PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
Reactions- Product Name
- PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
- CAS No.
- 185812-86-6
- Chemical Name
- PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
- Synonyms
- Pd-113;broMopalladiuM;[Pd(μ-Br)t-Bu3P]2;bromopalladium tritert-butylphosphane;PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE;Dibromobis(tri-tert-butylphosphine)dipalladium;Bromo(tri-tert-butylphosphine)palladium(I)dimer;DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium(I);Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
- CBNumber
- CB3279937
- Molecular Formula
- C24H56Br2P2Pd2
- Formula Weight
- 779.31
- MOL File
- 185812-86-6.mol
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Property
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- form
- crystal
- color
- dark-green
- Water Solubility
- Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water.
- Sensitive
- Air Sensitive
Safety
- Hazard Codes
- F,C
- Risk Statements
- 36/37/38-34-17-14
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3393 4.2/PG 1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 044446
- Product name
- Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
- Packaging
- 0.1g
- Price
- $73.1
- Updated
- 2024/03/01
- Product number
- 044446
- Product name
- Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
- Packaging
- 0.5g
- Price
- $292
- Updated
- 2024/03/01
- Product number
- 46-0355
- Product name
- Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
- Packaging
- 100mg
- Price
- $64
- Updated
- 2024/03/01
- Product number
- 46-0355
- Product name
- Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
- Packaging
- 500mg
- Price
- $254
- Updated
- 2024/03/01
- Product number
- 044446
- Product name
- Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
- Packaging
- 2g
- Price
- $1020
- Updated
- 2024/03/01
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Chemical Properties,Usage,Production
Reactions
- Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids.
- Aryl bromide - silyl ketene acetal coupling.
- Catalyst for intermolecular α-arylation of zinc amide enolates.
- Catalyst for α-vinylation of carbonyl compounds.
- Catalyst for thiol coupling of heteroaromatic aryl bromides.
Chemical Properties
Greenish blue
Uses
Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Suppliers
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View Lastest Price from PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE manufacturers
- Product
- Dibromobis(tri-tert-butylphosphine)dipalladium(I) 185812-86-6
- Price
- US $8.70/g
- Min. Order
- 10g
- Purity
- 27.4%
- Supply Ability
- 10000kg
- Release date
- 2024-08-20
- Product
- PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE 185812-86-6
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 95%-99%
- Supply Ability
- 100kg
- Release date
- 2018-12-22