2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

ChemicalBook > CAS DataBase List > 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Product Name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
CAS No.: 898838-07-8
Chemical Name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
Synonyms: piperidinyL;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride;Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1);2,2,6,6-tetramethylpiperidin-1-ide;lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-Tetramethylpiperidinylmagnesium chloride l;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)
CBNumber: CB32489918
Molecular Formula: C9H18Cl2LiMgN
Formula Weight: 242.4
MOL File: 898838-07-8.mol

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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Property

Density: 0.96g/mLat 25℃
Flash point:: -15°C
storage temp.: 2-8°C

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Safety

Hazard Codes: F,C
Risk Statements: 63-11-14-19-34-37-40
Safety Statements: 16-26-36/37/39-45
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 3
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 703540
Product name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity: 1.0 M in THF/toluene
Packaging: 4x25ml
Price: $184
Updated: 2024/03/01

Sigma-Aldrich

Product number: 703540
Product name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity: 1.0 M in THF/toluene
Packaging: 100ml
Price: $216
Updated: 2024/03/01

Sigma-Aldrich

Product number: 703540
Product name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity: 1.0 M in THF/toluene
Packaging: 500ml
Price: $668
Updated: 2024/03/01

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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties,Usage,Production

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Preparation Products And Raw materials

Raw materials

Preparation Products

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898838-07-8, 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complexRelated Search:

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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution

2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

piperidinyL

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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl

2,2,6,6-Tetramethylpiperidinylmagnesium chloride l

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF

2,2,6,6-tetramethylpiperidin-1-ide

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 1.0 M solution in THF

2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX

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2,2,6,6-Tetramethyl piperidinyl Mag Chloride Lithium Chloride complex 1.M in THF

898838-07-8

899938-07-8

C9H18Cl2LiMgN

C9H18Cl2MgNLi

Chemical Synthesis

Grignard Reagents

Heteroaryl

Organometallic Reagents