Reactions
ChemicalBook > CAS DataBase List > PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE

Reactions
Product Name
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
CAS No.
185812-86-6
Chemical Name
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
Synonyms
Pd-113;broMopalladiuM;[Pd(μ-Br)t-Bu3P]2;bromopalladium tritert-butylphosphane;PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE;Dibromobis(tri-tert-butylphosphine)dipalladium;Bromo(tri-tert-butylphosphine)palladium(I)dimer;DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium(I);Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
CBNumber
CB3279937
Molecular Formula
C24H56Br2P2Pd2
Formula Weight
779.31
MOL File
185812-86-6.mol
More
Less

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Property

storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
crystal
color 
dark-green
Water Solubility 
Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water.
Sensitive 
Air Sensitive
More
Less

Safety

Hazard Codes 
F,C
Risk Statements 
36/37/38-34-17-14
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3393 4.2/PG 1
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Alfa Aesar
Product number
044446
Product name
Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
Packaging
0.1g
Price
$73.1
Updated
2024/03/01
Alfa Aesar
Product number
044446
Product name
Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
Packaging
0.5g
Price
$292
Updated
2024/03/01
Strem Chemicals
Product number
46-0355
Product name
Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
Packaging
100mg
Price
$64
Updated
2024/03/01
Strem Chemicals
Product number
46-0355
Product name
Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
Packaging
500mg
Price
$254
Updated
2024/03/01
Alfa Aesar
Product number
044446
Product name
Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I)
Packaging
2g
Price
$1020
Updated
2024/03/01
More
Less

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Chemical Properties,Usage,Production

Reactions

  • Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids.
  • Aryl bromide - silyl ketene acetal coupling.
  • Catalyst for intermolecular α-arylation of zinc amide enolates.
  • Catalyst for α-vinylation of carbonyl compounds.
  • Catalyst for thiol coupling of heteroaromatic aryl bromides.

Chemical Properties

Greenish blue

Uses

Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Suppliers

More
Less

View Lastest Price from PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE manufacturers

Hebei Guanlang Biotechnology Co,.LTD
Product
Dibromobis(tri-tert-butylphosphine)dipalladium(I) 185812-86-6
Price
US $8.70/g
Min. Order
10g
Purity
27.4%
Supply Ability
10000kg
Release date
2021-07-16
Career Henan Chemical Co
Product
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE 185812-86-6
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-22

185812-86-6, PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDERelated Search:


  • DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I)
  • Dibromobis(tri-tert-butylphosphine)dipalladium
  • Dibromobis(tri-tert-butylphosphine)dipalladium(I)
  • -bromobis(tri-tert-butylphosphine)dipalladium/ Pd (I) dimer Reasonably stable for packaging and transfer.
  • PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
  • PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE, DIMER
  • Bromo(tri-tert-butylphosphine)palladium(I)dimer
  • DI--BROMOBIS(TRI-TERT-BUTYLPHOSPHINO)DIPALLADIUM(I)
  • Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I)
  • Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
  • Palladium, di-μ-bromobis[tris(1,1-dimethylethyl)phosphine]di-, (Pd-Pd)
  • Dibromobis(tri-tert-butylphosphino)dipalladium(I), Palladium(I) tri-tert-butylphosphine bromide, dimer
  • PalladiuM, di-M-broMobis[tris(1,1-diMethylethyl)phosphine]di-,(Pd-Pd)
  • Di-^M-broMobis(tri-tert-butylphosphine)dipalladiuM(I)
  • broMopalladiuM
  • [Pd(μ-Br)t-Bu3P]2
  • Pd-113
  • PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE ISO 9001:2015 REACH
  • Bis (tri-t-butylphosphine) palladium bromide (I), dimer
  • bromopalladium tritert-butylphosphane
  • 185812-86-6
  • PdC4H93PBr2
  • C24H54Br2P2Pd2
  • C12H27BrPPd
  • Pd
  • metal phosphine complex