ChemicalBook > CAS DataBase List > ETHYL 2-(BROMOMETHYL)ACRYLATE

ETHYL 2-(BROMOMETHYL)ACRYLATE

Product Name
ETHYL 2-(BROMOMETHYL)ACRYLATE
CAS No.
17435-72-2
Chemical Name
ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonyms
Ethyl Bromomethacrylate;3-bromo-2-methyl-2-propenoic acid ethyl ester;DK588;NSC 215252;DKFELEX0148;2-Carbethoxyallyl Bromide;Ethyl2-(Bromomethyl)acrvlate;ETHYL 2-(BROMOMETHYL)ACRYLATE;Ethyl 2-(bromomethyl)propenoate;Ethyl 2-(bromomethyl)acrylate,97%
CBNumber
CB0741901
Molecular Formula
C6H9BrO2
Formula Weight
193.04
MOL File
17435-72-2.mol
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ETHYL 2-(BROMOMETHYL)ACRYLATE Property

Melting point:
134-136℃
Boiling point:
38 °C/0.8 mmHg (lit.)
Density 
1.398 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.479(lit.)
Flash point:
178 °F
storage temp. 
-20°C
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly)
form 
Liquid
color 
Colorless to pale yellow
BRN 
970108
InChIKey
MTCMFVTVXAOHNQ-UHFFFAOYSA-N
CAS DataBase Reference
17435-72-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 2810 6.1 / PGII
WGK Germany 
3
F 
10-19-23
HS Code 
29161900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
425222
Product name
Ethyl 2-(bromomethyl)acrylate
Purity
98%
Packaging
1g
Price
$74.7
Updated
2024/03/01
Sigma-Aldrich
Product number
425222
Product name
Ethyl 2-(bromomethyl)acrylate
Purity
98%
Packaging
5g
Price
$238
Updated
2024/03/01
TCI Chemical
Product number
B1820
Product name
Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)
Purity
>97.0%(GC)
Packaging
1g
Price
$55
Updated
2024/03/01
TCI Chemical
Product number
B1820
Product name
Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)
Purity
>97.0%(GC)
Packaging
5g
Price
$207
Updated
2024/03/01
Alfa Aesar
Product number
H65384
Product name
Ethyl 2-(bromomethyl)acrylate, 97%
Packaging
1g
Price
$61.65
Updated
2024/03/01
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ETHYL 2-(BROMOMETHYL)ACRYLATE Chemical Properties,Usage,Production

Chemical Properties

Colourless Oil

Uses

ETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.

Uses

It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.

General Description

Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.

Purification Methods

If it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]

ETHYL 2-(BROMOMETHYL)ACRYLATE Preparation Products And Raw materials

Raw materials

tert-Butyl methyl ether Sodium chloride Formaldehyde 1,4-Dioxane Diethyl ether Ethyl acetate Sodium bicarbonate Phosphorus tribromide Ethyl acrylate Magnesium sulfate Triethylenediamine PETROLEUM ETHER

Preparation Products

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View Lastest Price from ETHYL 2-(BROMOMETHYL)ACRYLATE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
ETHYL 2-(BROMOMETHYL)ACRYLATE 17435-72-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
ETHYL 2-(BROMOMETHYL)ACRYLATE 17435-72-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100Kg
Release date
2018-08-08

17435-72-2, ETHYL 2-(BROMOMETHYL)ACRYLATERelated Search:

Ethyl 2-(hydroxymethyl)acrylate 2-AMINO-4,7-DIHYDRO-5H-THIENO[2,3-C]PYRIDINE-3,6-DICARBOXYLIC ACID 6-TERT BUTYL ESTER 3-ETHYL ESTER ethyl 2-((ethoxycarbonyl)amino)-4-methyl-5-(4-nitrophenyl)thiophene-3-carboxylate ETHYL 2,3-EPOXYPROPANOATE ethyl 6-(trifluoromethyl)tetrahydro-2H-pyran-3-carboxylate Ethyl 6-oxohexanoate ETHYL 2,3,4-TRI-O-BENZYL-1-THIO-BETA-L-FUCOPYRANOSIDE ETHYL 2-OXAZOLECARBOXYLATE ETHYL 2-(BROMOMETHYL)ACRYLATE Allyl bromide 3-Bromo-1-propanol 2-(BROMOMETHYL)ACRYLIC ACID Methyl 3-bromopropionate Methyl 2-(bromomethyl)acrylate 3-Bromopropionic acid 3-Bromo-2-methylpropene Ethyl methacrylate 1-BROMO-3-ETHOXYPROPANE

  • Ethyl2-(Bromomethyl)acrvlate
  • 3-bromo-2-methyl-2-propenoic acid ethyl ester
  • 2-Propenoic acid, 2-(bromomethyl)-, ethyl ester
  • 2-(Bromomethyl)-2-propenoic Acid Ethyl Ester
  • 2-Carbethoxyallyl Bromide
  • Ethyl 2-(Bromomethyl)-2-propenoate
  • Ethyl 3-Bromo-2-(methylene)propanoate
  • Ethyl Bromomethacrylate
  • NSC 215252
  • Ethyl 2-(bromomethyl)acrylate,97%
  • Ethyl 2-(bromomethyl)acrylate ,98%
  • Ethyl 2-(bromomethyl)prop-2-enoate
  • Ethyl 2-(broMoMethyl)acrylate, 97% 5GR
  • 2-(BROMOMETHYL)ACRYLIC ACID ETHYL ESTER
  • ETHYL 2-(BROMOMETHYL)ACRYLATE
  • Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)
  • Ethyl 2-(bromomethyl)propenoate
  • Ethyl 3-bromo-2-methylenepropionate
  • Ethyl 2-(bromomethyl)acrylate, 97%, for synthesis
  • Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)&gt
  • DK588
  • DKFELEX0148
  • 17435-72-2
  • CH2CCH2BrCO2CH2CH3
  • ESTER
  • C6 to C7
  • Carbonyl Compounds
  • Building Blocks
  • Organic Building Blocks
  • Esters
  • Benzothiophenes ,Thiophenes
  • Aliphatics
  • AcrylateCarbonyl Compounds
  • Acrylic Monomers
  • C6 to C7
  • Esters
  • Monomers
  • All Aliphatics