (total)
WGK Germany 
3
RTECS 
VV9170000
Hazardous Substances Data
1344-95-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
742503
Product name
Calcium silicate
Purity
purum, 12-22% Ca (as CaO) basis, ≥87% SiO2 basis
Packaging
1kg
Price
$131
Updated
2024/03/01
Sigma-Aldrich
Product number
742503
Product name
Calcium silicate
Purity
purum, 12-22% Ca (as CaO) basis, ≥87% SiO2 basis
Packaging
15kg
Price
$1440
Updated
2024/03/01
Sigma-Aldrich
Product number
742503
Product name
Calcium silicate
Purity
purum, 12-22% Ca (as CaO) basis, ≥87% SiO2 basis
Packaging
500g
Price
$69.2
Updated
2024/03/01
Usbiological
Product number
270471
Product name
Calcium silicate
Packaging
500g
Price
$340
Updated
2021/12/16
AK Scientific
Product number
8206AF
Product name
Calciumsilicate,≥87%SiO2basis,12-22%Ca(asCaO)basis
Packaging
500g
Price
$147
Updated
2021/12/16
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Calcium silicate Chemical Properties,Usage,Production

Description

Calcium Silicate is a hydrous or anhydrous silicate with varying proportions of calcium oxideand silica. many different calcium silicates occur in nature in mineral form (e.g.,wollastonite, afwillite, grammite). The stoichiometry of the hydrate in cement paste is variable and the state of the chemically and physically bound water in its structure is not clear. Thus, calcium silicate can be prepared by calcining the oxide with silica, SiO2, at an elevated temperature: CaO + SiO2+ heat→CaSiO3. Calcium orthosilicate is commonly used as a safe alternative to asbestos for high-temperature insulation materials. Industrial grade piping and equipment insulation are often fabricated from calcium orthosilicate.

Chemical Properties

Calcium silicate occurs as a crystalline or amorphous white or off white material, and often exists in different hydrate forms. It consists of different ratios of CaO and SiO4, including tricalcium silicate (3CaO.SiO2) and dicalcium silicate Ca2SiO4. It is insoluble in water and forms a gel with inorganic acids. The pH of 5% suspension is 8.4~10.2.

Uses

Calcium Silicate is an anticaking agent that exists in different forms, which are insoluble in water. it is used in salt to enhance flowability under extremely high humidity conditions. it is also used in baking powder and fabricated chips to absorb water or other liquids.

Production Methods

Calcium silicate is made in various ways by reacting siliceous material (such as diatomaceous earth) and calcium compounds (such as calcium hydroxide (Ca (OH) 2).The refinement of wollastonite ore into high-grade wollastonite was originally done by manual selection at many mines. This process is now performed by screening and magnetic separators, sometimes in combination with flotation and vacuum filtration. Grinding and milling operations can produce variable mesh powders or aggregates.

Application

The main applications of calcium silicate relate to its anticaking properties, and it has therefore been used in dusting powders and a range of different cosmetic products (e.g. face powders, eye shadow). It is also used as anticaking agent in table salt, foods, pharmaceuticals, and agricultural pesticides; replacement for asbestos in thermal insulation; Constituent (produced in situ) of lime glass, portland cement; reinforcing filler in elastomers and plastics; absorbent for liquids, gases, vapors; as anti-caking agent, suspension agent, pigment and pigment extender; binder for refractory material; in chromatography; in road construction.

Preparation

Calcium silicate is a naturally occurring mineral, but for commercial applications it is usually prepared from lime and diatomaceous earth under carefully controlled conditions.

Hazard

Irritating dust. Use in foods restricted to 5% in baking powder, 2% in table salt. Upper res- piratory tract irritant. Questionable carcinogen.

Health Hazard

The toxicity of calcium silicate depends on particle size, aspect ratio, and amount of silica and respirable fiber.1 Synthetic nonfibrous calcium silicate is considered to be a nuisance dust.
Skin irritation was reported in a worker exposed to an atmosphere permeated with calcium silicate.1 A study of 104 wallastonite (a naturally occurring calcium silicate mineral) miners showed no relationship between the prevalence of chronic bronchitis or airflow obstruction with increasing exposure.1 In a cohort mortality study of wollastonite quarry workers the observed numbers of deaths from all cancers combined and lung cancer were lower than expected.

Flammability and Explosibility

Not classified

Pharmaceutical Applications

Calcium silicate (Ca2SiO4) is used in the pharmaceutical industry as an anticaking agent. Anti-caking agents absorb moisture and allow products to flow freely during the manufacturing process. It is also used as a filler aid for oral pharmaceuticals. It has also been used in pharmaceutical preparations as an antacid.

Industrial uses

Calcium silicate compounds belong to a complicated class of silicates. Among their many industrial applications, calcium silicates are heavily used as a building material as they constitute the main ingredient in today’s cement clinker.

Safety Profile

A nuisance dust

Safety

GRAS listed. Included in the FDA Inactive Ingredients Database (oral dosage forms). Included in nonparenteral (oral, orodispersible, effervescent and enteric-coated tablets) formulations licensed in the UK.
calcium silicate is generally recognized as safe (GRAS) when used at levels not exceed 2% in table salt and 5% in baking powder.

storage

Calcium silicate is chemically stable and nonflammable, but it should be protected from moisture. Store in airtight containers in a cool, dry place.

Incompatibilities

None reported [Note: After prolonged contact with water, solution reverts to soluble calcium salts & amorphous silica.]

Regulatory Status

Calcium silicate (E552) is listed in Commission Regulation (EU) No 231/2012 as an authorised food additive and categorized as “additives other than colours and sweeteners”. It is an approved ingredient in Australia and New Zealand with the code number 552.

Calcium silicate Preparation Products And Raw materials

Raw materials

Preparation Products

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Calcium silicate Suppliers

3B Pharmachem (Wuhan) International Co.,Ltd.
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Sigma-Aldrich
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klamar reagent
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View Lastest Price from Calcium silicate manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
CALCIUM SILICATE 1344-95-2
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-05
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
calcium silicate 1344-95-2
Price
US $40.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-05-23
Hebei Longbang Technology Co., Ltd
Product
CALCIUM SILICATE 1344-95-2
Price
US $5.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-27

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