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MERPHOS

Product Name
MERPHOS
CAS No.
150-50-5
Chemical Name
MERPHOS
Synonyms
Folex;Folen;MERPHOS;folex6ec;FOLEX(R);easyoff-d;NSC 27720;Easy off-D;folex (tm);deleafdefoliant
CBNumber
CB3226168
Molecular Formula
C12H27PS3
Formula Weight
298.51
MOL File
150-50-5.mol
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MERPHOS Property

Melting point:
100°C
Boiling point:
115-134 °C(Press: 0.08 Torr)
Density 
1.0200
solubility 
Chloroform (Slightly), Dichloromethane (Slightly), Diethyl Ether (Slightly)
form 
Liquid
Stability:
Air Sensitive, Hygroscopic, Moisture Sensitive
EPA Substance Registry System
Merphos (150-50-5)
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Safety

RIDADR 
3278
HazardClass 
6.1(b)
PackingGroup 
III
Hazardous Substances Data
150-50-5(Hazardous Substances Data)
Toxicity
guinea pig,LD50,oral,850mg/kg (850mg/kg),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 27(8), Pg. 97, 1962.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M257700
Product name
Merphos
Packaging
25mg
Price
$845
Updated
2021/12/16
TRC
Product number
M257700
Product name
Merphos
Packaging
50mg
Price
$1455
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AGR0000238
Product name
MERPHOS
Purity
95.00%
Packaging
1MG
Price
$405
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AGR0000238
Product name
MERPHOS
Purity
95.00%
Packaging
10MG
Price
$450
Updated
2021/12/16
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MERPHOS Chemical Properties,Usage,Production

Chemical Properties

Nearly colorless liquid. Insoluble in water; soluble in a variety of organic solvents.

Uses

Merphos is an organothiophosphorus compound used as a defoliant but the active ingredient is no longer contained in any registered pesticide product in the US and in EU. Therefore, Environmental Protection Agency (EPA) is characterizing it as canceled.
The status of merphos in the EU pesticide database is ‘Not Approved’ under the Regulation EC 1107/2009 and not authorized at national level in EU countries. However a maximum level of residues (MRL) is regulated in foods as the default MRL of 0.01 mg kg-1 according to Art 18(1)(b) Reg 396/2005.
Merphos was used to defoliate cotton at application rates of 1.1–2.2 kg active ingredient per acre and can induce leaf abscission in some other plants, such as roses and hydrangeas. It was particularly suited for total defoliation of cotton preparatory to machine harvesting because the natural action of the substance causes the leaves to drop in a relatively green state with fresh weight adequate to cause them to fall to the ground.
The technical product used to have 95% purity. Formulation used to contain 720 g active ingredient per liter or being an emulsifiable concentrate containing 6 lb per gallon.

Uses

Organophosphate pesticide used in the agriculture industry

General Description

Emulsifiable oil.

Reactivity Profile

Organothiophosphates, such as MERPHOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Cholinesterase inhibitor.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. A cholinesterase inhibitor. Combustible when exposed to heat or flame. Can react vigorously with oxidzing materials. When heated to decomposition it emits highly toxic fumes of POx and SOx. Used as a defoliant. See also PARATHION.

Environmental Fate

Merphos is adsorbed strongly to soil and oxidized to S,S,S-tributyl phosphorotrithioate (DEF). The Koc estimated for merphos is theoretically 62 000; accordingly, merphos would be immobile in soil.
In water, merphos will be oxidized to DEF. The fact that merphos is expected to adsorb strongly to particulate matter in the water column, apparently did not impede its oxidation.
In the atmosphere, merphos will exist as an aerosol and be removed by gravitational settling and readily oxidized to DEF. Vapor-phase merphos will react with photochemically produced hydroxyl radicals, with an estimated half-life of 4.9 h.

MERPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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MERPHOS Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
Chemsky (shanghai) International Co.,Ltd
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
15421
Advantage
60
Nanjing Peiwill Biotechnology Co.,Ltd.
Tel
025-57027729 15850702895
Fax
025-57027729
Email
15850702895@163.com
Country
China
ProdList
73
Advantage
55
Shenzhen Regent Biochemical Technology Co., Ltd.
Tel
0755-0755-85201366 18938635012
Fax
0755-85201366
Email
sales@regentsciences.com
Country
China
ProdList
9293
Advantage
58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 13028896684
Email
sales@rrkchem.com
Country
China
ProdList
55827
Advantage
58
Shanghai UCHEM Inc.
Tel
+862156762820 +86-13564624040
Email
sales@myuchem.com
Country
China
ProdList
6709
Advantage
58
Career Henan Chemica Co
Tel
+86-0371-86658258 15093356674;
Fax
0371-86658258
Email
laboratory@coreychem.com
Country
China
ProdList
30255
Advantage
58
Hubei Jusheng Technology Co.,Ltd.
Tel
18871490254
Fax
027-59599243
Email
linda@hubeijusheng.com
Country
CHINA
ProdList
28180
Advantage
58
Changzhou Yinghao Technology Development Co., Ltd
Tel
15151934985
Email
sales@yingsapharm.com
Country
China
ProdList
4291
Advantage
58
ShangHai Anpel Co, Ltd.
Tel
18501792038; 18501792038
Email
shanpel@anpel.com.cn
Country
China
ProdList
9614
Advantage
58
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View Lastest Price from MERPHOS manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
MERPHOS 150-50-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-22

150-50-5, MERPHOSRelated Search:


  • TRIBUTYLPHOSPHORO-TRITHIOITE
  • Butyl phosphorotrithioite ((bus)3p)
  • butylphosphorotrithioite
  • butylphosphorotrithioite[(bus)3p]
  • Deleaf defoliant
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  • Easy off-D
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  • Folex
  • folex6ec
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  • Phosphorotrithious acid, tributyl ester
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  • S,S,S-Tributyl phosphorotrithioite
  • S,S,S-Tributyl trithiophosphite
  • s,s,s-tributylphosphorotrithioite
  • s,s,s-tributyltrithiophosphite
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  • Merphos @100 μg/mL in MeOH
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  • 150-50-5
  • 150-50-7
  • C12H27PS3
  • Agro-Products
  • Sulfur & Selenium Compounds