2-Anilinobenzoic acid methyl ester

Product Name: 2-Anilinobenzoic acid methyl ester
CAS No.: 35708-19-1
Chemical Name: 2-Anilinobenzoic acid methyl ester
Synonyms: METHYL 2-ANILINOBENZOATE;methyl 2-(phenylamino)benzoate;2-Anilinobenzoic acid methyl ester;2-(Phenylamino)benzoic acid methyl ester;Benzoic acid, 2-(phenylaMino)-, Methyl ester
CBNumber: CB32336256
Molecular Formula: C14H13NO2
Formula Weight: 227.26
MOL File: 35708-19-1.mol

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2-Anilinobenzoic acid methyl ester Property

Melting point:: 58-59 °C
Boiling point:: 140 °C(Press: 0.1 Torr)
Density: 1.175±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: -1.27±0.20(Predicted)
Appearance: Off-white to gray Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: CHM0304374
Product name: METHYL-2-(PHENYLAMINO)BENZOATE
Purity: 95.00%
Packaging: 5MG
Price: $499.84
Updated: 2021/12/16

Alichem

Product number: 35708191
Product name: 2-Anilinobenzoicacidmethylester
Packaging: 5g
Price: $334.62
Updated: 2021/12/16

Alichem

Product number: 35708191
Product name: 2-Anilinobenzoicacidmethylester
Packaging: 10g
Price: $585.52
Updated: 2021/12/16

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2-Anilinobenzoic acid methyl ester Chemical Properties,Usage,Production

Synthesis

108-86-1

134-20-3

35708-19-1

General procedure for the synthesis of methyl 2-aminobenzoate from bromobenzene and methyl o-aminobenzoate: 15 g of methyl o-aminobenzoate, 15.6 g of bromobenzene, 0.9 g of tris(dibenzylideneacetone)dipalladium (Pd2(dba)3), 0.4 g of tri-tert-butylphosphine (P(t-Bu)3), and 28.6 g of tertiary butylsodium alcohol (Na(t-BuO)) were added, under nitrogen protection, to a round bottom flask followed by addition of 100 mL of toluene as solvent. The mixture was stirred and heated to reflux. Upon completion of the reaction, the reaction mixture was cooled to room temperature and washed with dichloromethane and water. The organic layer was separated, dried over anhydrous magnesium sulfate (MgSO4), filtered and purified by column chromatography to give the final methyl 2-(phenylamino)benzoate in a yield of 21.0 g in 93%.

References

[1] Tetrahedron, 2006, vol. 62, # 48, p. 11100 - 11105
[2] Patent: TWI579270, 2017, B. Location in patent: Paragraph 0094; 0095
[3] Chemistry - A European Journal, 2006, vol. 12, # 13, p. 3636 - 3646
[4] Journal of Organic Chemistry, 2005, vol. 70, # 20, p. 8107 - 8109
[5] Patent: KR2016/102142, 2016, A. Location in patent: Paragraph 0215; 0218; 0219

2-Anilinobenzoic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Anilinobenzoic acid methyl ester Suppliers

China 38 India 1 United States 3 Global 42

Hangzhou Sage Chemical Co., Ltd.

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35708-19-1, 2-Anilinobenzoic acid methyl esterRelated Search:

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2-Anilinobenzoic acid methyl ester

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35708-19-1