1-N-CBZ-MORPHOLINE

Product Name: 1-N-CBZ-MORPHOLINE
CAS No.: 25070-73-9
Chemical Name: 1-N-CBZ-MORPHOLINE
Synonyms: Benzyl morpholine-4-carboxylate;1-N-CBZ-MORPHOLINE;4-?Morpholinecarboxylic acid, phenylmethyl ester
CBNumber: CB32456291
Molecular Formula: C12H15NO3
Formula Weight: 221.25
MOL File: 25070-73-9.mol

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1-N-CBZ-MORPHOLINE Property

Melting point:: 47-49 °C
Boiling point:: 349.7±42.0 °C(Predicted)
Density: 1.183±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: -1.63±0.20(Predicted)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Chemenu

Product number: CM251701
Product name: Benzylmorpholine-4-carboxylate
Purity: 97%
Packaging: 1g
Price: $173
Updated: 2021/12/16

Alichem

Product number: 25070739
Product name: Benzylmorpholine-4-carboxylate
Packaging: 1g
Price: $180.2
Updated: 2021/12/16

Chemenu

Product number: CM251701
Product name: Benzylmorpholine-4-carboxylate
Purity: 97%
Packaging: 5g
Price: $477
Updated: 2021/12/16

Alichem

Product number: 25070739
Product name: Benzylmorpholine-4-carboxylate
Packaging: 5g
Price: $504.9
Updated: 2021/12/16

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1-N-CBZ-MORPHOLINE Chemical Properties,Usage,Production

Synthesis

110-91-8

501-53-1

25070-73-9

GENERAL METHODS: Benzyl chloroformate (1 mmol) was slowly added to morpholine (1 mmol), followed by microwave radiation (100 W) of the mixture, with reaction times referring to Tables 2, 3, 4, and 5.The progress of the reaction was monitored by Thin Layer Chromatography (TLC), with the unfolding agent ratio of dichloromethane: methanol (98:2). Upon completion of the reaction, n-hexane (15-20 mL) was added to the reaction mixture and allowed to stand overnight at room temperature. The solid product was collected by filtration, washed with hexane and dried to give benzyl morpholine-4-carboxylate in good to excellent yield. The successful protection of the amine structure was confirmed by the generation of hydrogen chloride gas during the reaction.

References

[1] Journal of Organic Chemistry, 2004, vol. 69, # 2, p. 577 - 580
[2] Tetrahedron Letters, 2007, vol. 48, # 1, p. 55 - 59
[3] Tetrahedron Letters, 2006, vol. 47, # 36, p. 6393 - 6396
[4] Tetrahedron Letters, 2008, vol. 49, # 16, p. 2607 - 2610
[5] Chemistry Letters, 2010, vol. 39, # 3, p. 228 - 229

1-N-CBZ-MORPHOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-N-CBZ-MORPHOLINE Suppliers

China 20 India 1 United States 1 Global 22

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25070-73-9, 1-N-CBZ-MORPHOLINERelated Search:

4-CBZ-3(R)-MORPHOLINECARBOXYLIC ACID 3-CARBOXYMETHYL-MORPHOLINE-4-CARBOXYLIC ACID BENZYL ESTER 2-(4-N-CBZ-MORPHOLIN-2-YL)ACETIC ACID 3-AMINOMETHYL-MORPHOLINE-4-CARBOXYLIC ACID BENZYL ESTER (R)-1-CBZ-3-CYANOMETHYLMORPHOLINE 3-Cbz-6-oxa-3-aza-bicyclo[3.1.0]hexane 4-CBZ-3(S)-MORPHOLINECARBOXYLIC ACID 4-CBZ-2-HYDROXYMETHYLMORPHOLINE (5R)-3,4,5,6-TETRAHYDRO-5-PHENYL-N-(BENZYLOXYCARBONYL)-4(H)-1,4-OXAZIN-2-ONE (R)-1-CBZ-3-(1H-TETRAZOL-5-YLMETHYL)MORPHOLINE 3-(2-CARBOXY-ETHYL)-MORPHOLINE-4-CARBOXYLIC ACID BENZYL ESTER (5S)-3,4,5,6-TETRAHYDRO-5-PHENYL-N-(BENZYLOXYCARBONYL)-4(H)-1,4-OXAZIN-2-ONE 4-CBZ-MORPHOLINE-3-CARBOXYLIC ACID Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

1-N-CBZ-MORPHOLINE

Benzyl morpholine-4-carboxylate

4-?Morpholinecarboxylic acid, phenylmethyl ester

25070-73-9