2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER

Product Name: 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER
CAS No.: 193537-14-3
Chemical Name: 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER
Synonyms: 6-(TERT-BUTYL) 3-ETHYL 2-AMINO-4,7-DIHYDROTHIENO[2,3-C]PYRIDINE-3,6(5H)-DICARBOXYLATE;Ethyl 6-Boc-2-amino-4,7-dihydro-5H-thieno[2,3-c]pyridine-3-carboxylate;106278;ST5408868;ZINC04287569;BUTTPARK 75\08-01;Ethyl 2-aMino-6-Boc-4,7-d...;2-Amino-4,7-Dihydro-5H-Thieno[2,3-C]Pyridine-3,6-Dicarboxyli...;Ethyl 2-amino-6-Boc-4,7-dihydro-5H-thieno[2,3-c]pyridine-3-carboxylate;Ethyl 2-aMino-6-Boc-4,7-dihydro-5H-thieno[3,2-c]pyridine-3-carboxylate
CBNumber: CB3198472
Molecular Formula: C15H22N2O4S
Formula Weight: 326.41
MOL File: 193537-14-3.mol

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2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER Property

Melting point:: 153 °C
Boiling point:: 492.5±45.0 °C(Predicted)
Density: 1.252±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 0.40±0.20(Predicted)
Appearance: Light yellow to yellow Solid
CAS DataBase Reference: 193537-14-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/39
Hazard Note: Irritant
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: T141453
Product name: 6-tert-Butyl 3-ethyl 2-amino-4,7-dihydrothieno[2,3-c]pyridine-3,6(5H)-dicarboxylate
Purity: AldrichCPR
Packaging: 5MG
Price: $30.7
Updated: 2025/07/31

TRC

Product number: E900148
Product name: Ethyl6-Boc-2-amino-4,7-dihydro-5H-thieno[2,3-c]pyridine-3-carboxylate
Packaging: 100mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H58-1-35
Product name: Ethyl 2-amino-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate, N-Boc protected
Purity: 95%
Packaging: 250mg
Price: $38
Updated: 2021/12/16

AK Scientific

Product number: X0339
Product name: Ethyl6-Boc-2-amino-4,7-dihydro-5H-thieno[2,3-c]pyridine-3-carboxylate
Packaging: 5g
Price: $170
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB135848
Product name: 6-tert-Butyl 3-ethyl 2-amino-4,7-dihydrothieno[2,3-c]pyridine-3,6(5H)-dicarboxylate
Packaging: 500mg
Price: $75
Updated: 2021/12/16

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2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER Chemical Properties,Usage,Production

Synthesis

79099-07-3

105-56-6

193537-14-3

General Steps: Step a. Synthesis of 2-amino-4,7-dihydro-5H-thieno[2,3-c]pyridine-3,6-dicarboxylic acid 6-tert-butyl 3-ethyl ester In anhydrous ethanol (50 mL), N-tert-butoxycarbonyl-4-piperidone (12.9 g), ethyl cyanoacetate (7.345 g), and sulfur powder (2.080 g) were mixed, followed by the addition of triethylamine (9 mL). The reaction mixture was stirred at room temperature for 16 hours. Upon completion of the reaction, the precipitate was collected by filtration and washed with ethanol to afford 2-amino-4,5-dihydrothieno[2,3-c]pyridine-3,6(7H)-dicarboxylic acid-6-tert-butyl ester (18.7 g, 88% yield). Product characterization data: 1H NMR (300 MHz, CDCl3): δ 6.02 (s, 2H), 4.31 (s, 2H), 4.23 (q, 2H, J = 7.2 Hz), 3.58 (t, 2H, J = 6.0 Hz), 2.72-2.80 (br s, 2H), 1.44 (s, 9H), 1.30 (t, 3H, J = 7.2 Hz). LC-MS (ESI) m/z: 327.0 (M + H)+.

References

[1] Synlett, 2010, # 9, p. 1351 - 1354
[2] Patent: US2010/120805, 2010, A1. Location in patent: Page/Page column 44
[3] Journal of Medicinal Chemistry, 2010, vol. 53, # 20, p. 7316 - 7326
[4] Patent: WO2009/33581, 2009, A1. Location in patent: Page/Page column 62
[5] Journal of Medicinal Chemistry, 2012, vol. 55, # 7, p. 3101 - 3112

2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER Suppliers

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View Lastest Price from 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 6-tert-butyl 3-ethyl 2-amino-4H,5H,6H,7H-thieno[2,3-c]pyridine-3,6-dicarboxylate 193537-14-3
Price: US $1.10/g
Min. Order: 1g
Purity: 99.0% min
Supply Ability: 100 tons min
Release date: 2021-04-30

Career Henan Chemical Co

Product: 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER 193537-14-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1ton
Release date: 2019-07-11

193537-14-3, 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTERRelated Search:

