Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

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Product Name: Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
CAS No.: 228120-95-4
Chemical Name: Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Synonyms: (S)-RuCl[(p-cymene)(T-BINAP)]Cl;[RuCl(p-cymene)((S)-tolbinap)]Cl;-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((S)-tolbinap)]Cl，95%
CBNumber: CB81181041
Molecular Formula: C58H52Cl2P2Ru
Formula Weight: 982.97
MOL File: 228120-95-4.mol

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Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Property

Melting point:: >100°C
storage temp.: 2-8°C
Water Solubility: Insoluble in water
form: solid
color: yellow to dark brown
Sensitive: air sensitive

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Safety

WGK Germany: 3
HS Code: 2843.90.0000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692964
Product name: (S)-RuCl[(p-cymene)(T-BINAP)]Cl
Packaging: 500mg
Price: $51.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 692964
Product name: (S)-RuCl[(p-cymene)(T-BINAP)]Cl
Packaging: 100mg
Price: $32.9
Updated: 2023/06/20

TCI Chemical

Product number: R0149
Product name: [RuCl(p-cymene)((S)-tolbinap)]Cl
Packaging: 200mg
Price: $50
Updated: 2024/03/01

TCI Chemical

Product number: R0149
Product name: [RuCl(p-cymene)((S)-tolbinap)]Cl
Packaging: 1g
Price: $162
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0089
Product name: Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl
Packaging: 250mg
Price: $53
Updated: 2024/03/01

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Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chemical Properties,Usage,Production

Reactions

1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
2. Ligand for palladium-catalyzed α-arylation of ketones.
3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
5. Enantioselective conjugate reduction of lactones and lactams.
6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
7. Catalytic Aldol reaction to ketones.
8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
11. Rhodium-catalyzed cross cyclotrimerization.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Suppliers

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View Lastest Price from Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride manufacturers

Career Henan Chemical Co

Product: Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride 228120-95-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

228120-95-4, Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chlorideRelated Search:

Chloro[tri(p-tolyl)phosphine]gold(I),97% XantPhos-Pd-G2 (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl BrettPhosPalladacycle Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro[tri(o-tolyl)phosphine]gold(I) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)chloro(cinnamyl)palladate(II) CHLORO(TRIS(PARA-TRIFLUOROMETHYLPHENYL)& (R)-(+)-TolBINAP 2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

(S)-RuCl[(p-cymene)(T-BINAP)]Cl

[RuCl(p-cymene)((S)-tolbinap)]Cl

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl

-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((S)-tolbinap)]Cl，95%

228120-95-4

C58H54ClP2RuCl8722

Ru