Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Product Name: Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
CAS No.: 100516-54-9
Chemical Name: Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Synonyms: William's lactone;CIVENTICHEM CV-2655;CIVENTICHEM CV-2652;(2R,3S)-()-N-Z-6-oxo-2,3-diphenylMorpholine;(2R,3S)-N-Cbz-6-oxo-2,3- diphenylmorpholine;(2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylmorpholine 98%;benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholin;Benzyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate;(2R,3S)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-morpholinone
CBNumber: CB2331294
Molecular Formula: C24H21NO4
Formula Weight: 387.43
MOL File: 100516-54-9.mol

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Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Property

Melting point:: 205-207 °C(lit.)
alpha: -66 º (c=5.5 in methylene chloride)
Boiling point:: 583.5±50.0 °C(Predicted)
Density: 1.242±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form: Solid
pka: -3.33±0.60(Predicted)
color: White
optical activity: [α]25/D 66°, c = 5.5 in methylene chloride
InChI: InChI=1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,23+/m0/s1
InChIKey: HECRUWTZAMPQOS-XZOQPEGZSA-N
SMILES: N1(C(OCC2=CC=CC=C2)=O)CC(=O)O[C@H](C2=CC=CC=C2)[C@@H]1C1=CC=CC=C1

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
HS Code: 29349990
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 331872
Product name: (2R,3S)-(?)-N-Z-6-oxo-2,3-diphenylmorpholine
Purity: 98%
Packaging: 1g
Price: $87
Updated: 2023/01/07

Cayman Chemical

Product number: 30497
Product name: (2R,3S)-N-Cbz-6-oxo-2,3-Diphenylmorpholine
Packaging: 250mg
Price: $44
Updated: 2024/03/01

Cayman Chemical

Product number: 30497
Product name: (2R,3S)-N-Cbz-6-oxo-2,3-Diphenylmorpholine
Packaging: 500mg
Price: $84
Updated: 2024/03/01

Cayman Chemical

Product number: 30497
Product name: (2R,3S)-N-Cbz-6-oxo-2,3-Diphenylmorpholine
Packaging: 1g
Price: $145
Updated: 2024/03/01

TRC

Product number: O855550
Product name: (2R,3S)-(−)-N-Z-6-Oxo-2,3-diphenylmorpholine
Packaging: 10g
Price: $690
Updated: 2021/12/16

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Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties,Usage,Production

Uses

(2R,3S)-(?)-N-Z-6-Oxo-2,3-diphenylmorpholine can be used in the optimized large scale synthesis of L-m-tyrosine. Also used in the asymmetric synthesis of Fmoc-L-cyclopentylglycine.

Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Suppliers

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View Lastest Price from Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate manufacturers

Career Henan Chemical Co

Product: Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 100516-54-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95%-99%
Supply Ability: 100KG
Release date: 2019-08-29

100516-54-9, Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylateRelated Search:

Tridemorph Benzyl isocyanate Benzyl alcohol Biphenyl Moroxydine hydrochloride Moroxydine N-Carbobenzyloxyglycine Benzyl chloride Benzyl benzoate Dimethomorph Benzyl nicotinate Benzyl Ephedrine hemihydrate 3-methylmorpholine BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE (S)-(+)-2-Phenylglycinol Phenmetrazine ETHYL-N-BENZYLCARBAMATE

CIVENTICHEM CV-2652

CIVENTICHEM CV-2655

BENZYL (2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE

benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholin

Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholine-carboxylate 98%

(2R,3S)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate

(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone,98%

(2R,3S)-()-N-Z-6-oxo-2,3-diphenylMorpholine

(2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylMorpholine

(2R,3S)-N-Cbz-6-oxo-2,3- diphenylmorpholine

(2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylmorpholine 98%

Benzyl (2R,3S)-6-Oxo-2,3-diphenyl-4-morpholinecarbox ylate,99%e.e.

(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-morpholinone

(5S,6R)-4-(benzyloxycarbonyl)-5,6-diphenyl-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one

O=C(N1[C@@H](C2=CC=CC=C2)[C@@H](C3=CC=CC=C3)OC(C1)=O)OCC4=CC=CC=C4

Benzyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate

(2R, 3S) - n-benzyloxycarbonyl-2,3-diphenylmorpholine-6-one

4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2R,3S)-

Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate, 98%,

William's lactone

100516-54-9

Asymmetric Synthesis

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