ChemicalBook > CAS DataBase List > Allyltributyltin

Allyltributyltin

Product Name
Allyltributyltin
CAS No.
24850-33-7
Chemical Name
Allyltributyltin
Synonyms
ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;Allyltributyltin(Ⅳ)
CBNumber
CB3257937
Molecular Formula
C15H32Sn
Formula Weight
331.12
MOL File
24850-33-7.mol
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Allyltributyltin Property

Melting point:
134-135 °C
Boiling point:
88-92 °C0.2 mm Hg(lit.)
Density 
1.068 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.486(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear colorless
Specific Gravity
1.068
Water Solubility 
Immiscible with water.
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
Sensitive 
Air Sensitive
BRN 
3588340
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability:
Air Sensitive
InChIKey
YLGRTLMDMVAFNI-UHFFFAOYSA-N
CAS DataBase Reference
24850-33-7(CAS DataBase Reference)
NIST Chemistry Reference
Allyltributyltin(24850-33-7)
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Safety

Hazard Codes 
T,N
Risk Statements 
21-25-36/38-48/23/25-50/53-23/24/25
Safety Statements 
35-36/37/39-45-60-61-28-27-26
RIDADR 
UN 2788 6.1/PG 2
WGK Germany 
3
F 
13
TSCA 
No
HazardClass 
6.1
PackingGroup 
II
HS Code 
29319019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
271411
Product name
Allyltributylstannane
Purity
97%
Packaging
5g
Price
$62.7
Updated
2024/03/01
Sigma-Aldrich
Product number
271411
Product name
Allyltributylstannane
Purity
97%
Packaging
25g
Price
$136
Updated
2024/03/01
Alfa Aesar
Product number
L14087
Product name
Allyltri-n-butyltin, 97%
Packaging
5g
Price
$39.6
Updated
2023/06/20
Alfa Aesar
Product number
L14087
Product name
Allyltri-n-butyltin, 97%
Packaging
25g
Price
$136
Updated
2023/06/20
Sigma-Aldrich
Product number
271411
Product name
Allyltributylstannane
Purity
97%
Packaging
100g
Price
$290
Updated
2024/03/01
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Allyltributyltin Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

Purification Methods

A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]

Allyltributyltin Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Allyltributyltin manufacturers

Nanjing Kaitian Chemical Co., LTD
Product
Allyltributyltin 24850-33-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1 ton
Release date
2022-12-06
Career Henan Chemical Co
Product
Allyltributyltin 24850-33-7
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-08

24850-33-7, AllyltributyltinRelated Search:

Allyl chloride Tributyltin chloride Diallylamine Allyl bromide Sodium allylsulfonate Allyl glycidyl ether ALLYLOXY-T-BUTYLDIMETHYLSILANE ALLYLOXYTRIMETHYLSILANE POTASSIUM ALLYLTRIFLUOROBORATE Allyl methyl sulfide Allyltrimethylsilane allyltrimethylammonium chloride Allyltriphenylphosphonium bromide 3-Allyloxy-2-Hydroxy-1-Propane,Sodium Salt Allyltrimethoxysilane ALLYLTRIS(TRIMETHYLSILOXY)SILANE ALLYLTRIISOPROPYLSILANE ALLYLTRIETHOXYSILANE

  • Stannane, tributyl-2-propenyl-
  • ALLYLTRIBUTYLSTANNANE
  • ALLYLTRIBUTYLTIN
  • ALLYLTRIBUTYLTIN(IV)
  • ALLYLTRI-N-BUTYLTIN
  • TRIBUTYL-2-PROPENYLSTANNANE
  • 3-(Tributylstannyl)prop-1-ene
  • Allytri-N-Butyltin
  • Allyltri-n-butyltin,97%
  • (2-Propenyl)tributylstannane
  • 2-Propenyltributylstannane
  • Tributylallylstannane
  • Allyltributyltin,97%
  • Allyltributyltin(Ⅳ)
  • allyitri－n－butyltin
  • allyltri-n-butylstannane
  • tri-n-butyl-2-propenylstannane
  • Allyltributylstannane 97%
  • The threebutyltinpropenyl
  • Allyltributyltin, 97% 1GR
  • (Prop-2-en-1-yl)tributyl stannane, 3-(Tributylstannyl)prop-1-ene
  • Stannane, tributyl-2-propen-1-yl-
  • Allyltributyltin ISO 9001：2015 REACH
  • SKL1093
  • tributyl(prop-2-enyl)stannane
  • ributyl(prop-2-enyl)stannane
  • Allyl Tri n-butyl tin /stannane
  • 24850-33-7
  • CH2CHCH2SnCH2CH2CH2CH33
  • Classes of Metal Compounds
  • Alkyl Metals
  • Sn (Tin) Compounds
  • Typical Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Organotin
  • Organotins
  • Organometallic Reagents
  • Chemical Synthesis
  • Organometallic Reagents
  • Alkyl Metals
  • Sn (Tin) Compounds
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
  • Organometallic Reagents
  • Organotin
  • Organotins
  • Stannanes