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Allyltriphenylphosphonium bromide

Product Name
Allyltriphenylphosphonium bromide
CAS No.
1560-54-9
Chemical Name
Allyltriphenylphosphonium bromide
Synonyms
TAL;triphenyl(prop-2-en-1-yl)phosphaniuM broMide;NSC 59815;NSC 110609;allyltriphenylphosphonium;allyltriphenyl-phosphoniubromide;Allytriphenylphosphonium bromide;allyl triphenylphosphine bromide;Triphenylallylphosphonium bromide;ALLYLTRIPHENYLPHOSPHONIUM BROMIDE
CBNumber
CB4381501
Molecular Formula
C21H20BrP
Formula Weight
383.26
MOL File
1560-54-9.mol
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Allyltriphenylphosphonium bromide Property

Melting point:
222-225 °C (lit.)
storage temp. 
Sealed in dry,Room Temperature
form 
Powder
color 
White
Water Solubility 
decomposes
Sensitive 
Hygroscopic
BRN 
3579053
InChI
InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
InChIKey
FWYKRJUVEOBFGH-UHFFFAOYSA-M
SMILES
[P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-]
CAS DataBase Reference
1560-54-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
RTECS 
TA1843000
HS Code 
29310095
Toxicity
mouse,LD50,intravenous,22mg/kg (22mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01708,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S280178
Product name
ALLYL-TRIPHENYL-PHOSPHONIUM, BROMIDE
Purity
AldrichCPR
Packaging
25MG
Price
$29.8
Updated
2024/03/01
Sigma-Aldrich
Product number
A36603
Product name
Allyltriphenylphosphonium bromide
Purity
99%
Packaging
100g
Price
$63
Updated
2024/03/01
TCI Chemical
Product number
A1007
Product name
Allyltriphenylphosphonium Bromide
Purity
>98.0%(T)
Packaging
25g
Price
$126
Updated
2024/03/01
Alfa Aesar
Product number
A14490
Product name
Allyltriphenylphosphonium bromide, 99%
Packaging
50g
Price
$47.65
Updated
2024/03/01
Alfa Aesar
Product number
A14490
Product name
Allyltriphenylphosphonium bromide, 99%
Packaging
250g
Price
$160.65
Updated
2024/03/01
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Allyltriphenylphosphonium bromide Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes.

Preparation

Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.

Application

Reactant for:
Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene

Allyltriphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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Allyltriphenylphosphonium bromide Suppliers

Beijing Taiya Jie Technology Development Co., Ltd.
Tel
021-33690831-8001 13552411790
Fax
021-33690831
Email
postmaster@tyjchem.cn
Country
China
ProdList
1541
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Beijing VSciChem Technology Co., Ltd.
Tel
13811761079
Email
vscichem@163.com
Country
China
ProdList
251
Advantage
64
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View Lastest Price from Allyltriphenylphosphonium bromide manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Allyltriphenylphosphonium bromide 1560-54-9
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-15
Henan Aochuang Chemical Co.,Ltd.
Product
Allyltriphenylphosphonium bromide 1560-54-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-10
Career Henan Chemical Co
Product
Allyltriphenylphosphonium bromide 1560-54-9
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10TON
Release date
2018-12-18

1560-54-9, Allyltriphenylphosphonium bromideRelated Search:


  • TAL
  • ALLYLTRIPHENYLPHOSPHONIUM BROMIDE
  • allyltriphenyl-phosphoniubromide
  • allyltriphenylphosphonium
  • Allyltriphenylphosphoniumbromide,99%
  • Phosphonium, triphenyl-2-propenyl-, bromide
  • 2-Propenyltriphenylphosphonium bromide
  • Triphenyl(2-propenyl)phosphonium bromide
  • Triphenylallylphosphonium bromide
  • Triphenyl-prop-2-enylphosphanium bromide
  • ALLYLTRIPHENYLPHOSPHONIUM BROMIDE (TAL)
  • Allytriphenylphosphonium bromide
  • triphenyl(prop-2-en-1-yl)phosphaniuM broMide
  • ALLYLTRIPHENYLPHOSPHONIUM BROMIDE FOR SY
  • NSC 110609
  • NSC 59815
  • Allyltriphenylphosphonium bromide 99%
  • Phosphonium,triphenyl-2-propen-1-yl-, bromide
  • triphenyl(prop-2-enyl)phosphonium bromide
  • AllyltriphenylphosphoniumBromide&gt
  • allyl triphenylphosphine bromide
  • Phosphonium, triphenyl-2-propen-1-yl-, bromide (1:1)
  • triphenyl(prop-2-enyl)phosphanium
  • 1560-54-9
  • C21H20P
  • C21H20BrP
  • CH2CHCH2C6H53PBr
  • H2CCHCH2PC6H53Br
  • Wittig Reaction
  • Wittig & Horner-Emmons Reaction
  • Phosphonium Compounds
  • C-C Bond Formation
  • Synthetic Reagents
  • Wittig Reagents
  • Olefination
  • organophosphorus compound
  • Pharmaceutical Intermediates
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents