ChemicalBook > CAS DataBase List > Silver(I) trifluoromethanethiolate

Silver(I) trifluoromethanethiolate

Product Name
Silver(I) trifluoromethanethiolate
CAS No.
811-68-7
Chemical Name
Silver(I) trifluoromethanethiolate
Synonyms
AgSCF3;ver(I) TrifL;uoromethanethioL;silver,trifluoromethanethiol;Silver trifluoromethanethiolate;(Trifluoromethylthio) silver(I);Silver(I)trifluoromethanethiolate;[(Trifluoromethyl)thio] silver(I);Trifluoromethanethiol Silver(I) Salt;Methanethiol,1,1,1-trifluoro-, silver(1+) salt (1:1)
CBNumber
CB32256985
Molecular Formula
CHAgF3S
Formula Weight
209.94
MOL File
811-68-7.mol
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Silver(I) trifluoromethanethiolate Property

storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Water Solubility 
Insoluble in water
solubility 
Methanol
form 
powder to crystal
color 
White to Light yellow to Light red
InChI
InChI=1S/CHF3S.Ag/c2-1(3,4)5;/h5H;
InChIKey
SVPQZGWGYCARGG-UHFFFAOYSA-N
SMILES
C(S)(F)(F)F.[Ag]
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Safety

HS Code 
2843290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
S0977
Product name
Silver(I) Trifluoromethanethiolate
Purity
>95.0%(T)
Packaging
1g
Price
$148
Updated
2025/07/31
TCI Chemical
Product number
S0977
Product name
Silver(I) Trifluoromethanethiolate
Purity
>95.0%(T)
Packaging
5g
Price
$534
Updated
2025/07/31
TRC
Product number
S465063
Product name
Silver(I) Trifluoromethanethiolate
Packaging
100mg
Price
$75
Updated
2021/12/16
Arctom
Product number
AS448718
Product name
Silver(I) Trifluoromethanethiolate
Purity
95%
Packaging
1g
Price
$137
Updated
2021/12/16
Ambeed
Product number
A139672
Product name
Silver(I) Trifluoromethanethiolate
Purity
95%
Packaging
1g
Price
$138
Updated
2021/12/16
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Silver(I) trifluoromethanethiolate Chemical Properties,Usage,Production

Uses

Silver(I) trifluoromethanethiolate is an important organic synthesis intermediate and pharmaceutical intermediate for the preparation of trifluoromethyl aryl sulfides and indanone derivatives[1-2].

Synthesis

14104-20-2

2926-29-6

811-68-7

Silver tetrafluoroborate (AgBF4, 19.77 g, 100 mmol) and sodium trifluoromethanesulfinate (CF3SO2Na, 18.73 g, 120 mmol) were dissolved in anhydrous acetonitrile (400 mL) under nitrogen protection. After cooling the reaction mixture to 0°C, triphenylphosphine (Ph3P, 62.95 g, 240 mmol) was slowly added. Subsequently, the reaction mixture was brought back to room temperature and heated to 50°C and maintained at this temperature for 12 hours. Upon completion of the reaction, the mixture was filtered through diatomaceous earth and the filtrate was cooled to -20°C to promote crystallization. After the crystals were sufficiently precipitated, the supernatant was decanted to remove most of the triphenylphosphine oxide. The supernatant was concentrated under reduced pressure to remove the solvent and the residue was washed well with ether and dried under vacuum. Finally, the resulting solid was recrystallized with tetrahydrofuran and benzene to afford silver trifluoromethane thiol (I) (18.60 g, 89% yield).

References

[1] DAVE J. ADAMS, James H C. ChemInform Abstract: Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I) Trifluoromethanethiolate and an Inorganic Iodide.[J]. ChemInform, 2010, 31 23. DOI:10.1002/chin.200023091.
[2] YI-KANG SONG. Synthesis of 2-(trifluoromethylthio)-indenones by silver-mediated cascade trifluoromethylthiolation/cyclization of arylpropynones[J]. Tetrahedron, 2016, 72 47: Pages 7589-7593. DOI:10.1016/j.tet.2016.10.013.

Silver(I) trifluoromethanethiolate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Silver(I) trifluoromethanethiolate manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
(Trifluoromethylthio) silver(I) 811-68-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-09
Longyan Tianhua Biological Technology Co., Ltd
Product
Silver(I) Trifluoromethanethiolate 811-68-7
Price
US $35.00/Kg/Bag
Min. Order
25Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2020-11-13

811-68-7, Silver(I) trifluoromethanethiolateRelated Search:

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  • (Trifluoromethylthio) silver(I)
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  • Silver(I)trifluoromethanethiolate
  • silver,trifluoromethanethiol
  • Trifluoromethanethiol Silver(I) Salt
  • AgSCF3
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  • uoromethanethioL
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  • 811-68-7
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  • CAgF3S