PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

ChemicalBook > CAS DataBase List > PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

Reactions

Product Name: PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
CAS No.: 185812-86-6
Chemical Name: PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
Synonyms: Pd-113;broMopalladiuM;[Pd(μ-Br)t-Bu3P]2;bromopalladium tritert-butylphosphane;PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE;Dibromobis(tri-tert-butylphosphine)dipalladium;Bromo(tri-tert-butylphosphine)palladium(I)dimer;DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium(I);Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
CBNumber: CB3279937
Molecular Formula: C24H56Br2P2Pd2
Formula Weight: 779.31
MOL File: 185812-86-6.mol

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PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Property

storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: crystal
color: dark-green
Water Solubility: Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water.
Sensitive: Air Sensitive

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Safety

Hazard Codes: F,C
Risk Statements: 36/37/38-34-17-14
Safety Statements: 26-36/37/39-45
RIDADR: UN 3393 4.2/PG 1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: 044446
Product name: Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
Packaging: 0.1g
Price: $73.1
Updated: 2024/03/01

Alfa Aesar

Product number: 044446
Product name: Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
Packaging: 0.5g
Price: $292
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0355
Product name: Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
Packaging: 100mg
Price: $64
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0355
Product name: Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
Packaging: 500mg
Price: $254
Updated: 2024/03/01

Alfa Aesar

Product number: 044446
Product name: Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
Packaging: 2g
Price: $1020
Updated: 2024/03/01

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PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Chemical Properties,Usage,Production

Reactions

Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids.
Aryl bromide - silyl ketene acetal coupling.
Catalyst for intermolecular α-arylation of zinc amide enolates.
Catalyst for α-vinylation of carbonyl compounds.
Catalyst for thiol coupling of heteroaromatic aryl bromides.

Chemical Properties

Greenish blue

Uses

Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE manufacturers

Hebei Guanlang Biotechnology Co,.LTD

Product: Dibromobis(tri-tert-butylphosphine)dipalladium(I) 185812-86-6
Price: US $8.70/g
Min. Order: 10g
Purity: 27.4%
Supply Ability: 10000kg
Release date: 2021-07-16

Career Henan Chemical Co

Product: PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE 185812-86-6
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 100kg
Release date: 2018-12-22

185812-86-6, PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDERelated Search:

T-BUTYLPHOSPHINE DI-T-BUTYL(I-PROPYL)PHOSPHINE Tri-tert-butylphosphine Bis(tri-tert-butylphosphine)palladium(0) TERT-BUTYLDIISOPROPYLPHOSPHINE PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I)

Dibromobis(tri-tert-butylphosphine)dipalladium

Dibromobis(tri-tert-butylphosphine)dipalladium(I)

-bromobis(tri-tert-butylphosphine)dipalladium/ Pd (I) dimer Reasonably stable for packaging and transfer.

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE, DIMER

Bromo(tri-tert-butylphosphine)palladium(I)dimer

DI--BROMOBIS(TRI-TERT-BUTYLPHOSPHINO)DIPALLADIUM(I)

Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I)

Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium

Palladium, di-μ-bromobis[tris(1,1-dimethylethyl)phosphine]di-, (Pd-Pd)

Dibromobis(tri-tert-butylphosphino)dipalladium(I), Palladium(I) tri-tert-butylphosphine bromide, dimer

PalladiuM, di-M-broMobis[tris(1,1-diMethylethyl)phosphine]di-,(Pd-Pd)

Di-^M-broMobis(tri-tert-butylphosphine)dipalladiuM(I)

broMopalladiuM

[Pd(μ-Br)t-Bu3P]2

Pd-113

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE ISO 9001：2015 REACH

Bis (tri-t-butylphosphine) palladium bromide (I), dimer

bromopalladium tritert-butylphosphane

185812-86-6

PdC4H93PBr2

C24H54Br2P2Pd2

C12H27BrPPd

metal phosphine complex