PHENYLMAGNESIUM CHLORIDE Property

Melting point:

89-90℃

Boiling point:

230℃ (8 Torr)

Density 

0.98 g/mL at 20 °C

Flash point:

1 °F

storage temp. 

2-8°C

Water Solubility 

It reacts violently with water.

Sensitive 

Air & Moisture Sensitive

Merck 

14,7298

BRN 

3587900

InChIKey

GQONLASZRVFGHI-UHFFFAOYSA-M

CAS DataBase Reference

100-59-4(CAS DataBase Reference)

EPA Substance Registry System

Magnesium, chlorophenyl- (100-59-4)

Safety

Hazard Codes 

F,C

Risk Statements 

14-19-20/21/22-34-67-65-63-48/20-11-40-37

Safety Statements 

26-36/37/39-45-62-33-16

RIDADR 

UN 2924 3/PG 2

WGK Germany 

2

F 

10

TSCA 

Yes

HazardClass 

8

PackingGroup 

II

HS Code 

29319090

Hazardous Substances Data

100-59-4(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

PHENYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

yellowish-brown to dark brown solution

Uses

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl₃) in the rechargeable magnesium batteries.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.

Definition

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.

General Description

This product has been enhanced for energy efficiency.