ChemicalBook > CAS DataBase List > Ferrocenecarboxylic acid

Ferrocenecarboxylic acid

Product Name
Ferrocenecarboxylic acid
CAS No.
1271-42-7
Chemical Name
Ferrocenecarboxylic acid
Synonyms
FEPRAZONE;CARBOXYFERROCENE;Ferocene monocarboxylic acid;Ferroncene Monocarboxylic Acid;Cyclopentadienecarboxylic acid;cyclopenta-2,4-diene-1-carboxylic acid;(CARBOXYCYCLOPENTADIENYL)-CYCLOPENTADIENYLIRON;JACS-1271-42-7;Ferrocenoic acid;FerrocenecarboxyL
CBNumber
CB3215027
Molecular Formula
C11H10FeO210*
Formula Weight
230.04
MOL File
1271-42-7.mol
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Ferrocenecarboxylic acid Property

Melting point:
210 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Sparingly), DMSO (Slightly), Methanol (Slightly)
form 
crystal
color 
yellow
Water Solubility 
Insoluble in water.
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:
Stable. Incompatible with strong oxidizing agents.
InChI
InChI=1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;
InChIKey
VUJLGCHOGQEAED-UHFFFAOYSA-N
SMILES
[C]1(C(=O)O)[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Fe] |^1:0,4,5,6,7,8,9,10,11,12|
CAS DataBase Reference
1271-42-7(CAS DataBase Reference)
NIST Chemistry Reference
Ferrocene carboxylic acid(1271-42-7)
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
106887
Product name
Ferrocenecarboxylic acid
Purity
97%
Packaging
1g
Price
$46.8
Updated
2023/06/20
Sigma-Aldrich
Product number
106887
Product name
Ferrocenecarboxylic acid
Purity
97%
Packaging
10g
Price
$241
Updated
2023/06/20
Alfa Aesar
Product number
A16874
Product name
Ferrocenecarboxylic acid, 98%
Packaging
1g
Price
$44.2
Updated
2023/06/20
Alfa Aesar
Product number
A16874
Product name
Ferrocenecarboxylic acid, 98%
Packaging
5g
Price
$143
Updated
2023/06/20
Strem Chemicals
Product number
26-1900
Product name
Ferrocene monocarboxylic acid, min. 97%
Packaging
1g
Price
$46
Updated
2024/03/01
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Ferrocenecarboxylic acid Chemical Properties,Usage,Production

Description

Ferrocenecarboxylic acid is a metal-organic compound characterized by connecting two ferrocene molecules through a carboxy ligand. Notably, ferrocene is a stable yet highly reactive metal-organic compound that has been extensively researched due to its potential applications in catalysis, materials science, and medicine. It serves as a catalyst in catalysis, facilitating the synthesis of diverse compounds through polymerization, oxidation, and reduction reactions. In materials science, it acts as a fundamental molecular building block for synthesizing polymers and nanomaterials. Although the precise mechanism of action of Ferrocenecarboxylic acid remains fully elucidated, it is believed that the carboxy ligand binds to the ferrocene molecules, forming a stable complex. This complex, in turn, engages with other molecules, including proteins, to facilitate various reactions[1-2].

Chemical Properties

dark brown powder

Uses

Ferrocenecarboxylic acid is used to esterify complex mixtures of phenols and alcohols for analysis by GCMS. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

Purification Methods

It crystallises as yellow crystals from pet ether (m 225-230odec), CHCl3 (m 208.5odec), toluene/pet ether (m 195-205odec), or aqueous ethanol. [Matsue et al. J Am Chem Soc 107 3411 1985.] The acid chloride m 49o crystallises from pentane, and has max at 458nm [Lau & Hart J Org Chem 24 280 1959]. The methyl ester crystallises from aqueous MeOH with m 70-71o. The anhydride has m 143-145o when recrystallised from pet ether [Acton & Silverstein J Org Chem 24 1487 1959]. The amide has m 168-170o when crystallised from CHCl3/Et2O or m 167-169o when crystallised from *C6H6/MeOH. [Arimoto & Haven J Am Chem Soc 77 6295 1955, Benkeser et al. J Am Chem Soc 76 4025 1954.] [Beilstein 16 IV 1807.]

References

[1] C. Pess?a, L. Kubota, Y. Gushikem. “Ferrocenecarboxylic acid adsorbed on Nb2O5 film grafted on a SiO2 surface: NADH oxidation study.” Electrochimica Acta 46 1 (2001): 2499–2505.
[2] H. Tsukube, S. Shinoda, H. Fukui. “Synergistic binding and chirality sensing of unprotected amino acids with ferrocenecarboxylic acid–crown ether conjugate.” Tetrahedron Letters 42 1 (2001): 7583–7585.

Ferrocenecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ferrocenecarboxylic acid manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Ferrocenecarboxylic acid 1271-42-7
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-25
Hebei Weibang Biotechnology Co., Ltd
Product
Ferrocenecarboxylic acid 1271-42-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-04
Hebei Yanxi Chemical Co., Ltd.
Product
ferrocenecarboxylic acid 1271-42-7
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-10

1271-42-7, Ferrocenecarboxylic acidRelated Search:

Folic acid tert-Butylferrocene Stearic acid Aminoferrocene ETHYNYLFERROCENE Ferrocene Hyaluronic acid Ethyl 2-(Chlorosulfonyl)acetate Ferrocenecarboxaldehyde Acetylferrocene Citric acid Ferrocenemethanol Ferrocenecarboxamide Ascoric Acid Ethylboronic acid 7-Bromo-2,4-dichloropyrido[3,2-d]pyrimidine 2-HYDROXYTHIOPHENOL 3-Amino-6-methylpicolinic acid

  • (CARBOXYCYCLOPENTADIENYL)-CYCLOPENTADIENYLIRON
  • CARBOXYFERROCENE
  • FERROCENE MONOCARBOXYLIC ACID
  • FERROCENE, CARBOXY-
  • FERROCENECARBOXYLIC ACID
  • Ferroncene Monocarboxylic Acid
  • FERROENECARBOXYLIC ACID
  • Ferocene monocarboxylic acid
  • Ferrocenemonocarboxylicacid,min.97%
  • FERROCENECARBOXYLIC ACID (controlled chemical)
  • FEPRAZONE
  • Ferrocene monocarboxylic acid, min. 97%
  • FerrocenecarboxyL
  • Ferrocenecarboxylic acid,97%
  • Ferrocenecarboxylic acid ,98%
  • Ferrocenecarboxylic acid 97%
  • Cyclopentadienecarboxylic acid ferrocenoic acid
  • Ferrocenecarboxylic acid≥ 99% (HPLC)
  • Ferrocenecarboxylic acid puruM, >=97.0% (Fe)
  • Carboxylferrocene
  • Cyclopentadienecarboxylic acid
  • Ferrocenoic acid
  • Ferrocenecarboxylic acid, >=99%
  • JACS-1271-42-7
  • FerrocenecarboxylicAcid&gt
  • Ferrocenecarboxylic acid ISO 9001：2015 REACH
  • Ferrocene, carboxy- (9CI)
  • cyclopenta-2,4-diene-1-carboxylic acid
  • errocenecarboxylic acid
  • 1271-42-7
  • HOOCC5H4FeC5H5
  • C11H10FeO2
  • Catalysis and Inorganic Chemistry
  • metallocene
  • Pyridines ,Heterocyclic Acids
  • Piperazine derivates
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • Ferrocene series
  • bc0001
  • 1271-42-7