2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane

Description Synthesis

Product Name: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
CAS No.: 83558-87-6
Chemical Name: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
Synonyms: 6FAP;AHHFP;BAFA;4,4'-(Perfluoropropane-2,2-diyl)bis(2-aMinophenol);BAPAF;2,2-Bis(3-aMino-4-hydroxylphenyl)hexafluoropropane(6FAP);1,1-Bis(3-aMino-4-hydroxyphenyl)-2,2,2-trifluoro-1-(trifluoroMethyl)ethane;BIS-AP-AF;Bis-AP-AF2;Bis-AP-AF/6FAP
CBNumber: CB7397729
Molecular Formula: C15H12F6N2O2
Formula Weight: 366.26
MOL File: 83558-87-6.mol

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2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Property

Melting point:: 245-248 °C (lit.)
Boiling point:: 411.3±45.0 °C(Predicted)
Density: 1.545±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: DMSO (Slightly), Methanol (Slightly)
form: Solid
pka: 9.07±0.10(Predicted)
color: White to Off-White
InChI: InChI=1S/C15H12F6N2O2/c16-14(17,18)13(15(19,20)21,7-1-3-11(24)9(22)5-7)8-2-4-12(25)10(23)6-8/h1-6,24-25H,22-23H2
InChIKey: MSTZGVRUOMBULC-UHFFFAOYSA-N
SMILES: C(C1=CC=C(O)C(N)=C1)(C1=CC=C(O)C(N)=C1)(C(F)(F)F)C(F)(F)F
CAS DataBase Reference: 83558-87-6(CAS DataBase Reference)
EPA Substance Registry System: Phenol, 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[2-amino- (83558-87-6)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29222990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 541710
Product name: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
Purity: 97%
Packaging: 5g
Price: $67.68
Updated: 2024/03/01

TCI Chemical

Product number: B1415
Product name: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
Purity: >98.0%(T)
Packaging: 5g
Price: $86
Updated: 2024/03/01

TCI Chemical

Product number: B1415
Product name: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
Purity: >98.0%(T)
Packaging: 25g
Price: $257
Updated: 2024/03/01

TRC

Product number: B591980
Product name: 2,2-Bis(3-Amino-4-hydroxyphenyl(hexafluoropropane))
Packaging: 500mg
Price: $50
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4756-3-34
Product name: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
Purity: 99%
Packaging: 25g
Price: $60
Updated: 2021/12/16

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2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Chemical Properties,Usage,Production

Description

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane (6FAP) is white crystal. Its boiling point and density are expected to be 411.3±45.0 °C and 1.545±0.06 g/cm3, respectively. It is slightly soluble in DMSO and methanol.The product is non-toxic and can be stored at room temperature away from light and air.

Synthesis

30 g two (3-nitro-4-hydroxyphenyl) hexafluoropropanes are dropped into the 1000 mL autoclave, add 300 g DMF and 1.5 g palladium/carbon (the mass fraction of palladium in the palladium/carbon is 5%), press hydrogen to 1MPa, open stirring and be warmed up to 70 ℃, stop reaction after two (3-nitro-4-hydroxyphenyl) hexafluoropropane content＜0.1%, target product two (3-amino-4-hydroxyphenyl) hexafluoropropane Fluoropropane gas phase content is 98%, and the system is black, and the temperature of the still is lowered to room temperature, filtered, and the filtrate is de-dried under reduced pressure at 70-80°C to obtain bis(3-amino-4-hydroxyphenyl) hexafluoropropane crude product , the crude product is recrystallized, the recrystallization solvent is water and DMF, and the mass ratio of bis(3-amino-4-hydroxyphenyl)hexafluoropropane, water and DMF is 1:4:2.
First, the bis(3-nitro-4-hydroxyphenyl) hexafluoropropane crude product is mixed with the recrystallization solvent to increase the still temperature to 60 °C and stir, and then the still temperature is reduced to 10-20 °C for crystallization, filtered, After drying, 25.4 g of pure bis(3-nitro-4-hydroxyphenyl)hexafluoropropane was obtained. The yield of bis(3-amino-4-hydroxyphenyl)hexafluoropropane was 98.3% and the purity was 99.6%. 1H-NMR (400MHz, D6-DMSO) δ (ppm): 4.64 (s, 4H), 6.42 (d, 2H), 7.57 (s, 2H), 6.65 (d, 2H), 9.36 (s, 2H). 19F-NMR (400MHz, D6-DMSO) δ (ppm): -62.78. [1].

