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3-methylmorpholine

Product Name
3-methylmorpholine
CAS No.
42185-06-8
Chemical Name
3-methylmorpholine
Synonyms
3-methylmorpholine;Morpholine, 3-methyl-;3-Methylmorpholine 97%;3-MethylMorpholine hcl h2o
CBNumber
CB31261195
Molecular Formula
C5H11NO
Formula Weight
101.15
MOL File
42185-06-8.mol
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3-methylmorpholine Property

Boiling point:
133-134 °C
Density 
0.9591 g/cm3(Temp: 16 °C)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
9.03±0.40(Predicted)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-41
Safety Statements 
26-39
RIDADR 
UN2924
HazardClass 
3, 8
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M725213
Product name
3-Methylmorpholine
Packaging
25mg
Price
$75
Updated
2021/12/16
Oakwood
Product number
093767
Product name
3-Methylmorpholine
Purity
95%
Packaging
250mg
Price
$92
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-98
Product name
3-Methylmorpholine
Purity
97%
Packaging
1g
Price
$112
Updated
2021/12/16
AK Scientific
Product number
W6211
Product name
3-Methylmorpholine
Packaging
1g
Price
$114
Updated
2021/12/16
Matrix Scientific
Product number
074238
Product name
3-Methylmorpholine
Purity
95+%
Packaging
250mg
Price
$231
Updated
2021/12/16
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3-methylmorpholine Chemical Properties,Usage,Production

Synthesis

1268866-46-1

42185-06-8

A solution of 4-(4-methoxybenzyl)-3-methylmorpholine (7 g, 31.53 mmol, 1.00 eq.) in methanol (70 mL) was added to a 250 mL round-bottom flask under nitrogen protection. A 10% palladium-carbon catalyst (2 g) was then added. After passing hydrogen (H2), the reaction mixture was stirred in an oil bath at 50 °C overnight. Upon completion of the reaction, the solid catalyst was removed by filtration. The filtrate was concentrated under reduced pressure to give 2.1 g (66% yield) of 3-methylmorpholine as a yellow oil.LC-MS analysis: (ES, m/z): 102 [M + H]+.

References

[1] Patent: WO2011/28947, 2011, A2. Location in patent: Page/Page column 154; 157

3-methylmorpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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3-methylmorpholine Suppliers

Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
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66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
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66
ChangZhou SIDU chemical Co., Ltd.
Tel
0519-81291281 18015082300
Fax
0519-81291281
Email
siduchem@hotmail.com
Country
China
ProdList
274
Advantage
62
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Shanghai yirong biology science and technology co., ltd
Tel
18049974220
Fax
+86 (21) 51062076
Email
3060526242@qq.com
Country
China
ProdList
995
Advantage
60
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
150-2103-5486 18017383231
Fax
qq:2817624287
Email
983544897@qq.com
Country
China
ProdList
9342
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Sheepchem Co., Ltd.
Tel
+86 (21) 6715-7650
Fax
+86 (21) 6715-7651
Email
sheepchem@163.com
Country
China
ProdList
994
Advantage
60
Shanghai Raise Chemical Technology Co.,Ltd
Tel
+86-021-50935922
Fax
+86-021-33847795
Country
China
ProdList
7865
Advantage
55
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View Lastest Price from 3-methylmorpholine manufacturers

Hong Kong Tiansheng New Material Trading Co., Ltd
Product
3-Methylmorpholine 42185-06-8
Price
US $8.60/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2021-09-24
Hong Kong Tiansheng New Material Trading Co., Ltd
Product
3-Methylmorpholine 42185-06-8
Price
US $8.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000kg
Release date
2021-11-26
Hong Kong Tiansheng New Material Trading Co., Ltd
Product
3-Methylmorpholine 42185-06-8
Price
US $8.60/KG
Min. Order
1KG
Purity
98%
Supply Ability
10KG
Release date
2021-11-26