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GALLIUM(III) CHLORIDE

Product Name
GALLIUM(III) CHLORIDE
CAS No.
13450-90-3
Chemical Name
GALLIUM(III) CHLORIDE
Synonyms
GaCl3;Nsc94002;granular;Wln: ga G3;gallium(iii);ium(III) chL;Trichlorogallium;GALLIUM CHLORIDE;GalliuM trchloride;galliumchloride[qr]
CBNumber
CB3275575
Molecular Formula
Cl3Ga
Formula Weight
176.08
MOL File
13450-90-3.mol
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GALLIUM(III) CHLORIDE Property

Melting point:
78 °C(lit.)
Boiling point:
35 °C
Density 
2.47 g/mL at 25 °C(lit.)
vapor pressure 
1 mm Hg ( 48 °C)
Flash point:
−26 °F
form 
beads
color 
White
Specific Gravity
2.47
Water Solubility 
Very soluble in water. Soluble in benzene, carbon tetrachloride and carbon disulfide
Sensitive 
Moisture Sensitive
Merck 
14,4348
Stability:
Stability Stable, but reacts violently with water.
InChIKey
UPWPDUACHOATKO-UHFFFAOYSA-K
CAS DataBase Reference
13450-90-3(CAS DataBase Reference)
EPA Substance Registry System
Gallium trichloride (13450-90-3)
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Safety

Hazard Codes 
C,N,F+
Risk Statements 
14-34-51/53-12-67-65
Safety Statements 
26-27-28-36/37/39-45-61-33-29-16-62
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
LW9100000
3-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28273990
Hazardous Substances Data
13450-90-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H224Extremely flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H336May cause drowsiness or dizziness

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
427128
Product name
Gallium(III) chloride
Purity
beads, anhydrous, ≥99.999% trace metals basis
Packaging
5g
Price
$62.9
Updated
2021/12/16
Sigma-Aldrich
Product number
427128
Product name
Gallium(III) chloride
Purity
beads, anhydrous, ≥99.999% trace metals basis
Packaging
25g
Price
$157
Updated
2021/12/16
Sigma-Aldrich
Product number
552798
Product name
Gallium(III) chloride solution
Purity
0.5 M in pentane
Packaging
25ml
Price
$62.2
Updated
2020/08/18
Sigma-Aldrich
Product number
552798
Product name
Gallium(III) chloride solution
Purity
0.5 M in pentane
Packaging
100ml
Price
$203
Updated
2020/08/18
Sigma-Aldrich
Product number
427128
Product name
Gallium(III) chloride
Purity
beads, anhydrous, ≥99.999% trace metals basis
Packaging
100g
Price
$578
Updated
2019/12/02
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GALLIUM(III) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

white crystals or powder

Chemical Properties

Gallium trichloride is a colorless solid which forms needle-like crystals. Acidic odor.

Uses

Lewis acid catalyst in organic synthesis; reagent for generating organogallium compounds, metallic gallium, and gallium semiconductors.

Uses

Gallium(III) chloride is a catalyst for a number of transformations including the ring opening and recyclization of epoxides and the trimerization of alkynes. It is used to detect the solar neutrions.

Production Methods

The trichloride salt of trivalent gallium is prepared by the action of either hydrogen chloride or chlorine on the metal.

General Description

Colorless needles. Used as a raw material in the production of metallic gallium and in the processing of mono crystal semiconductor compounds.

Air & Water Reactions

Water soluble.

Reactivity Profile

GALLIUM(III) CHLORIDE acts as a weak inorganic acid. Materials in this group are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

(Non-Specific -- Gallium Compounds) In view of the toxicity of gallium and its compounds, as shown by experiments, all persons involved in work with these substances should undergo periodic medical examinations, during which special attention should be paid to the condition of the liver, respiratory organs, and skin.

Fire Hazard

Emits toxic chloride fumes when heated to decomposition. Decomposes upon sufficient heating.

Potential Exposure

Used as a raw material in the produc tion of metallic gallium; and in the processing of mono crystal, semiconductor compounds.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN1759 Corrosive solids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name required.

Purification Methods

The pure compound can be obtained by redistillation in a stream of Cl2 or Cl2/N2 followed by vacuum sublimation or zone refining. It forms colourless needles which give gallium dichloride [Ga(GaCl4), m 172.4o] on heating. It dissolves in H2O with liberation of heat. It is soluble in Et2O and can be extracted from an HCl solution with Et2O. [Laubengayer & Schirmer J Am Chem Soc 62 1579 1940, D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 846 1963.]

GALLIUM(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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GALLIUM(III) CHLORIDE Suppliers

Shandong Ono Chemical Co., Ltd.
Tel
0539-6362799(To 20)
Fax
0539-6362799(To 20)
Email
68188893@qq.com
Country
China
ProdList
10009
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3579
Advantage
66
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30159
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820-
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1401
Advantage
62
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057-
Fax
0757-86311057
Email
sales.gd@hwrkchemical.com
Country
China
ProdList
17295
Advantage
55
Energy Chemical
Tel
021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
43431
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12270
Advantage
60
Nanjing Chemlin Chemical Co., Ltd
Tel
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
20007
Advantage
64
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View Lastest Price from GALLIUM(III) CHLORIDE manufacturers

Career Henan Chemical Co
Product
GALLIUM(III) CHLORIDE 13450-90-3
Price
US $1.00/g
Min. Order
50 g
Purity
99.99%
Supply Ability
20kg
Release date
2018-12-18

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