Physical properties

White powder

Uses

2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane（BisAPAF） is a polyimide monomer.It is mairly used in the aynthesis of the heat resisting polymers,especially in the manufacture of specialty polymeoric electronic material-fluorinated polyimides.

General Description

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane, also referred to as 4,4′-(1,1,1,3,3,3-hexafluoro-2,2-propanediyl)bis(2-aminophenol), is an aromatic diamine.

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Suppliers

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View Lastest Price from 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd

Product: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 83558-87-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.91%
Supply Ability: 200000
Release date: 2024-04-23

Henan Fengda Chemical Co., Ltd

Product: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 83558-87-6
Price: US $158.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-05

Shanghai UCHEM Inc.

Product: 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 83558-87-6
Price: US $24.00-151.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 100kg
Release date: 2023-12-14

83558-87-6, 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropaneRelated Search:

Glycerol 3,4'-DIAMINODIPHENYLMETHANE Hexafluoropropylene oxide ALTRENOGEST Glycine Tris(hydroxymethyl)aminomethane 1,1,1,2,2,3-HEXAFLUOROPROPANE 1,1,1,2,3,3,3-Heptafluoropropane 3,3'-DIAMINODIPHENYLMETHANE 3-Amino-6-morpholinopyridine 1,1,1,3,3,3-Hexafluoropropane 4-CUMYLPHENOL 2,2-Bis(3-amino-4-hydroxyphenyl)propane Hexafluorobisphenol A Bisphenol A 2-Amino-4-tert-butylphenol PERFLUOROPROPANE hexafluoro-2,2-diphenylpropane

1,1-Bis(3-aMino-4-hydroxyphenyl)-2,2,2-trifluoro-1-(trifluoroMethyl)ethane

2,2-Bis(3-aMino-4-hydroxylphenyl)hexafluoropropane(6FAP)

2-aMino-4-[2-(3-aMino-4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]phenol

4,4'-(Perfluoropropane-2,2-diyl)bis(2-aMinophenol)

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluopropane

2,2-Bis(3-amino-4-hydroxyphenyl)-hexafluoropropane(Bis-AP-AF/6FAP)

BIS-AP-AF

4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS(2-AMINOPHENOL)

2,2-BIS(3-AMINO-4-HYDROXYPHENYL)HEXAFLUOROPROPANE

2,2'-DIAMINO-4,4'-(PERFLUOROPROPANE-2,2-DIYL)DIPHENOL

2,2-BIS(3-AMINO-4-HYDROXYPHENYL)HEXAFLUO

6FAP

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane,6-FAP

2,2-Bis(3-amino-4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane

4,4'-(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis(2-aminophenol)

4,4'-[Bis(trifluoromethyl)methylene]bis(2-aminophenol)

AHHFP

Phenol, 4,4'-(2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(2-amino-

2,2-bis(3-amino-4-hy

2,2-bis(3-amino-4-hydroxyphenyl) -hexafluoropropane (Bis-AP-AF)

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 99%

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane99%

2,2-Bis(3-amino-4-hydroxyphenyl)-

BAPAF

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane &gt

BAFA

2-Amino-4-[1-(3-amino-4-hydroxy-phenyl)-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenol

2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane USP/EP/BP

2-aMino-4-[2-(3-aMino-4-hydroxyphenyl)-1,1,1,3,3,3-

Bis-AP-AF2

Bis-AP-AF/6FAP

O-aminobisphenol AF

4,4'-(Perfluoropropane-2,2-diyl)bis(2-aminophenol)

83558-87-6

F3C2CC6H3NH2OH2

C15H12F6N2O2

Organic Building Blocks

Oxygen Compounds

Bisphenol AF type Compounds (for High-Performance Polymer Research)

Reagent for High-Performance Polymer Research

Building Blocks

Amino Alcohols

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, Organic Building Blocks

Bisphenol AF type Compounds (for High-Performance Polymer Research)

Functional Materials

Reagent for High-Performance Polymer Research

Amino Alcohols

Organic Building Blocks

Oxygen Compounds

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials

83558-87-6