Uses
ChemicalBook > CAS DataBase List > 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE

Uses
Product Name
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
CAS No.
69563-88-8
Chemical Name
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE
Synonyms
HFBAPP;6FBAPP;4-BDAF;BAPOFP;BIS-AF-A;GI 530159;isbenzenamine;leneoxy))bis-;leneoxy)]bis-;2,2-BIS[4-(4-AMINOPH
CBNumber
CB3265411
Molecular Formula
C27H20F6N2O2
Formula Weight
518.45
MOL File
69563-88-8.mol
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2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Property

Melting point:
159-163 °C(lit.)
Boiling point:
544.8±50.0 °C(Predicted)
Density 
1.3455 (estimate)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Water Solubility 
Insoluble in water
solubility 
Soluble in DMSO
form 
powder to crystal
pka
4.80±0.10(Predicted)
color 
White to Almost white
InChIKey
HHLMWQDRYZAENA-UHFFFAOYSA-N
CAS DataBase Reference
69563-88-8(CAS DataBase Reference)
EPA Substance Registry System
Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
CY1213000
HazardClass 
IRRITANT
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
386669
Product name
4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline
Purity
97%
Packaging
5g
Price
$82.6
Updated
2024/03/01
TCI Chemical
Product number
B1398
Product name
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$57
Updated
2024/03/01
TCI Chemical
Product number
B1398
Product name
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$188
Updated
2024/03/01
Tocris
Product number
6689
Product name
GI530159
Purity
≥99%(HPLC)
Packaging
50
Price
$516
Updated
2021/12/16
Tocris
Product number
6689
Product name
GI530159
Purity
≥99%(HPLC)
Packaging
10
Price
$122
Updated
2021/12/16
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2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Chemical Properties,Usage,Production

Uses

2,2-bis[4-(4-Aminophenoxy)phenyl]hexafluoropropane (cas# 69563-88-8) has been used in the preparation of permeable membranes for atmospheric CO2 capture and gas transport.

Description

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].

Chemical Properties

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is white crystal or powder

Uses

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.

Hazard

Moderately toxic by ingestion and skin contact. An eye irritant.

storage

Store at +4°C

References

[1] M.E. ROGERS. Semicrystalline and amorphous fluorine-containing polyimides[J]. Polymer, 1993. DOI:10.1016/0032-3861(93)90373-I.

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE Suppliers

Chengdu Yuanda chemical co.,ltd
Tel
028-85356300 18980937689
Fax
+86-28-85356300
Email
chenquanxing@126.com
Country
China
ProdList
100
Advantage
55
Changzhou Josen Pharmaceutical Chemical Material Co., Ltd.
Tel
18961143913
Fax
0519-85286950
Email
444964576@qq.com
Country
China
ProdList
56
Advantage
58
Wuhan kemike Biomedical Technology Co., Ltd
Tel
027-87747081 18186681184
Email
1344475572@qq.com
Country
China
ProdList
7235
Advantage
58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
Tel
+86-022-83726202 +86-18222493702
Fax
022-83726200
Email
sales@chinatechem.com
Country
China
ProdList
81
Advantage
58
Changzhou Sunlight Pharmaceutical Co., Ltd
Tel
0519-83131668 15995063688
Fax
+86-519-83138041
Email
info@sunlightchem.com
Country
China
ProdList
99
Advantage
69
Heynova (Shanghai) New Material Technology CO., Ltd
Tel
17821320848
Email
zoe@heynovachem.com
Country
China
ProdList
174
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
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View Lastest Price from 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Product
2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP) 69563-88-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1500KG/month
Release date
2021-11-01
Hebei Weibang Biotechnology Co., Ltd
Product
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE 69563-88-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
Product
2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane (HFBAPP) 69563-88-8
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
≥99%
Supply Ability
10TM
Release date
2021-12-15

69563-88-8, 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANERelated Search:


  • 4-(4-aminophenoxy)phenyl
  • 6FBAPP
  • 2,2'-Bis[4-(4- aminophenoxy)-1,1,1,3,3,3-sixfluoropropane(HFBAPP)
  • 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-HEXAFLUOROPROPANANE
  • 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane, 4,4μ-(Hexafluoroisopropylidene)bis(p-phenylenoxy)dianiline
  • HFBAPP
  • 2,2-Bis[4-(4-aminophenoxyphenyl)]hexafluoropropane 98%
  • 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]-1,1,1,3,3,3-HEXAFLUOROPROPANE
  • 2,2-Bis[4-(4-aminophenoxyphenyl])hexafluoropropane98%
  • 2,2''-BIS[4-(4-AMINOPHENOXY)PHENY]HEXAFLUOROPROPANE
  • 4,4'-[HEXAFLUOROISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE
  • 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS(P-PHE NYLENOXY)DIANILINE
  • 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS[(4-AMINOPHENOXY)BENZENE]
  • 4'',4'''-(HEXAFLUOROISOPROPYLIDENE)BIS(4-PHENOXYANILINE)
  • 4',4'''-(HEXAFLUOROISOPROPYLIDENE)-BIS-(4-PHENOXYANILINE)
  • 4-BDAF
  • isbenzenamine
  • leneoxy))bis-
  • leneoxy)]bis-
  • 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane
  • [4-[4-[1-[4-(4-aminophenoxy)phenyl]-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenoxy]phenyl]amine
  • 4-[4-[2-[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]aniline
  • 4-[4-[2-[4-(4-azanylphenoxy)phenyl]-1,1,1,3,3,3-hexafluoro-propan-2-yl]phenoxy]aniline
  • 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane ,99%
  • 2,2-BIS[4-(4-AMINOPH
  • 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline 97%
  • BAPOFP
  • GI 530159
  • 4,4'-[[2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis[benzenamine]
  • 4-[2-(4-amino-2-phenoxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-3-phenoxyaniline
  • 2,2-Bis[4-(-aMinophenoxy)phenyl]hexafluoropropane(HFBAPP)
  • 4,4'-{(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis[(benzene-4,1-diyl)oxy]}dianiline, BIS-AF-A, 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline
  • 2,2- double[4-(4- aMinophenoxy)]six fluorinepropane
  • 2,2-Bis[4-(-aminophenoxy)phenyl]hexafluoropropane
  • 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (HFBAPP)
  • 4,4'-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))dianiline
  • 2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane 4′
  • 4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline)
  • 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane(HFBAPP)
  • BIS-AF-A
  • 4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-phenyleneoxy))b
  • benzenamine,4,4’-((2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis(4,1-pheny
  • benzenamine,4,4’-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-pheny
  • 2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane
  • 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane &gt
  • Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis-
  • 2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE ISO 9001:2015 REACH
  • 2,2-Bis[4-(4-aminophenoxy)
  • 2,2-bi [4-(4-aminophenoxy)benzeneHexafluoropropane
  • 2,2-double [4-4-aminophenoxy)phenyl]Hexafluoropropane
  • 2,2-Bis[4-(4-aminophenoxybenzene)]hexafluoropropane, 97%
  • 4,4'-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline
  • 2,2- Bis[ 4-(4-aminophenoxy)pheny] hexafluoropropane (HFBAPP)
  • 69563-88-8
  • 6956-88-8
  • C27H20F6N2O2
  • CF32CC6H4OC6H4NH22
  • Reagent for High-Performance Polymer Research