ChemicalBook > CAS DataBase List > Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Product Name
Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
CAS No.
105228-46-4
Chemical Name
Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Synonyms
6-oxo-2;Benzyl (2S;3-diphenyl-;4-Morpholinecarboxylicacid;(2S,3R)-N-CBZ-6-OXO-2,3- DIPHENYLMORPHOLINE;(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine;(2S,3R)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;(5S,6R)-(+)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone;(2S,3R)-(+)-N-Benzyloxycarbonyl-6-oxo-2,3-diphenylMorpholine;BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE
CBNumber
CB8215941
Molecular Formula
C24H21NO4
Formula Weight
387.43
MOL File
105228-46-4.mol
More
Less

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Property

Melting point:
205-207 °C(lit.)
alpha 
66 º (c=5.5 in methylene chloride)
Boiling point:
583.5±50.0 °C(Predicted)
Density 
1.242±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
-3.33±0.60(Predicted)
optical activity
[α]25/D +66°, c = 5.5 in methylene chloride
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29349990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
331856
Product name
(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine
Purity
99%
Packaging
1g
Price
$101
Updated
2023/06/20
TRC
Product number
B287520
Product name
(2S,3R)-Benzyl6-Oxo-2,3-diphenylmorpholine-4-carboxylate
Packaging
500mg
Price
$155
Updated
2021/12/16
ChemScene
Product number
CS-B0131
Product name
4-Morpholinecarboxylicacid,6-oxo-2,3-diphenyl-,phenylmethylester,(2S,3R)-
Packaging
1g
Price
$78
Updated
2021/12/16
Chem-Impex
Product number
41476
Product name
(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine,≥98.5%(HPLC)
Purity
≥98.5%(HPLC)
Packaging
1G
Price
$88.52
Updated
2021/12/16
AK Scientific
Product number
1194AA
Product name
(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate
Packaging
250mg
Price
$92
Updated
2021/12/16
More
Less

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties,Usage,Production

Uses

(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine can be used as a starting material for the synthesis of:

  • α-Amino-β-silyloxy-ester, a key intermediate for the preparation of antimalarial drug quinine and its analogs.
  • R, R-Formylglycine dimethylacetal, a key intermediate for the preparation of tuberculostatic compound capreomycin IB.
  • 2R,5R,6S-2-(Methoxycarbonylmethyl)-5,6-diphenylmorpholine hydrochloride, a key intermediate for the preparation of an antibiotic (+)-negamycin.

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Suppliers

China 62 Germany 1 India 1 Switzerland 1 United Kingdom 2 United States 15 Global 82
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
2918
Advantage
50
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
ForeChem (Nantong) Technology Co.,Ltd.
Tel
513-85982855 18921614129
Fax
051385915507
Email
sales@xianxingpharm.com
Country
China
ProdList
1819
Advantage
61
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9551
Advantage
66
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10194
Advantage
62
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
zhangsn@titansci.com
Country
China
ProdList
14113
Advantage
59
More
Less

View Lastest Price from Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate manufacturers

Career Henan Chemical Co
Product
Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 105228-46-4
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-09

105228-46-4, Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylateRelated Search:

Moroxydine Moroxydine hydrochloride Biphenyl Benzyl isocyanate Benzyl benzoate Tridemorph Benzyl nicotinate Benzyl alcohol Benzyl chloride Dimethomorph Benzyl (+)-N-METHYLEPHEDRINE (S)-(-)-N-(2-HYDROXYETHYL)-ALPHA-PHENYLETHYLAMINE Z-SAR-OH 5-Phenyl-2-morpholinone D-(+)-Norephedrine BENZYL (2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE N-ISOPROPYL-N-METHYLGLYCINE

  • BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE
  • (2S,3R)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate
  • 4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2S,3R)-
  • 3-diphenyl-
  • 4-Morpholinecarboxylicacid
  • 6-oxo-2
  • (2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine
  • (5S,6R)-(+)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone
  • (2S,3R)-(+)-N-Benzyloxycarbonyl-6-oxo-2,3-diphenylMorpholine
  • (5R,6S)-4-(benzyloxycarbonyl)-5,6-diphenyl-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one
  • (2<I>S</I>,3<I>R</I>)-(+)-<I>N</I>-<WBR>Z-<WBR>6-<WBR>oxo-<WBR>2,3-<WBR>diphenylMorpholine
  • (2S,3R)-N-CBZ-6-OXO-2,3- DIPHENYLMORPHOLINE
  • Benzyl (2S
  • Benzyl (2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarbox ylate,99%e.e.
  • (2S,3R)-6-oxo-2,3-diphenyl-4-morpholinecarboxylic acid (phenylmethyl) ester
  • 105228-46-4
  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Morpholines
  • Heterocyclic Building Blocks
  • Chiral Building Blocks
  • Heterocyclic Building Blocks
  • Morpholines