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Cartap hydrochloride

Product Name
Cartap hydrochloride
CAS No.
15263-52-2
Chemical Name
Cartap hydrochloride
Synonyms
ntd2;patap;Cadan;Carta;Padan;kartap;Cardan;padan4g;Cartapp;vegetox
CBNumber
CB3191392
Molecular Formula
C7H16ClN3O2S2
Formula Weight
273.79
MOL File
15263-52-2.mol
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Cartap hydrochloride Property

Density 
1.4008 (rough estimate)
vapor pressure 
Negligible
refractive index 
1.6100 (estimate)
solubility 
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
pka
7.61 (base)
Water Solubility 
ca. 200 g l-1 (20 °C, pH 5)
BRN 
5157539
EPA Substance Registry System
Carbamothioic acid, S,S'-(2-(dimethylamino)-1,3-propanediyl) ester, monohydrochloride (15263-52-2)
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Safety

Hazard Codes 
Xn;N,N,Xn
Risk Statements 
21/22-50/53
Safety Statements 
2-36/37-60-61
RIDADR 
2771
WGK Germany 
3
RTECS 
FD1225000
HazardClass 
6.1(b)
PackingGroup 
III
Toxicity
LD50 oral in rat: 250mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45995
Product name
Cartap hydrochloride
Purity
PESTANAL , analytical standard
Packaging
100mg
Price
$113
Updated
2024/03/01
TRC
Product number
C184453
Product name
Cartap hydrochloride
Packaging
100mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC40940
Product name
Cartap HCl
Packaging
50mg
Price
$100
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC40940
Product name
Cartap HCl
Packaging
25mg
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC40940
Product name
Cartap HCl
Packaging
100mg
Price
$150
Updated
2021/12/16
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Cartap hydrochloride Chemical Properties,Usage,Production

Uses

Cartap hydrochloride is used to control sucking and chewing insects (particularly Lepidoptera and Coleoptera), at almost all stages of development, on many crops including rice, potatoes, cabbage and other vegetables. It is also used on soya, peanuts, sunflower, maize, sugar beet, wheat, pearl barley, pome, stone and citrus fruit, vines, tea, chestnuts, ginger, cotton and sugar cane.

Agricultural Uses

Insecticide: Cartap hydrochloride is used to control chewing and sucking insects on many crops, including rice, potatoes, cabbage and other vegetables, soy beans, peanuts, sunflowers, maize, sugar beet, wheat, pearl barley, pome fruit, stone fruit, citrus fruit, vines, chestnuts, ginger, tea, cotton, and sugar cane. Not currently registered in the U.S. or registered for use in EU countries. There are approximately 15 global suppliers.

Trade name

CADAN®; CALDAN®; KRITAP®; NTD 2®; PADAN®; PATAP®; SANVEX®; THIOBEL®; TI1258®; VEGETOX®

Safety Profile

Poison by ingestion andintravenous routes. An experimental teratogen. Aninsecticide. When heated to decomposition it emits verytoxic fumes of NOx, SOx, and HCl.

Metabolic pathway

Nereistoxin, 4-N,N-dimethylamino-1,2-dithiolane, is produced from cartap hydrochloride as a main product through photoreaction under UV irradiation in aqueous and methanolic solutions, and on glass and silica gel surfaces. Cartap hydrochloride is also oxidized with N-bromosuccinimide (NBS) to give nereistoxin.

Degradation

Cartap hydrochloride was hydrolysed to dihydronereistoxin (2) when automatically titrated with sodium hydroxide solution and subsequently oxidised to nereistoxin (3) (see Scheme 1). The hydrolysis was a base catalysed pseudo-first-order reaction with a half-life of 10 minutes at pH 7 and 25 °C. Nereistoxin was so stable that no degradation was observed after 24 hours at 100 °C and with pH in the range 1-4. The DT50 s of nereistoxin at 100 °C and at the higher pH values of 7/10 and 12.3 were 26,20 and 7.9 hours, respectively. It was predicted that nereistoxin (3) would be hydrolysed by alkali to the 3-mercaptopropanesulfenic acid (4) which would be oxidised to the sulfinic acid (5) and thence to the sulfonic acid (6) (Asahi and Yoshida, 1977).
An aqueous solution of unlabelled cartap hydrochloride was exposed to sunlight for a period of 5 days. Analysis was by IR, UV and MS methods. Three products were isolated after irradiation and the major of these was identified as a polymer of nereistoxin (7) and represented 80% of applied dose. The polymer (7) was not toxic to fish (Oryzias latips).
Cartap was hydrolysed to nereistoxin (3) via dihydronereistoxin (2). Nereistoxin (3) was converted into the polymer (7) probably after photolytic formation of a nereistoxin diradical as shown in Scheme 1 (Obayashi and Asaka, 1983).

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Cartap hydrochloride Suppliers

Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Leancare Ltd.
Tel
--
Fax
--
Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
Advantage
42
CARBONE SCIENTIFIC CO.,LTD
Tel
--
Fax
--
Email
sales@carbonesci.com
Country
United Kingdom
ProdList
6666
Advantage
30
UK GREEN SCIENTIFIC CO.,LIMITED
Tel
--
Fax
--
Email
sales@gs-chem.com
Country
United Kingdom
ProdList
6098
Advantage
47
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View Lastest Price from Cartap hydrochloride manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Cartap hydrochloride 15263-52-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
500 tons
Release date
2020-04-27
Career Henan Chemical Co
Product
Cartap Hydrochloride 15263-52-2
Price
US $1.00/kg
Min. Order
1g
Purity
99%
Supply Ability
100KG
Release date
2018-12-25

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