Lithium difluoro(oxalato)borate(1-)

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Lithium difluoro(oxalato)borate(1-)

Appearance

Product Name: Lithium difluoro(oxalato)borate(1-)
CAS No.: 409071-16-5
Chemical Name: Lithium difluoro(oxalato)borate(1-)
Synonyms: LiDFOB;LIODFB;Lithium difluoro(oxalato)borate;LIFOB;Lithium Difluoro(oxalato)borate (LiODFB);LithiuM difluoro oxalate borate;LithiuM Oxalyldifluoroborate;LIF2OB;LiFBOB;Lithium difluoro
CBNumber: CB32554322
Molecular Formula: C2BF2O4.Li
Formula Weight: 143.76
MOL File: 409071-16-5.mol

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Lithium difluoro(oxalato)borate(1-) Property

Melting point:: 265-271°C
Boiling point:: 275.3℃ at 102kPa
Density: 2.01-2.065g/cm3 at 20℃
vapor pressure: 0.003Pa at 20℃
storage temp.: Inert atmosphere,Room Temperature
solubility: Water (Slightly)
form: powder
color: White to Off-White
InChI: InChI=1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1
InChIKey: MEDDCIKGDMDORY-UHFFFAOYSA-N
SMILES: [F-][B+3]1([O-]C(=O)C(=O)[O-]1)[F-].[Li+]
LogP: -1.18--1.1 at 25℃ and pH2-8

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 774138
Product name: Lithium difluoro(oxalato)borate
Packaging: 25g
Price: $352
Updated: 2024/03/01

TRC

Product number: L468890
Product name: Lithium difluoro(oxalato)borate
Packaging: 5g
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 167659
Product name: Lithium difluoro(oxalato)?borate
Packaging: 25g
Price: $445
Updated: 2021/12/16

Matrix Scientific

Product number: 167659
Product name: Lithium difluoro(oxalato)?borate
Packaging: 100g
Price: $885
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 59509
Product name: Lithium difluoro(oxalato)borate
Packaging: 10g
Price: $2000
Updated: 2021/12/16

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Lithium difluoro(oxalato)borate(1-) Chemical Properties,Usage,Production

Appearance

White Solid

Uses

LiODFB is used as a thermally stable novel salt and an electrolytic additive for lithium-ion batteries. It facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode during the fabrication of the cell. It substantially enhances the cyclic performance, capacity and power retention of the electrochemical system.

Uses

Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. Lithium difluorooxalatoborate can be used as a film-forming additive in the electrolyte of lithium batteries or replace lithium hexafluorophosphate as a conductive salt.

General Description

This product has been enhanced for energy efficiency.

Advantages

lithium difluoro(oxalato)borate(1-), a hybrid salt of lithium bis(oxalate)borate(LiBOB) and lithium tetrafluoroborate(LiBF4), possesses beneficial properties of both parent anions. These merits include 1) a relatively high ionic conductivity over a wide temperature range, 2) the ability to not only support metallic lithium cycling reversibly on the surface of a copper anode current collector but also passivate the aluminum cathode current collector at high voltage, 3) the active formation of a SEI layer, and 4) the possibility to increase battery safety protection and overcharge tolerance[1].

References

[1] Hongming Zhou. “Synthesis of lithium difluoro(oxalate)borate (LiODFB), phase diagram and ions coordination of LiODFB in dimethyl carbonate.” Journal of Central South University 25 1 (2018): 550–560.

Lithium difluoro(oxalato)borate(1-) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Lithium difluoro(oxalato)borate(1-) manufacturers

hebei hongtan Biotechnology Co., Ltd

Product: Lithium difluoro(oxalato)borate(1-) 409071-16-5
Price: US $30.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 2000kg
Release date: 2024-03-25

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Lithium difluoro(oxalato)borate(1-) 409071-16-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-21

Hebei Yanxi Chemical Co., Ltd.

Product: Lithium difluoro(oxalato)borate(1-) 409071-16-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-11-27

409071-16-5, Lithium difluoro(oxalato)borate(1-)Related Search:

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