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ChemicalBook > CAS DataBase List > Lithium difluoro(oxalato)borate(1-)

Lithium difluoro(oxalato)borate(1-)

Appearance
Product Name
Lithium difluoro(oxalato)borate(1-)
CAS No.
409071-16-5
Chemical Name
Lithium difluoro(oxalato)borate(1-)
Synonyms
LiDFOB;LIODFB;Lithium difluoro(oxalato)borate;LIFOB;Lithium Difluoro(oxalato)borate (LiODFB);LithiuM difluoro oxalate borate;LithiuM Oxalyldifluoroborate;LIF2OB;LiFBOB;Lithium difluoro
CBNumber
CB32554322
Molecular Formula
C2BF2O4.Li
Formula Weight
143.76
MOL File
409071-16-5.mol
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Lithium difluoro(oxalato)borate(1-) Property

Melting point:
265-271°C
Boiling point:
275.3℃ at 102kPa
Density 
2.01-2.065g/cm3 at 20℃
vapor pressure 
0.003Pa at 20℃
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Water (Slightly)
form 
powder
color 
White to Off-White
InChI
InChI=1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1
InChIKey
MEDDCIKGDMDORY-UHFFFAOYSA-N
SMILES
[F-][B+3]1([O-]C(=O)C(=O)[O-]1)[F-].[Li+]
LogP
-1.18--1.1 at 25℃ and pH2-8
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
774138
Product name
Lithium difluoro(oxalato)borate
Packaging
25g
Price
$352
Updated
2024/03/01
TRC
Product number
L468890
Product name
Lithium difluoro(oxalato)borate
Packaging
5g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
2360EC
Product name
Lithium difluoro(oxalato)borate
Packaging
100g
Price
$296
Updated
2021/12/16
Matrix Scientific
Product number
167659
Product name
Lithium difluoro(oxalato)?borate
Packaging
25g
Price
$445
Updated
2021/12/16
Matrix Scientific
Product number
167659
Product name
Lithium difluoro(oxalato)?borate
Packaging
100g
Price
$885
Updated
2021/12/16
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Lithium difluoro(oxalato)borate(1-) Chemical Properties,Usage,Production

Appearance

White Solid

Uses

LiODFB is used as a thermally stable novel salt and an electrolytic additive for lithium-ion batteries. It facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode during the fabrication of the cell. It substantially enhances the cyclic performance, capacity and power retention of the electrochemical system.

Uses

Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. Lithium difluorooxalatoborate can be used as a film-forming additive in the electrolyte of lithium batteries or replace lithium hexafluorophosphate as a conductive salt.

General Description

This product has been enhanced for energy efficiency.

Advantages

lithium difluoro(oxalato)borate(1-), a hybrid salt of lithium bis(oxalate)borate(LiBOB) and lithium tetrafluoroborate(LiBF4), possesses beneficial properties of both parent anions. These merits include 1) a relatively high ionic conductivity over a wide temperature range, 2) the ability to not only support metallic lithium cycling reversibly on the surface of a copper anode current collector but also passivate the aluminum cathode current collector at high voltage, 3) the active formation of a SEI layer, and 4) the possibility to increase battery safety protection and overcharge tolerance[1].

References

[1] Hongming Zhou. “Synthesis of lithium difluoro(oxalate)borate (LiODFB), phase diagram and ions coordination of LiODFB in dimethyl carbonate.” Journal of Central South University 25 1 (2018): 550–560.

Lithium difluoro(oxalato)borate(1-) Preparation Products And Raw materials

Raw materials

Preparation Products

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Lithium difluoro(oxalato)borate(1-) Suppliers

Hubei Bojie Biotechnology Co., Ltd
Tel
0713-0713-2060728 15629612610
Email
825477621@qq.com
Country
China
ProdList
445
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58
Shanghai demo pharmaceutical technology co., LTD
Tel
400-0217337 13341686687
Fax
021-50182339
Email
2355568894@qq.com
Country
China
ProdList
42
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58
Hangzhou Jinghao Biotechnology Co., LTD
Tel
17513242016 17513242016
Fax
QQ:1576861551
Email
1576861551@qq.com
Country
China
ProdList
2800
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58
Suzhou yacoo science co.,Ltd
Tel
0512-87182056 13451648594
Fax
0512-87182056
Email
sales@yacoo.com.cn
Country
China
ProdList
4578
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58
Hebei Dj Yan Chemical Co., Ltd.
Tel
17531190177
Fax
QQ:672648158
Email
peter@yan-xi.com
Country
China
ProdList
459
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58
Shijiazhuang Jianxin Biotechnology Co., LTD
Tel
0311-1906231-3169 19062313169
Email
19062313169@163.com
Country
China
ProdList
281
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58
Zhengzhou Fluorescence Laboratory Equipment Co., Ltd
Tel
0371-86628211 13698823211
Email
381946309@qq.com
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China
ProdList
17
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58
Tianjin Rongshen Chemical Co., Ltd
Tel
18317763565 18317763565
Email
18317763565@163.com
Country
China
ProdList
10187
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58
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
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55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
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View Lastest Price from Lithium difluoro(oxalato)borate(1-) manufacturers

hebei hongtan Biotechnology Co., Ltd
Product
Lithium difluoro(oxalato)borate(1-) 409071-16-5
Price
US $30.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2024-03-25
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Lithium difluoro(oxalato)borate(1-) 409071-16-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-21
Hebei Yanxi Chemical Co., Ltd.
Product
Lithium difluoro(oxalato)borate(1-) 409071-16-5
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-27

409071-16-5, Lithium difluoro(oxalato)borate(1-)Related Search:


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