Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Product Name: Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
CAS No.: 105228-46-4
Chemical Name: Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Synonyms: 6-oxo-2;Benzyl (2S;3-diphenyl-;4-Morpholinecarboxylicacid;(2S,3R)-N-CBZ-6-OXO-2,3- DIPHENYLMORPHOLINE;(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine;(2S,3R)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;(5S,6R)-(+)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone;(2S,3R)-(+)-N-Benzyloxycarbonyl-6-oxo-2,3-diphenylMorpholine;BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE
CBNumber: CB8215941
Molecular Formula: C24H21NO4
Formula Weight: 387.43
MOL File: 105228-46-4.mol

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Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Property

Melting point:: 205-207 °C(lit.)
alpha: 66 º (c=5.5 in methylene chloride)
Boiling point:: 583.5±50.0 °C(Predicted)
Density: 1.242±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: -3.33±0.60(Predicted)
optical activity: [α]25/D +66°, c = 5.5 in methylene chloride

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 331856
Product name: (2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine
Purity: 99%
Packaging: 1g
Price: $101
Updated: 2023/06/20

TRC

Product number: B287520
Product name: (2S,3R)-Benzyl6-Oxo-2,3-diphenylmorpholine-4-carboxylate
Packaging: 500mg
Price: $155
Updated: 2021/12/16

ChemScene

Product number: CS-B0131
Product name: 4-Morpholinecarboxylicacid,6-oxo-2,3-diphenyl-,phenylmethylester,(2S,3R)-
Packaging: 1g
Price: $78
Updated: 2021/12/16

Chem-Impex

Product number: 41476
Product name: (2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine,≥98.5%(HPLC)
Purity: ≥98.5%(HPLC)
Packaging: 1G
Price: $88.52
Updated: 2021/12/16

AK Scientific

Product number: 1194AA
Product name: (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate
Packaging: 250mg
Price: $92
Updated: 2021/12/16

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Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties,Usage,Production

Uses

(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine can be used as a starting material for the synthesis of:

α-Amino-β-silyloxy-ester, a key intermediate for the preparation of antimalarial drug quinine and its analogs.
R, R-Formylglycine dimethylacetal, a key intermediate for the preparation of tuberculostatic compound capreomycin IB.
2R,5R,6S-2-(Methoxycarbonylmethyl)-5,6-diphenylmorpholine hydrochloride, a key intermediate for the preparation of an antibiotic (+)-negamycin.

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Suppliers

China 60 Germany 1 India 1 Switzerland 1 United Kingdom 2 United States 15 Global 80

SIGMA-RBI

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Country: Switzerland
ProdList: 6896
Advantage: 91

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View Lastest Price from Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate manufacturers

Career Henan Chemical Co

Product: Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 105228-46-4
Price: US $6.68/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg-1000kg
Release date: 2020-01-09

105228-46-4, Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylateRelated Search:

Moroxydine Moroxydine hydrochloride Biphenyl Benzyl isocyanate Benzyl benzoate Tridemorph Benzyl nicotinate Benzyl alcohol Benzyl chloride Dimethomorph Benzyl (+)-N-METHYLEPHEDRINE (S)-(-)-N-(2-HYDROXYETHYL)-ALPHA-PHENYLETHYLAMINE Z-SAR-OH 5-Phenyl-2-morpholinone D-(+)-Norephedrine BENZYL (2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE N-ISOPROPYL-N-METHYLGLYCINE

BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE

(2S,3R)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate

4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2S,3R)-

3-diphenyl-

4-Morpholinecarboxylicacid

6-oxo-2

(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine

(5S,6R)-(+)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone

(2S,3R)-(+)-N-Benzyloxycarbonyl-6-oxo-2,3-diphenylMorpholine

(5R,6S)-4-(benzyloxycarbonyl)-5,6-diphenyl-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one

(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine

(2S,3R)-N-CBZ-6-OXO-2,3- DIPHENYLMORPHOLINE

Benzyl (2S

Benzyl (2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarbox ylate,99%e.e.

(2S,3R)-6-oxo-2,3-diphenyl-4-morpholinecarboxylic acid (phenylmethyl) ester

105228-46-4

Chiral Building Blocks

Asymmetric Synthesis

Morpholines

Heterocyclic Building Blocks

Chiral Building Blocks

Heterocyclic Building Blocks

Morpholines