2-Anilinobenzoic acid methyl ester
- Product Name
- 2-Anilinobenzoic acid methyl ester
- CAS No.
- 35708-19-1
- Chemical Name
- 2-Anilinobenzoic acid methyl ester
- Synonyms
- METHYL 2-ANILINOBENZOATE;methyl 2-(phenylamino)benzoate;2-Anilinobenzoic acid methyl ester;2-(Phenylamino)benzoic acid methyl ester;Benzoic acid, 2-(phenylaMino)-, Methyl ester
- CBNumber
- CB32336256
- Molecular Formula
- C14H13NO2
- Formula Weight
- 227.26
- MOL File
- 35708-19-1.mol
2-Anilinobenzoic acid methyl ester Property
- Melting point:
- 58-59 °C
- Boiling point:
- 140 °C(Press: 0.1 Torr)
- Density
- 1.175±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- -1.27±0.20(Predicted)
- Appearance
- Off-white to gray Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- CHM0304374
- Product name
- METHYL-2-(PHENYLAMINO)BENZOATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $499.84
- Updated
- 2021/12/16
- Product number
- 35708191
- Product name
- 2-Anilinobenzoicacidmethylester
- Packaging
- 10g
- Price
- $585.52
- Updated
- 2021/12/16
- Product number
- 35708191
- Product name
- 2-Anilinobenzoicacidmethylester
- Packaging
- 5g
- Price
- $334.62
- Updated
- 2021/12/16
2-Anilinobenzoic acid methyl ester Chemical Properties,Usage,Production
Synthesis
108-86-1
134-20-3
35708-19-1
General procedure for the synthesis of methyl 2-aminobenzoate from bromobenzene and methyl o-aminobenzoate: 15 g of methyl o-aminobenzoate, 15.6 g of bromobenzene, 0.9 g of tris(dibenzylideneacetone)dipalladium (Pd2(dba)3), 0.4 g of tri-tert-butylphosphine (P(t-Bu)3), and 28.6 g of tertiary butylsodium alcohol (Na(t-BuO)) were added, under nitrogen protection, to a round bottom flask followed by addition of 100 mL of toluene as solvent. The mixture was stirred and heated to reflux. Upon completion of the reaction, the reaction mixture was cooled to room temperature and washed with dichloromethane and water. The organic layer was separated, dried over anhydrous magnesium sulfate (MgSO4), filtered and purified by column chromatography to give the final methyl 2-(phenylamino)benzoate in a yield of 21.0 g in 93%.
References
[1] Tetrahedron, 2006, vol. 62, # 48, p. 11100 - 11105
[2] Patent: TWI579270, 2017, B. Location in patent: Paragraph 0094; 0095
[3] Chemistry - A European Journal, 2006, vol. 12, # 13, p. 3636 - 3646
[4] Journal of Organic Chemistry, 2005, vol. 70, # 20, p. 8107 - 8109
[5] Patent: KR2016/102142, 2016, A. Location in patent: Paragraph 0215; 0218; 0219
2-Anilinobenzoic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
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