ChemicalBook > CAS DataBase List > Glycidyl methacrylate

Glycidyl methacrylate

Product Name
Glycidyl methacrylate
CAS No.
106-91-2
Chemical Name
Glycidyl methacrylate
Synonyms
2,3-EPOXYPROPYL METHACRYLATE;oxiran-2-ylmethyl methacrylate;Glycidyl methacylate;2-Propenoicacid,2-methyl-,oxiranylmethylester;cp105;sr379;CP 105;SR-379;blemmerg;blemmergma
CBNumber
CB3258080
Molecular Formula
C7H10O3
Formula Weight
142.15
MOL File
106-91-2.mol
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Glycidyl methacrylate Property

Melting point:
-52°C
Boiling point:
189 °C(lit.)
Density 
1.075 g/mL at 20 °C
vapor pressure 
4.2hPa at 25℃
refractive index 
n20/D 1.449(lit.)
Flash point:
169 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear
Water Solubility 
0.5-1.0 g/100 mL at 20 ºC
BRN 
2506
Stability:
Unstable. Light sensitive. May be stabilized with around 100ppm MEHQ. Refrigerate.
InChIKey
VOZRXNHHFUQHIL-UHFFFAOYSA-N
LogP
0.96 at 25℃
CAS DataBase Reference
106-91-2(CAS DataBase Reference)
IARC
2A (Vol. 125) In prep.
NIST Chemistry Reference
2-Propenoic acid, 2-methyl-, oxiranylmethyl ester(106-91-2)
EPA Substance Registry System
Glycidyl methacrylate (106-91-2)
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Safety

Hazard Codes 
Xn,T,T+
Risk Statements 
20/21/22-36/38-43-60-45-68-39/26-34
Safety Statements 
26-28-28A-45-36/37-53-36/37/39
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
2
RTECS 
OZ4375000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29161490
Hazardous Substances Data
106-91-2(Hazardous Substances Data)
Toxicity
dog,LCLo,inhalation,1400mg/m3/6H (1400mg/m3),LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,National Technical Information Service. Vol. OTS0530684,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H335May cause respiratory irritation

H341Suspected of causing genetic defects

H350May cause cancer

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
151238
Product name
Glycidyl methacrylate
Purity
97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor
Packaging
100g
Price
$49
Updated
2024/03/01
Sigma-Aldrich
Product number
151238
Product name
Glycidyl methacrylate
Purity
97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor
Packaging
5kg
Price
$708
Updated
2024/03/01
TCI Chemical
Product number
M0590
Product name
Glycidyl Methacrylate (stabilized with MEHQ)
Purity
>95.0%(GC)
Packaging
25g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
M0590
Product name
Glycidyl Methacrylate (stabilized with MEHQ)
Purity
>95.0%(GC)
Packaging
500g
Price
$104
Updated
2024/03/01
Alfa Aesar
Product number
L11133
Product name
Glycidyl methacrylate, 97%, stab. with 100ppm 4-methoxyphenol
Packaging
50g
Price
$34.4
Updated
2024/03/01
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Glycidyl methacrylate Chemical Properties,Usage,Production

Description

Glycidyl Methacrylate (GMA) is a clear, colorless liquid with a potent ester and fruity odor. It comprises a polymerizable methacrylate functional group on one end and a reactive epoxy group on the other. It is slightly miscible with water, soluble in most organic solvents, and has relatively low volatility. Its vapor is heavier than air. It copolymerizes readily with various functional groups, such as phenols, ketones, acids, and amines. The added epoxy group imparts durability, mechanical strength, optical transparency, and adhesiveness.

Chemical Properties

Glycidyl methacrylate (GMA) is a colorless liquid with a fruity odor. Floats on water. (USCG, 1999)

Glycidyl methacrylate is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.

Uses

Glycidyl methacrylate is commonly used as a monomer for the preparation of epoxy resins. It is also used to provide epoxy functionalization to polyolefins and other acrylate resins. Further, it is also useful as an epoxy resin additive for paint coating formulations and adhesive applications.

Uses

Glycidyl methacrylate (GMA) is a common monomer used in the creation of epoxy resins. It is used to provide epoxy functionalization to polyolefins and other acrylate resins.
Glycidyl methacrylate is used in the production of polymer coatings and finishes, adhesives, plastics and elastomers.
Glycidyl methacrylate dextran has been reported to be used as a biocompatible hydrogel. In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported. GMA may also be grafted onto polypropylene.

Preparation

Glycidyl methacrylate is produced from methacrylic acid and glycidol. Glycidol contain both epoxide and alcohol functional groups.It is an enoate ester and an epoxide. It derives from a methacrylic acid and a glycidol.

Definition

ChEBI: Glycidyl methacrylate is an enoate ester obtained by formal condensation of the carboxy group of methacrylic acid with the hydroxy group of glycidol. It is an enoate ester and an epoxide. It is functionally related to a methacrylic acid and a glycidol.

Reactions

Glycidyl methacrylate (GMA) is a kind of functional monomer. Its active vinyl and epoxy groups could be grafted with polyolefin and reacted with the polar groups such as amine, hydroxyl and carboxyl group, respectively. It can also undergo polymerization to form poly (glycidyl methacrylate).

Synthesis Reference(s)

Tetrahedron, 48, p. 5099, 1992 DOI: 10.1016/S0040-4020(01)90120-6
Synthesis, p. 1019, 1986 DOI: 10.1055/s-1986-31856

General Description

Colorless liquid with a fruity odor. Floats on water.

Air & Water Reactions

Flammable. Slightly water soluble.

Reactivity Profile

Epoxides, such as Glycidyl methacrylate, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Health Hazard

The liquid irritates eyes about as much as soap. Prolonged contact with skin produces irritation and dermatitis.

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors are generated when heated

Flammability and Explosibility

Flammable

Glycidyl methacrylate Preparation Products And Raw materials

Raw materials

SODIUM METHACRYLATE Sodium hydroxide Epichlorohydrin Methacrylic acid

Preparation Products

water-soluble organosilicone softening agent
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Glycidyl methacrylate Suppliers

Americas 1 Belgium 3 Canada 1 CHINA 472 Europe 5 France 1 Germany 9 India 20 Japan 11 Russia 1 South Korea 3 Spain 1 Switzerland 3 The Netherlands 2 United Kingdom 8 United States 44 USA 1 Global 586
Pure Chemistry Scientific Inc.
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View Lastest Price from Glycidyl methacrylate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Glycidyl methacrylate 106-91-2
Price
US $99.00-66.00/kg
Min. Order
0.0010000000474974513kg
Purity
99%
Supply Ability
5000
Release date
2024-08-19
Hebei Weibang Biotechnology Co., Ltd
Product
Glycidyl methacrylate 106-91-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-22
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Glycidyl Methacrylate 106-91-2
Price
US $120.00-65.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-29

106-91-2, Glycidyl methacrylateRelated Search:

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