2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
Uses- Product Name
- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
- CAS No.
- 69563-88-8
- Chemical Name
- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
- Synonyms
- HFBAPP;6FBAPP;4-BDAF;BAPOFP;BIS-AF-A;GI 530159;isbenzenamine;leneoxy))bis-;leneoxy)]bis-;2,2-BIS[4-(4-AMINOPH
- CBNumber
- CB3265411
- Molecular Formula
- C27H20F6N2O2
- Formula Weight
- 518.45
- MOL File
- 69563-88-8.mol
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Property
- Melting point:
- 159-163 °C(lit.)
- Boiling point:
- 544.8±50.0 °C(Predicted)
- Density
- 1.3455 (estimate)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Water Solubility
- Insoluble in water
- solubility
- Soluble in DMSO
- form
- powder to crystal
- pka
- 4.80±0.10(Predicted)
- color
- White to Almost white
- InChIKey
- HHLMWQDRYZAENA-UHFFFAOYSA-N
- CAS DataBase Reference
- 69563-88-8(CAS DataBase Reference)
- EPA Substance Registry System
- Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- RTECS
- CY1213000
- HazardClass
- IRRITANT
- HS Code
- 29222990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 386669
- Product name
- 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline
- Purity
- 97%
- Packaging
- 5g
- Price
- $82.6
- Updated
- 2024/03/01
- Product number
- B1398
- Product name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 5g
- Price
- $57
- Updated
- 2024/03/01
- Product number
- B1398
- Product name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $188
- Updated
- 2024/03/01
- Product number
- 6689
- Product name
- GI530159
- Purity
- ≥99%(HPLC)
- Packaging
- 50
- Price
- $516
- Updated
- 2021/12/16
- Product number
- 6689
- Product name
- GI530159
- Purity
- ≥99%(HPLC)
- Packaging
- 10
- Price
- $122
- Updated
- 2021/12/16
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Chemical Properties,Usage,Production
Uses
2,2-bis[4-(4-Aminophenoxy)phenyl]hexafluoropropane (cas# 69563-88-8) has been used in the preparation of permeable membranes for atmospheric CO2 capture and gas transport.
Description
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].
Chemical Properties
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is white crystal or powder
Uses
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.
Hazard
Moderately toxic by ingestion and skin contact. An eye irritant.
storage
Store at +4°C
References
[1] M.E. ROGERS. Semicrystalline and amorphous fluorine-containing polyimides[J]. Polymer, 1993. DOI:10.1016/0032-3861(93)90373-I.
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE manufacturers
- Product
- 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE 69563-88-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-24
- Product
- 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP) 69563-88-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1500KG/month
- Release date
- 2021-11-01
- Product
- 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane (HFBAPP) 69563-88-8
- Price
- US $0.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- ≥99%
- Supply Ability
- 10TM
- Release date
- 2021-12-15