Ethyl oxazole-4-carboxylate ethyl 2-(2-(2-(2-bromoethoxy)ethoxy)ethoxy)acetate ETHYL 2 3-BUTADIENOATE 95 Ethyl 2-(hydroxymethyl)acrylate ethyl 2-((ethoxycarbonyl)amino)-4-methyl-5-(4-nitrophenyl)thiophene-3-carboxylate ETHYL 2,3-EPOXYPROPANOATE ethyl 6-(trifluoromethyl)tetrahydro-2H-pyran-3-carboxylate Ethyl 6-oxohexanoate ETHYL 2-(BROMOMETHYL)ACRYLATE ETHYL 2,3,4-TRI-O-BENZYL-1-THIO-BETA-L-FUCOPYRANOSIDE ETHYL 2-OXAZOLECARBOXYLATE 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER TERT-BUTYL FORMATE 6-BOC-4,5,6,7-TETRAHYDRO-THIENO[2,3-C]PYRIDINE-3-CARBOXYLIC ACID (2-THIOPHEN-3-YL-ETHYL)-CARBAMIC ACID TERT-BUTYL ESTER BUTTPARK 93\08-100 BUTTPARK 77\08-23 BUTTPARK 77\08-24

Ethyl2-amino-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate,N-BOCprotected95%

Ethyl 2-amino-6-Boc-4,7-dihydro-5H-thieno[2,3-c]pyridine-3-carboxylate

6-O-tert-butyl 3-O-ethyl 2-amino-5,7-dihydro-4H-thieno[2,3-c]pyridine-3,6-dicarboxylate

2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER

6-TERT-BUTYL 3-ETHYL-2-AMINO-4,5-DIHYDRO-THIENO[2,3-C]PYRIDINE-3,6(7H)-DICARBOXYLATE

6-(TERT-BUTYL) 3-ETHYL 2-AMINO-4,7-DIHYDROTHIENO[2,3-C]PYRIDINE-3,6(5H)-DICARBOXYLATE

BUTTPARK 75\08-01

Ethyl 2-amino-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate, N-BOC protected

Ethyl 2-amino-6-tertbutoxycarbonyl-4,5,6,7-tetrahydrothieno[2.3-c]pyridine-3-carboxylate

Thieno[2,3-c]pyridine-3,6(5H)-dicarboxylic acid, 2-amino-4,7-dihydro-, 6-(1,1-dimethylethyl) 3-ethyl ester

2-AMINO-6-BOC-4,5,6,7-TETRAHYDRO-THIENO[2,3-C]PYRIDINE-3-CARBOXYLIC ACID ETHYL ESTER

BOC-ETHYL 2-AMINO- 4,5,6,7-TETRAHYDROTHIENO[2,3-C]PYRIDINE-3-CARBOXYLATE

Ethyl 2-aMino-6-Boc-4,7-d...

2-AMino-6-Boc-4,5,6,7-tetrahydro-thieno[2,3-c]pyridine-3-carboxylic acid ethyl e

Ethyl 2-aMino-6-Boc-4,7-dihydro-5H-thieno[3,2-c]pyridine-3-carboxylate

Ethyl 6-Boc-2-amino-4,7-dihydro-5H-thieno[2,3-c]pyridine-3-carboxylate

2-Amino-4,7-dihydro-5H-thieno[2,3-c]pyridine-3,6-dicarboxylic acid 6-tert-butyl 3-ethyl ester

2-amino-4,7-dihydro-5h-thieno(2,3-c)pyridine-3,6-dicarboxylic acid 6-tert-butyl 3-ethyl

106278

2-amino-5,7-dihydro-4H-thieno[2,3-c]pyridine-3,6-dicarboxylic acid O6-tert-butyl ester O3-ethyl ester

6-tert-butyl 3-ethyl 2-aMino-4H,5H,6H,7H-thieno[2,3-c]pyridine-3,6-dicarboxylate

2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTE

2-amino-5,7-dihydro-4H-thieno[5,4-c]pyridine-3,6-dicarboxylic acid O6-tert-butyl O3-ethyl ester

O6-tert-butyl O3-ethyl 2-amino-5,7-dihydro-4H-thieno[5,4-c]pyridine-3,6-dicarboxylate

ST5408868

ZINC04287569

Ethyl 2-aMino-6-boc-4,7-dihydrothieno[2,3-c]pyridine-3(5H)-carboxylate, 97%

Ethyl2-amino-6-Boc-4,7-dihydrothieno[2,3-c]pyridine-3(5H)-carboxylate,97%

2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER ISO 9001：2015 REACH

2-Amino-4,7-Dihydro-5H-Thieno[2,3-C]Pyridine-3,6-Dicarboxyli...

6-(tert-butyl) 3-ethyl 2-amino-4,5,6,7-tetrahydrothieno[3,2-c]pyridine-3,6-dicarboxylate

193537-14-3

C15H22N2O4S

CHIRAL CHEMICALS

Esters

Fused Ring Systems