Reactions
ChemicalBook > CAS DataBase List > Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　

Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　

Reactions
Product Name
Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　
CAS No.
944451-30-3
Chemical Name
Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　
Synonyms
Reaxys ID: 11782593;oro{(R)-(+)-5,5'-bis[di(3,5-xyL;(R)-RuCl[(p-cyMene)(DM-SEGPHOS)]Cl;[RUCL(P-CYMENE)((R)-DM-SEGPHOS)]CL;[RuCl(p-cymene)((R)-dm-segphos[R])]Cl;[RuCl(p-cymene)((R)-dm-segphos(regR))]Cl;[RuCl(p-cymene)((R)-dm-segphos(regR))]Cl [RuCl(p-cymene)((R)-dm-segphos)]Cl;Chloro[(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride;Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　;Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-dm-segphos(R))]Cl
CBNumber
CB32512467
Molecular Formula
C56H58Cl2O4P2Ru
Formula Weight
1028.980842
MOL File
944451-30-3.mol
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Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Property

Melting point:
>100°C
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Powder
color 
orange to brown
Sensitive 
air sensitive
CAS DataBase Reference
944451-30-3
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Safety

WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692417
Product name
(R)-RuCl[(p-cymene)(DM-SEGPHOS?)]Cl
Packaging
50mg
Price
$30.5
Updated
2024/03/01
Sigma-Aldrich
Product number
692417
Product name
(R)-RuCl[(p-cymene)(DM-SEGPHOS?)]Cl
Packaging
100mg
Price
$54.9
Updated
2023/06/20
TCI Chemical
Product number
R0156
Product name
[RuCl(p-cymene)((R)-dm-segphos[R])]Cl
Packaging
200mg
Price
$64
Updated
2024/03/01
TCI Chemical
Product number
R0156
Product name
[RuCl(p-cymene)((R)-dm-segphos[R])]Cl
Packaging
1g
Price
$213
Updated
2024/03/01
Strem Chemicals
Product number
44-0098
Product name
Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-dm-segphos(R))]Cl
Packaging
250mg
Price
$64
Updated
2024/03/01
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Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Chemical Properties,Usage,Production

Reactions

Ruthenium catalyst used for the asymmetric hydrogenation of β-ketoimides.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Suppliers

China 13 India 1 Japan 1 United States 3 Global 18
TCI Chemicals (India) Pvt. Ltd.
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944451-30-3, Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　Related Search:

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　

  • Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　
  • (R)-RuCl[(p-cyMene)(DM-SEGPHOS)]Cl
  • [RuCl(p-cymene)((R)-dm-segphos(regR))]Cl
  • [RUCL(P-CYMENE)((R)-DM-SEGPHOS)]CL
  • Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-dm-segphos(R))]Cl
  • [RuCl(p-cymene)((R)-dm-segphos[R])]Cl
  • [RuCl(p-cymene)((R)-dm-segphos(regR))]Cl [RuCl(p-cymene)((R)-dm-segphos)]Cl
  • Reaxys ID: 11782593
  • oro{(R)-(+)-5,5'-bis[di(3,5-xyL
  • Chloro[(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride
  • 944451-30-3
  • C56H58ClO4P2RuCl
  • C56H58ClO4P2Ru