ChemicalBook > CAS DataBase List > 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Product Name
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
CAS No.
898838-07-8
Chemical Name
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
Synonyms
piperidinyL;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride;Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1);2,2,6,6-tetramethylpiperidin-1-ide;lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-tetramethylpiperidinato)magnesate lithium;2,2,6,6-Tetramethylpiperidinylmagnesium chloride l;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
CBNumber
CB32489918
Molecular Formula
C9H18Cl2LiMgN
Formula Weight
242.4
MOL File
898838-07-8.mol
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Property

Boiling point:
66°/759.8mm
Density 
0.96g/mLat 25℃
Flash point:
-15°C
storage temp. 
2-8°C
form 
liquid
InChI
InChI=1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChIKey
JHBZAAACZVPPRQ-UHFFFAOYSA-L
SMILES
[Mg+2]([N-]1C(CCCC1(C)C)(C)C)([Cl-])[Cl-].[Li+]
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Safety

Hazard Codes 
F,C
Risk Statements 
63-11-14-19-34-37-40
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
3
HazardClass 
3, 8
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
703540
Product name
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity
1.0 M in THF/toluene
Packaging
4x25ml
Price
$190
Updated
2025/07/31
Sigma-Aldrich
Product number
703540
Product name
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity
1.0 M in THF/toluene
Packaging
100ml
Price
$223
Updated
2025/07/31
Sigma-Aldrich
Product number
703540
Product name
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity
1.0 M in THF/toluene
Packaging
500ml
Price
$689
Updated
2025/07/31
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties,Usage,Production

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base

reaction suitability

reaction type: Grignard Reaction

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Preparation Products And Raw materials

Raw materials

Preparation Products

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898838-07-8, 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complexRelated Search:

2-NAPHTHYLMAGNESIUM BROMIDE 2-Thienylmagnesium bromide solution 2-METHYLBENZYLMAGNESIUM CHLORIDE 1-NAPHTHYLMAGNESIUM BROMIDE 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE 2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE Hexylmagnesium chloride 1-PROPYNYLMAGNESIUM BROMIDE 2-BUTENYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM BROMIDE N-PROPYLMAGNESIUM BROMIDE Benzylmagnesium chloride PHENYLMAGNESIUM CHLORIDE Isopropylmagnesium chloride lithium chloride complex ISOBUTYLMAGNESIUM BROMIDE

  • Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
  • 2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
  • piperidinyL
  • Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1)
  • lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride
  • Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride l
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF
  • 2,2,6,6-tetramethylpiperidin-1-ide
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 1.0 M solution in THF
  • 2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX
  • 2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX 1.0 M in THF
  • 2,2,6,6-Tetramethyl piperidinyl Mag Chloride Lithium Chloride complex 1.M in THF
  • 2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride (Complex 1.0 M in THF)
  • 2,2,6,6-tetramethylpiperidinato)magnesate lithium
  • Magnesium dichloride (2,2,6,6-tetramethylpiperidine) lithium salt
  • 898838-07-8
  • 899938-07-8
  • C9H18Cl2LiMgN
  • C9H18Cl2MgNLi
  • Chemical Synthesis
  • Grignard Reagents
  • Heteroaryl
  • Organometallic Reagents