ChemicalBook > CAS DataBase List > Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Product Name
Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
CAS No.
100516-54-9
Chemical Name
Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Synonyms
William's lactone;CIVENTICHEM CV-2655;CIVENTICHEM CV-2652;(2R,3S)-()-N-Z-6-oxo-2,3-diphenylMorpholine;(2R,3S)-N-Cbz-6-oxo-2,3- diphenylmorpholine;(2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylmorpholine 98%;benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholin;Benzyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate;(2R,3S)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-morpholinone
CBNumber
CB2331294
Molecular Formula
C24H21NO4
Formula Weight
387.43
MOL File
100516-54-9.mol
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Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Property

Melting point:
205-207 °C(lit.)
alpha 
-66 º (c=5.5 in methylene chloride)
Boiling point:
583.5±50.0 °C(Predicted)
Density 
1.242±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
pka
-3.33±0.60(Predicted)
form 
Solid
color 
White
optical activity
[α]25/D 66°, c = 5.5 in methylene chloride
InChIKey
HECRUWTZAMPQOS-XZOQPEGZSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
331872
Product name
(2R,3S)-(?)-N-Z-6-oxo-2,3-diphenylmorpholine
Purity
98%
Packaging
1g
Price
$87
Updated
2023/01/07
Alfa Aesar
Product number
H60821
Product name
(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-morpholinone, 98%
Packaging
1g
Price
$99.65
Updated
2024/03/01
Cayman Chemical
Product number
30497
Product name
(2R,3S)-N-Cbz-6-oxo-2,3-Diphenylmorpholine
Packaging
250mg
Price
$44
Updated
2024/03/01
Cayman Chemical
Product number
30497
Product name
(2R,3S)-N-Cbz-6-oxo-2,3-Diphenylmorpholine
Packaging
500mg
Price
$84
Updated
2024/03/01
Cayman Chemical
Product number
30497
Product name
(2R,3S)-N-Cbz-6-oxo-2,3-Diphenylmorpholine
Packaging
1g
Price
$145
Updated
2024/03/01
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Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties,Usage,Production

Uses

(2R,3S)-(?)-N-Z-6-Oxo-2,3-diphenylmorpholine can be used in the optimized large scale synthesis of L-m-tyrosine. Also used in the asymmetric synthesis of Fmoc-L-cyclopentylglycine.

Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate manufacturers

Career Henan Chemical Co
Product
Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 100516-54-9
Price
US $1.00/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
100KG
Release date
2019-08-29

100516-54-9, Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylateRelated Search:

Tridemorph Benzyl isocyanate Benzyl alcohol Biphenyl Moroxydine hydrochloride Moroxydine N-Carbobenzyloxyglycine Benzyl chloride Benzyl benzoate Dimethomorph Benzyl nicotinate Benzyl Ephedrine hemihydrate 3-methylmorpholine BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE (S)-(+)-2-Phenylglycinol Phenmetrazine ETHYL-N-BENZYLCARBAMATE

  • CIVENTICHEM CV-2652
  • CIVENTICHEM CV-2655
  • BENZYL (2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE
  • benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholin
  • Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholine-carboxylate 98%
  • (2R,3S)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate
  • (5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone,98%
  • (2R,3S)-()-N-Z-6-oxo-2,3-diphenylMorpholine
  • (2<I>R</I>,3<I>S</I>)-(-)-<I>N</I>-Z-6-oxo-2,3-diphenylMorpholine
  • (2R,3S)-N-Cbz-6-oxo-2,3- diphenylmorpholine
  • (2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylmorpholine 98%
  • Benzyl (2R,3S)-6-Oxo-2,3-diphenyl-4-morpholinecarbox ylate,99%e.e.
  • (5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-morpholinone
  • (5S,6R)-4-(benzyloxycarbonyl)-5,6-diphenyl-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one
  • O=C(N1[C@@H](C2=CC=CC=C2)[C@@H](C3=CC=CC=C3)OC(C1)=O)OCC4=CC=CC=C4
  • Benzyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • (2R, 3S) - n-benzyloxycarbonyl-2,3-diphenylmorpholine-6-one
  • 4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2R,3S)-
  • Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate, 98%,
  • William's lactone
  • 100516-54-9
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Heterocyclic Building Blocks
  • Morpholines
  • Chiral Building Blocks
  • Heterocyclic Building Blocks
  • Morpholines