2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

ChemicalBook > CAS DataBase List > 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

Uses

Product Name: 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
CAS No.: 69563-88-8
Chemical Name: 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
Synonyms: HFBAPP;6FBAPP;4-BDAF;BAPOFP;BIS-AF-A;GI 530159;isbenzenamine;leneoxy))bis-;leneoxy)]bis-;2,2-BIS[4-(4-AMINOPH
CBNumber: CB3265411
Molecular Formula: C27H20F6N2O2
Formula Weight: 518.45
MOL File: 69563-88-8.mol

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2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Property

Melting point:: 159-163 °C(lit.)
Boiling point:: 544.8±50.0 °C(Predicted)
Density: 1.3455 (estimate)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
Water Solubility: Insoluble in water
solubility: Soluble in DMSO
form: powder to crystal
pka: 4.80±0.10(Predicted)
color: White to Almost white
InChIKey: HHLMWQDRYZAENA-UHFFFAOYSA-N
CAS DataBase Reference: 69563-88-8(CAS DataBase Reference)
EPA Substance Registry System: Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 26-36
WGK Germany: 3
RTECS: CY1213000
HazardClass: IRRITANT
HS Code: 29222990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 386669
Product name: 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline
Purity: 97%
Packaging: 5g
Price: $82.6
Updated: 2024/03/01

TCI Chemical

Product number: B1398
Product name: 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
Purity: >98.0%(HPLC)(T)
Packaging: 5g
Price: $57
Updated: 2024/03/01

TCI Chemical

Product number: B1398
Product name: 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $188
Updated: 2024/03/01

Tocris

Product number: 6689
Product name: GI530159
Purity: ≥99%(HPLC)
Packaging: 50
Price: $516
Updated: 2021/12/16

Tocris

Product number: 6689
Product name: GI530159
Purity: ≥99%(HPLC)
Packaging: 10
Price: $122
Updated: 2021/12/16

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2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Chemical Properties,Usage,Production

Uses

2,2-bis[4-(4-Aminophenoxy)phenyl]hexafluoropropane (cas# 69563-88-8) has been used in the preparation of permeable membranes for atmospheric CO2 capture and gas transport.

Description

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications^[1].

Chemical Properties

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is white crystal or powder

Uses

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.

Hazard

Moderately toxic by ingestion and skin contact. An eye irritant.

storage

Store at +4°C

References

[1] M.E. ROGERS. Semicrystalline and amorphous fluorine-containing polyimides[J]. Polymer, 1993. DOI:10.1016/0032-3861(93)90373-I.

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP) 69563-88-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1500KG/month
Release date: 2021-11-01

Hebei Weibang Biotechnology Co., Ltd

Product: 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE 69563-88-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

CHINATECH(TIANJIN) CHEMICAL CO.,LTD.

Product: 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane (HFBAPP) 69563-88-8
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: ≥99%
Supply Ability: 10TM
Release date: 2021-12-15

69563-88-8, 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANERelated Search:

4,4'-Diaminodiphenylsulfone 4,4'-Bis(4-aminophenoxy)biphenyl 2,2-Bis(3-amino-4-hydroxyphenyl)propane 1,4-Bis(4-aminophenoxy)benzene 2,2-Bis(4-(4-maleimidephenoxy)phenyl)propane 2,2-Bis(4-aminophenyl)hexafluoropropane 2,2-BIS(3-AMINO-4-METHYLPHENYL)HEXAFLUOROPROPANE 1,3-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 2,2'-Bis(trifluoromethyl)benzidine 1,4-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE 9,9-Bis(4-aminophenyl)fluorene 1,1,1,2,2,3-HEXAFLUOROPROPANE 4-Phenoxyaniline 1,1,1,3,3,3-Hexafluoropropane

4-(4-aminophenoxy)phenyl

6FBAPP

2,2'-Bis[4-(4- aminophenoxy)-1,1,1,3,3,3-sixfluoropropane(HFBAPP)

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-HEXAFLUOROPROPANANE

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane, 4,4μ-(Hexafluoroisopropylidene)bis(p-phenylenoxy)dianiline

HFBAPP

2,2-Bis[4-(4-aminophenoxyphenyl)]hexafluoropropane 98%

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-1,1,1,3,3,3-HEXAFLUOROPROPANE

2,2-Bis[4-(4-aminophenoxyphenyl])hexafluoropropane98%

2,2''-BIS[4-(4-AMINOPHENOXY)PHENY]HEXAFLUOROPROPANE

4,4'-[HEXAFLUOROISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE

4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS(P-PHE NYLENOXY)DIANILINE

4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS[(4-AMINOPHENOXY)BENZENE]

4'',4'''-(HEXAFLUOROISOPROPYLIDENE)BIS(4-PHENOXYANILINE)

4',4'''-(HEXAFLUOROISOPROPYLIDENE)-BIS-(4-PHENOXYANILINE)

4-BDAF

isbenzenamine

leneoxy))bis-

leneoxy)]bis-

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane

[4-[4-[1-[4-(4-aminophenoxy)phenyl]-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenoxy]phenyl]amine

4-[4-[2-[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]aniline

4-[4-[2-[4-(4-azanylphenoxy)phenyl]-1,1,1,3,3,3-hexafluoro-propan-2-yl]phenoxy]aniline

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane ,99%

2,2-BIS[4-(4-AMINOPH

4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97%

BAPOFP

GI 530159

4,4'-[[2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis[benzenamine]

4-[2-(4-amino-2-phenoxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-3-phenoxyaniline

2,2-Bis[4-(-aMinophenoxy)phenyl]hexafluoropropane(HFBAPP)

4,4'-{(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis[(benzene-4,1-diyl)oxy]}dianiline, BIS-AF-A, 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline

2,2- double[4-(4- aMinophenoxy)]six fluorinepropane

2,2-Bis[4-(-aminophenoxy)phenyl]hexafluoropropane

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (HFBAPP)

4,4'-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))dianiline

2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane 4′

4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline)

2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP)

BIS-AF-A

4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-phenyleneoxy))b

benzenamine,4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-pheny

benzenamine,4,4’-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-pheny

2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane &gt

Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis-

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE ISO 9001：2015 REACH

2,2-Bis[4-(4-aminophenoxy)

2,2-bi [4-(4-aminophenoxy)benzeneHexafluoropropane

2,2-double [4-4-aminophenoxy)phenyl]Hexafluoropropane

2,2-Bis[4-(4-aminophenoxybenzene)]hexafluoropropane, 97%

4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline

2,2- Bis[ 4-(4-aminophenoxy)pheny] hexafluoropropane (HFBAPP)

69563-88-8

6956-88-8

C27H20F6N2O2

CF32CC6H4OC6H4NH22

Reagent for High-Performance Polymer Research