ChemicalBook > CAS DataBase List > PHENYLMAGNESIUM CHLORIDE

PHENYLMAGNESIUM CHLORIDE

Product Name
PHENYLMAGNESIUM CHLORIDE
CAS No.
100-59-4
Chemical Name
PHENYLMAGNESIUM CHLORIDE
Synonyms
Phenylmagnesiu;Chlorphenylmagnesium;chlorophenyl-magnesiu;Phenylchloromagnesium;chlorophenylmagnesium;Magnesium, chlorophenyl-;PHENYLMAGNESIUM CHLORIDE;phenylmagnessium chloride;PhenylMagnesiuM Chloride Phenylmagnesium chloride(2M THF)
CBNumber
CB5107614
Molecular Formula
C6H5ClMg
Formula Weight
136.86
MOL File
100-59-4.mol
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PHENYLMAGNESIUM CHLORIDE Property

Melting point:
89-90℃
Boiling point:
230℃ (8 Torr)
Density 
0.98 g/mL at 20 °C
Flash point:
1 °F
storage temp. 
2-8°C
form 
solution
Water Solubility 
It reacts violently with water.
Sensitive 
Air & Moisture Sensitive
Merck 
14,7298
BRN 
3587900
InChI
InChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChIKey
GQONLASZRVFGHI-UHFFFAOYSA-M
SMILES
C1([Mg]Cl)C=CC=CC=1
CAS DataBase Reference
100-59-4(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, chlorophenyl- (100-59-4)
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Safety

Hazard Codes 
F,C
Risk Statements 
14-19-20/21/22-34-67-65-63-48/20-11-40-37
Safety Statements 
26-36/37/39-45-62-33-16
RIDADR 
UN 2924 3/PG 2
WGK Germany 
2
F 
10
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
Hazardous Substances Data
100-59-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
224448
Product name
Phenylmagnesium chloride solution
Purity
2.0 M in THF
Packaging
8l
Price
$2540
Updated
2025/07/31
Sigma-Aldrich
Product number
224448
Product name
Phenylmagnesium chloride solution
Purity
2.0?M in THF
Packaging
18L
Price
$4880
Updated
2025/07/31
TCI Chemical
Product number
P1381
Product name
Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
Packaging
250g
Price
$130
Updated
2025/07/31
Strem Chemicals
Product number
93-1269
Product name
Phenylmagnesium chloride, 2-3M in THF
Packaging
0.25mole
Price
$44
Updated
2023/06/20
Strem Chemicals
Product number
93-1269
Product name
Phenylmagnesium chloride, 2-3M in THF
Packaging
1mole
Price
$123
Updated
2023/06/20
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PHENYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

yellowish-brown to dark brown solution

Uses

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.

Definition

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.

General Description

This product has been enhanced for energy efficiency.

reaction suitability

reaction type: Grignard Reaction

PHENYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

5-METHYL-2-NITROPHENYLBORONIC ACID 4-BROMO-2-NITROPHENYLBORONIC ACID 4-METHOXY-2-NITROPHENYLBORONIC ACID 4-Phenylpyridine 5-CYANO-2-NITROPHENYLBORONIC ACID 5-METHOXY-2-NITROPHENYLBORONIC ACID 4-FLUORO-2-NITROPHENYLBORONIC ACID 5-(BROMOMETHYL)-2-NITROPHENYLBORONIC ACID
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PHENYLMAGNESIUM CHLORIDE Suppliers

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View Lastest Price from PHENYLMAGNESIUM CHLORIDE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
PHENYLMAGNESIUM CHLORIDE 100-59-4
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
PHENYLMAGNESIUM CHLORIDE 100-59-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
PHENYLMAGNESIUM CHLORIDE 100-59-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

100-59-4, PHENYLMAGNESIUM CHLORIDERelated Search:

Phenylmagnesium bromide 2-METHYL-2-PHENYLPROPYLMAGNESIUM CHLORIDE Hexylmagnesium chloride 1,1-DIMETHYLPROPYLMAGNESIUM CHLORIDE Tetrahydrofuran Magnesium chloride P-TOLYLMAGNESIUM CHLORIDE PHENYLMAGNESIUM CHLORIDE 3 5-DIMETHYOXYPHENYLMAGNESIUM CHLORIDE 3,4-DIMETHYLPHENYLMAGNESIUM CHLORIDE M-TOLYLMAGNESIUM CHLORIDE 3-FLUORO-2-METHYLPHENYLMAGNESIUM CHLORI& O-TOLYLMAGNESIUM CHLORIDE 4-(METHYLTHIO)PHENYLMAGNESIUM CHLORIDE chloro(p-chlorophenyl)magnesium 3-[bis(trimethylsilyl)amino]phenylmagnesium chloride solution PHENYLMAGNESIUM CHLORIDE, 25% SOLNIN THF p-(2-Methoxyethyl)phenylmagnesium chloride

  • PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN
  • Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran
  • PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF
  • Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran
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  • Chlorphenylmagnesium
  • chlorophenyl-magnesiu
  • Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
  • Magnesium, chlorophenyl-
  • Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3
  • Phenylchloromagnesium
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  • PhenylMagnesiuM chloride, 25 wt% solution in tetrahydrofuran, AcroSeal 100ML
  • Phenylmagnesiu
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  • Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran, AcroSeal
  • PhenylMagnesiuM chloride, 25 wt% solution in tetrahydrofuran, AcroSeal 800ML
  • PHENYLMAGNESIUM CHLORIDE
  • chlorophenylmagnesium
  • PHENYLMAGNESIUM CHLORIDE SOLUTION &
  • PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF
  • Phenylmagnesium chloride 1M solution in THF
  • Phenylmagnesium chloride 2M solution in THF
  • Phenylmagnesium chloride 2M solution in DEE
  • Phenylmagnesium chloride 1M solution in CPME
  • PhenylMagnesiuM chloride, 2.0 M solution in THF, J&KSeal
  • PhenylMagnesiuM Chloride&nbsp
  • PhenylMagnesiuM chloride, 2M solution in CPME, AcroSeal
  • PhenylMagnesiuM Chloride (27% in Tetrahydrofur
  • PhenylMagnesiuM chloride, 1.0 M solution in THF, SpcSeal
  • PHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURANPHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURANPHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURANPHENYLMAGNESIUM CHLORIDE, 2 M, in TETRAHYDROFURAN
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  • Phenylmagnesium chloride 1M tetrahydrofuran
  • Phenylmagnesium chloride 2M tetrahydrofuran
  • Phenylmagnesium Chloride, 1.0 M in 2-MeTHF
  • Phenylmagnesium chloride(2M THF)
  • Phenylmagnesium chloride 2.0 M solution in THF
  • Phenyl Magnesium Chloride (2.0 M in THF)
  • Phenyl Magnesium Chloride (1.5 M in THF)
  • Phenylmagnesium chloride （2.0M THF）
  • Phenylmagnesium chloride, 2M in THF
  • Phenylmagnesiumchloride 2 % (in THF)
  • Phenylmagnesiumchloride 2 % (in Diethylether)
  • phenylmagnessium chloride
  • PHENYLMAGNESIUM CHLORIDE（2M chlorophenylmagnesium in THF）
  • Phenylmagnesium chloride 20% in THF / 2.0M in THF
  • 100-59-4
  • C6H5MgCl
  • C6H5ClMg
  • C6Cl1H5Mg1
  • Aryl
  • Organometallic Reagents
  • Grignard Reagents & Alkyl Metals
  • Grignard Reagents