ETHYL 2-(BROMOMETHYL)ACRYLATE

Product Name: ETHYL 2-(BROMOMETHYL)ACRYLATE
CAS No.: 17435-72-2
Chemical Name: ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonyms: Ethyl Bromomethacrylate;3-bromo-2-methyl-2-propenoic acid ethyl ester;DK588;NSC 215252;DKFELEX0148;2-Carbethoxyallyl Bromide;Ethyl2-(Bromomethyl)acrvlate;ETHYL 2-(BROMOMETHYL)ACRYLATE;Ethyl 2-(bromomethyl)propenoate;Ethyl 2-(bromomethyl)acrylate,97%
CBNumber: CB0741901
Molecular Formula: C6H9BrO2
Formula Weight: 193.04
MOL File: 17435-72-2.mol

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ETHYL 2-(BROMOMETHYL)ACRYLATE Property

Melting point:: 134-136℃
Boiling point:: 38 °C/0.8 mmHg (lit.)
Density: 1.398 g/mL at 25 °C (lit.)
refractive index: n20/D 1.479(lit.)
Flash point:: 178 °F
storage temp.: -20°C
solubility: Chloroform (Sparingly), Ethyl Acetate (Slightly)
form: Liquid
color: Colorless to pale yellow
BRN: 970108
InChIKey: MTCMFVTVXAOHNQ-UHFFFAOYSA-N
CAS DataBase Reference: 17435-72-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: UN 2810 6.1 / PGII
WGK Germany: 3
F: 10-19-23
HS Code: 29161900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 425222
Product name: Ethyl 2-(bromomethyl)acrylate
Purity: 98%
Packaging: 1g
Price: $74.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 425222
Product name: Ethyl 2-(bromomethyl)acrylate
Purity: 98%
Packaging: 5g
Price: $238
Updated: 2024/03/01

TCI Chemical

Product number: B1820
Product name: Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)
Purity: >97.0%(GC)
Packaging: 1g
Price: $55
Updated: 2024/03/01

TCI Chemical

Product number: B1820
Product name: Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)
Purity: >97.0%(GC)
Packaging: 5g
Price: $207
Updated: 2024/03/01

Alfa Aesar

Product number: H65384
Product name: Ethyl 2-(bromomethyl)acrylate, 97%
Packaging: 1g
Price: $61.65
Updated: 2024/03/01

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ETHYL 2-(BROMOMETHYL)ACRYLATE Chemical Properties,Usage,Production

Chemical Properties

Colourless Oil

Uses

ETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.

Uses

It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.

General Description

Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.

Purification Methods

If it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]

ETHYL 2-(BROMOMETHYL)ACRYLATE Preparation Products And Raw materials

Raw materials

tert-Butyl methyl ether Sodium chloride Formaldehyde 1,4-Dioxane Diethyl ether Ethyl acetate Sodium bicarbonate Phosphorus tribromide Ethyl acrylate Magnesium sulfate Triethylenediamine PETROLEUM ETHER

Preparation Products

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ETHYL 2-(BROMOMETHYL)ACRYLATE Suppliers

Americas 1 Australia 1 Belgium 3 Canada 2 China 157 Europe 2 France 1 Germany 7 India 11 Japan 4 Switzerland 2 The Netherlands 1 United Kingdom 12 United States 38 Global 242

Cool Pharm, Ltd

Tel: 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 13010
Advantage: 58

Huayan Chemical (Shanghai) Co., Ltd

Tel: 021-61559630 19512334056
Email: zhangkun2007@126.com
Country: China
ProdList: 49
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

PharmaBlock Sciences (Nanjing),Inc.

Tel: 025-86918202 4000255188
Fax: 86-025-86918232
Email: sales@pharmablock.com
Country: China
ProdList: 4986
Advantage: 55

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
Fax: (+86)-10-88425546
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Country: China
ProdList: 793
Advantage: 59

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
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ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
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Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
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Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

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View Lastest Price from ETHYL 2-(BROMOMETHYL)ACRYLATE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: ETHYL 2-(BROMOMETHYL)ACRYLATE 17435-72-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: ETHYL 2-(BROMOMETHYL)ACRYLATE 17435-72-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100Kg
Release date: 2018-08-08

17435-72-2, ETHYL 2-(BROMOMETHYL)ACRYLATERelated Search:

Ethyl 2-(hydroxymethyl)acrylate 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER ethyl 2-((ethoxycarbonyl)amino)-4-methyl-5-(4-nitrophenyl)thiophene-3-carboxylate ETHYL 2,3-EPOXYPROPANOATE ethyl 6-(trifluoromethyl)tetrahydro-2H-pyran-3-carboxylate Ethyl 6-oxohexanoate ETHYL 2,3,4-TRI-O-BENZYL-1-THIO-BETA-L-FUCOPYRANOSIDE ETHYL 2-OXAZOLECARBOXYLATE ETHYL 2-(BROMOMETHYL)ACRYLATE Allyl bromide 3-Bromo-1-propanol 2-(BROMOMETHYL)ACRYLIC ACID Methyl 3-bromopropionate Methyl 2-(bromomethyl)acrylate 3-Bromopropionic acid 3-Bromo-2-methylpropene Ethyl methacrylate 1-BROMO-3-ETHOXYPROPANE

Ethyl2-(Bromomethyl)acrvlate

3-bromo-2-methyl-2-propenoic acid ethyl ester

2-Propenoic acid, 2-(bromomethyl)-, ethyl ester

2-(Bromomethyl)-2-propenoic Acid Ethyl Ester

2-Carbethoxyallyl Bromide

Ethyl 2-(Bromomethyl)-2-propenoate

Ethyl 3-Bromo-2-(methylene)propanoate

Ethyl Bromomethacrylate

NSC 215252

Ethyl 2-(bromomethyl)acrylate,97%

Ethyl 2-(bromomethyl)acrylate ,98%

Ethyl 2-(bromomethyl)prop-2-enoate

Ethyl 2-(broMoMethyl)acrylate, 97% 5GR

2-(BROMOMETHYL)ACRYLIC ACID ETHYL ESTER

ETHYL 2-(BROMOMETHYL)ACRYLATE

Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)

Ethyl 2-(bromomethyl)propenoate

Ethyl 3-bromo-2-methylenepropionate

Ethyl 2-(bromomethyl)acrylate, 97%, for synthesis

Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)&gt

DK588

DKFELEX0148

17435-72-2

CH2CCH2BrCO2CH2CH3

ESTER

C6 to C7

Carbonyl Compounds

Building Blocks

Organic Building Blocks

Esters

Benzothiophenes ,Thiophenes

Aliphatics

AcrylateCarbonyl Compounds

Acrylic Monomers

C6 to C7

Esters

Monomers

All Aliphatics