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PHENYLMAGNESIUM CHLORIDE

Product Name
PHENYLMAGNESIUM CHLORIDE
CAS No.
100-59-4
Chemical Name
PHENYLMAGNESIUM CHLORIDE
Synonyms
Phenylmagnesiu;Chlorphenylmagnesium;chlorophenyl-magnesiu;Phenylchloromagnesium;chlorophenylmagnesium;Magnesium, chlorophenyl-;PHENYLMAGNESIUM CHLORIDE;phenylmagnessium chloride;PhenylMagnesiuM Chloride Phenylmagnesium chloride(2M THF)
CBNumber
CB5107614
Molecular Formula
C6H5ClMg
Formula Weight
136.86
MOL File
100-59-4.mol
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PHENYLMAGNESIUM CHLORIDE Property

Melting point:
89-90℃
Boiling point:
230℃ (8 Torr)
Density 
0.98 g/mL at 20 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
It reacts violently with water.
Sensitive 
Air & Moisture Sensitive
Merck 
14,7298
BRN 
3587900
InChIKey
GQONLASZRVFGHI-UHFFFAOYSA-M
CAS DataBase Reference
100-59-4(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, chlorophenyl- (100-59-4)
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Safety

Hazard Codes 
F,C
Risk Statements 
14-19-20/21/22-34-67-65-63-48/20-11-40-37
Safety Statements 
26-36/37/39-45-62-33-16
RIDADR 
UN 2924 3/PG 2
WGK Germany 
2
10
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
Hazardous Substances Data
100-59-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
224448
Product name
Phenylmagnesium chloride solution
Purity
2.0 M in THF
Packaging
8l
Price
$2460
Updated
2024/03/01
Sigma-Aldrich
Product number
224448
Product name
Phenylmagnesium chloride solution
Purity
2.0?M in THF
Packaging
18L
Price
$4730
Updated
2024/03/01
TCI Chemical
Product number
P1381
Product name
Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
Packaging
250g
Price
$130
Updated
2024/03/01
Strem Chemicals
Product number
93-1269
Product name
Phenylmagnesium chloride, 2-3M in THF
Packaging
0.25mole
Price
$44
Updated
2023/06/20
Strem Chemicals
Product number
93-1269
Product name
Phenylmagnesium chloride, 2-3M in THF
Packaging
1mole
Price
$123
Updated
2023/06/20
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PHENYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

yellowish-brown to dark brown solution

Uses

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.

Definition

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.

General Description

This product has been enhanced for energy efficiency.

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PHENYLMAGNESIUM CHLORIDE Suppliers

Gansu Gefu Chemical Technology Co.,Ltd
Tel
13951998329
Fax
0571-56059825 (fandachem@gmail.com)
Email
sjg9988@126.com
Country
China
ProdList
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55
Shaoxing youli biology science and technology co., ltd
Tel
0575-82148339 15967563458
Email
704090688@qq.com
Country
China
ProdList
28
Advantage
58
Nanjing Freehoo Chemical Technology Co., Ltd.
Tel
025-57798086 13951998329
Fax
025-57798086
Email
sjg9988@126.com
Country
China
ProdList
37
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
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View Lastest Price from PHENYLMAGNESIUM CHLORIDE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
PHENYLMAGNESIUM CHLORIDE 100-59-4
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
PHENYLMAGNESIUM CHLORIDE 100-59-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
PHENYLMAGNESIUM CHLORIDE 100-59-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

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  • 100-59-4
  • C6H5MgCl
  • C6H5ClMg
  • C6Cl1H5Mg1
  • Aryl
  • Organometallic Reagents
  • Grignard Reagents & Alkyl Metals
  • Grignard Reagents
  • Classes of Metal Compounds
  • Mg (Magnesium) Compounds