Glycidyl methacrylate
- Product Name
- Glycidyl methacrylate
- CAS No.
- 106-91-2
- Chemical Name
- Glycidyl methacrylate
- Synonyms
- 2,3-EPOXYPROPYL METHACRYLATE;oxiran-2-ylmethyl methacrylate;Glycidyl methacylate;2-Propenoicacid,2-methyl-,oxiranylmethylester;cp105;sr379;CP 105;SR-379;blemmerg;blemmergma
- CBNumber
- CB3258080
- Molecular Formula
- C7H10O3
- Formula Weight
- 142.15
- MOL File
- 106-91-2.mol
Glycidyl methacrylate Property
- Melting point:
- -52°C
- Boiling point:
- 189 °C(lit.)
- Density
- 1.075 g/mL at 20 °C
- vapor pressure
- 4.2hPa at 25℃
- refractive index
- n20/D 1.449(lit.)
- Flash point:
- 169 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Clear
- Water Solubility
- 0.5-1.0 g/100 mL at 20 ºC
- BRN
- 2506
- Stability:
- Unstable. Light sensitive. May be stabilized with around 100ppm MEHQ. Refrigerate.
- InChIKey
- VOZRXNHHFUQHIL-UHFFFAOYSA-N
- LogP
- 0.96 at 25℃
- CAS DataBase Reference
- 106-91-2(CAS DataBase Reference)
- IARC
- 2A (Vol. 125) In prep.
- NIST Chemistry Reference
- 2-Propenoic acid, 2-methyl-, oxiranylmethyl ester(106-91-2)
- EPA Substance Registry System
- Glycidyl methacrylate (106-91-2)
Safety
- Hazard Codes
- Xn,T,T+
- Risk Statements
- 20/21/22-36/38-43-60-45-68-39/26-34
- Safety Statements
- 26-28-28A-45-36/37-53-36/37/39
- RIDADR
- UN 2810 6.1/PG 3
- WGK Germany
- 2
- RTECS
- OZ4375000
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29161490
- Hazardous Substances Data
- 106-91-2(Hazardous Substances Data)
- Toxicity
- dog,LCLo,inhalation,1400mg/m3/6H (1400mg/m3),LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,National Technical Information Service. Vol. OTS0530684,
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H311Toxic in contact with skin
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
H335May cause respiratory irritation
H341Suspected of causing genetic defects
H350May cause cancer
H372Causes damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 151238
- Product name
- Glycidyl methacrylate
- Purity
- 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor
- Packaging
- 100g
- Price
- $49
- Updated
- 2024/03/01
- Product number
- 151238
- Product name
- Glycidyl methacrylate
- Purity
- 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor
- Packaging
- 5kg
- Price
- $708
- Updated
- 2024/03/01
- Product number
- M0590
- Product name
- Glycidyl Methacrylate (stabilized with MEHQ)
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $30
- Updated
- 2024/03/01
- Product number
- M0590
- Product name
- Glycidyl Methacrylate (stabilized with MEHQ)
- Purity
- >95.0%(GC)
- Packaging
- 500g
- Price
- $104
- Updated
- 2024/03/01
- Product number
- L11133
- Product name
- Glycidyl methacrylate, 97%, stab. with 100ppm 4-methoxyphenol
- Packaging
- 50g
- Price
- $34.4
- Updated
- 2024/03/01
Glycidyl methacrylate Chemical Properties,Usage,Production
Description
Glycidyl Methacrylate (GMA) is a clear, colorless liquid with a potent ester and fruity odor. It comprises a polymerizable methacrylate functional group on one end and a reactive epoxy group on the other. It is slightly miscible with water, soluble in most organic solvents, and has relatively low volatility. Its vapor is heavier than air. It copolymerizes readily with various functional groups, such as phenols, ketones, acids, and amines. The added epoxy group imparts durability, mechanical strength, optical transparency, and adhesiveness.
Chemical Properties
Glycidyl methacrylate (GMA) is a colorless liquid with a fruity odor. Floats on water. (USCG, 1999)
Glycidyl methacrylate is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.
Uses
Glycidyl methacrylate is commonly used as a monomer for the preparation of epoxy resins. It is also used to provide epoxy functionalization to polyolefins and other acrylate resins. Further, it is also useful as an epoxy resin additive for paint coating formulations and adhesive applications.
Uses
Glycidyl methacrylate (GMA) is a common monomer used in the creation of epoxy resins. It is used to provide epoxy functionalization to polyolefins and other acrylate resins.
Glycidyl methacrylate is used in the production of polymer coatings and finishes, adhesives, plastics and elastomers.
Glycidyl methacrylate dextran has been reported to be used as a biocompatible hydrogel. In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported. GMA may also be grafted onto polypropylene.
Preparation
Glycidyl methacrylate is produced from methacrylic acid and glycidol. Glycidol contain both epoxide and alcohol functional groups.It is an enoate ester and an epoxide. It derives from a methacrylic acid and a glycidol.
Definition
ChEBI: Glycidyl methacrylate is an enoate ester obtained by formal condensation of the carboxy group of methacrylic acid with the hydroxy group of glycidol. It is an enoate ester and an epoxide. It is functionally related to a methacrylic acid and a glycidol.
Reactions
Glycidyl methacrylate (GMA) is a kind of functional monomer. Its active vinyl and epoxy groups could be grafted with polyolefin and reacted with the polar groups such as amine, hydroxyl and carboxyl group, respectively. It can also undergo polymerization to form poly (glycidyl methacrylate).
Synthesis Reference(s)
Tetrahedron, 48, p. 5099, 1992 DOI: 10.1016/S0040-4020(01)90120-6
Synthesis, p. 1019, 1986 DOI: 10.1055/s-1986-31856
General Description
Colorless liquid with a fruity odor. Floats on water.
Air & Water Reactions
Flammable. Slightly water soluble.
Reactivity Profile
Epoxides, such as Glycidyl methacrylate, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Health Hazard
The liquid irritates eyes about as much as soap. Prolonged contact with skin produces irritation and dermatitis.
Fire Hazard
Special Hazards of Combustion Products: Irritating vapors are generated when heated
Flammability and Explosibility
Flammable
Glycidyl methacrylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Glycidyl methacrylate manufacturers
- Product
- Glycidyl methacrylate 106-91-2
- Price
- US $30.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 2000kg
- Release date
- 2024-05-15
- Product
- ISODECYL ACRYLATE 106-91-2
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99.0%
- Supply Ability
- 20 tons
- Release date
- 2024-06-05
- Product
- Glycidyl methacrylate 106-91-2
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99.5%
- Supply Ability
- 10 tons
- Release date
- 2024-04-28