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ChemicalBook > CAS DataBase List > Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)

Reactions
Product Name
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
CAS No.
174813-82-2
Chemical Name
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
Synonyms
[(R,R)-TsDPEN-Ru(Mesitylene)Cl];Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II);Chloro[(1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II);[(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(mesitylene)ruthenium(II);Chloro[[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II);Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min;RuCl[(R,R)-Tsdpen(mesitylene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II);[R-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]ruthenium;Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(R,R)-Tsdpen(Mesitylene);N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5- trimethylbenzene]-ruthenium
CBNumber
CB32512487
Molecular Formula
C30H30ClN2O3RuS-
Formula Weight
635.1588
MOL File
174813-82-2.mol
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Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Property

Melting point:
241-249°C
storage temp. 
2-8°C
form 
Powder
color 
orange
Sensitive 
air sensitive
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Safety

WGK Germany 
3
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
708682
Product name
RuCl[(R,R)-TsDPEN](mesitylene)
Purity
90%
Packaging
500mg
Price
$49.6
Updated
2024/03/01
TCI Chemical
Product number
R0127
Product name
RuCl[(R,R)-Tsdpen](mesitylene)
Purity
>90%(HPLC)
Packaging
200mg
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
R0127
Product name
RuCl[(R,R)-Tsdpen](mesitylene)
Purity
>90%(HPLC)
Packaging
1g
Price
$162
Updated
2024/03/01
Strem Chemicals
Product number
44-0154
Product name
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
Packaging
250mg
Price
$53
Updated
2024/03/01
Strem Chemicals
Product number
44-0154
Product name
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
Packaging
1g
Price
$158
Updated
2024/03/01
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Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Chemical Properties,Usage,Production

Reactions

Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture.

Uses

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

  • (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
  • Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Suppliers

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View Lastest Price from Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) manufacturers

Career Henan Chemical Co
Product
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) 174813-82-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-03-05

174813-82-2, Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)Related Search:

CHROMIUM(II) CHLORIDE HEXAAMMINENICKEL(II) CHLORIDE GADOLINIUM CHLORIDE NEODYMIUM CHLORIDE Mesitylene Chloro[tri(p-tolyl)phosphine]gold(I),97% XantPhos-Pd-G2 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl BrettPhosPalladacycle Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro[tri(o-tolyl)phosphine]gold(I) (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)chloro(cinnamyl)palladate(II) CHLORO(TRIS(PARA-TRIFLUOROMETHYLPHENYL)&

  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(<br />mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
  • Chloro[[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II)
  • Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(R,R)-Tsdpen(Mesitylene)
  • [(R,R)-TsDPEN-Ru(Mesitylene)Cl]
  • [R-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]ruthenium
  • Chloro[(1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II)
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II),min.90%RuCl[(R,R)-Tsdpen(mesitylene),S)-Tsdpen](mesitylene)
  • Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(mesitylene)ruthenium(II)
  • N-[(1R,2R)-2-(Amino-kN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro [(1,2,3,4,5,6-n)-1,3,5-trimethylbenzene]-ruthenium
  • RuCl[(R,R)-Tsdpen(mesitylene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II)
  • N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5- trimethylbenzene]-ruthenium
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min
  • 174813-82-2
  • C30H33ClN2O2RuS
  • Ru
  • organometallic complex