ChemicalBook > CAS DataBase List > 1-Bromopyrene

1-Bromopyrene

Product Name
1-Bromopyrene
CAS No.
1714-29-0
Chemical Name
1-Bromopyrene
Synonyms
2-Bromopyrene;DK4994;1-Bromopyene;1-BROMOPYRENE;Pyrene, 1-bromo-;1-Pyrenyl bromide;1-Bromopyrene >1-Bromopyrene 96%;1714-29-0 1-Bromopyrene;1-Bromopyrene in toluene
CBNumber
CB3285442
Molecular Formula
C16H9Br
Formula Weight
281.15
MOL File
1714-29-0.mol
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1-Bromopyrene Property

Melting point:
102-105 °C (lit.)
Boiling point:
255 °C / 7mmHg
Density 
1.4316 (rough estimate)
refractive index 
1.6000 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Soluble), DMSO (Slightly, Heated, Sonicated), Methanol (Slightly)
form 
Crystalline
color 
White to Pale Yellow
InChIKey
HYGLETVERPVXOS-UHFFFAOYSA-N
CAS DataBase Reference
1714-29-0(CAS DataBase Reference)
NIST Chemistry Reference
1-Bromopyrene(1714-29-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
391573
Product name
1-Bromopyrene
Purity
96%
Packaging
1g
Price
$66.6
Updated
2024/03/01
TCI Chemical
Product number
B1495
Product name
1-Bromopyrene
Purity
>95.0%(GC)
Packaging
5g
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
B1495
Product name
1-Bromopyrene
Purity
>95.0%(GC)
Packaging
25g
Price
$207
Updated
2024/03/01
Alfa Aesar
Product number
018280
Product name
1-Bromopyrene, 95%
Packaging
1g
Price
$48.65
Updated
2024/03/01
Alfa Aesar
Product number
018280
Product name
1-Bromopyrene, 95%
Packaging
5g
Price
$177
Updated
2024/03/01
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1-Bromopyrene Chemical Properties,Usage,Production

Chemical Properties

White to yellow to light brown powder

Uses

1-Bromopyrene is used in the cleavage of DNA in studies. It is also used in the preparation of DNA base analogs.

Uses

1-Bromopyrene is suitable reagent used in the comparative study of effect of substituents of some pyrene derivatives in inducing phototoxicity, DNA damage and repair in human skin keratinocytes and light-induced lipid peroxidation in methanol. It is suitable reagent used in the study to investigate the UV photon-assisted thermal decomposition of PAHs at elevated temperature.
1-Bromopyrene may be used as a standard to compare its spectral properties with that of pyrene based fluorescence probe. It may be used to study the effects of the addition of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic hydrocarbons.
It may be used in the synthesis of the following:
2-methyl-4-pyren-1-yl-but-3-yn-2-ol
1-ethynylpyrene
silsesquioxane (SSQ) based hybrid
ruthenium nanoparticles functionalized with pyrene moiety
mono- and di-pyrenyl perfluoroalkanes
oligo(1-bromopyrene)(OBrP) films
dinitropyrene-derived DNA adduct

Preparation

1-Bromopyrene is an important intermediate in the OLED material industry. The synthesis method is as follows: pyrene is dissolved in an organic solvent dichloromethane, and dibromohydantoin is added for reaction, filtered, and the obtained solid is recrystallized to obtain 1-bromopyrene.

Synthesis Reference(s)

Synthetic Communications, 18, p. 2207, 1988 DOI: 10.1080/00397918808082362
Synthesis of 1-Bromopyrene and 1-Pyrenecarbaldehyde

General Description

1-Bromopyrene, a polycyclic aromatic hydrocarbon (PAH), is a mono bromo substituted pyrene derivative. Its synthesis has been reported. Its gas phase UV-absorption spectra in the UV wavelength range at elevated temperature has been studied. Electron affinitiy (EA) of 1-bromopyrene has been investigated using electron attachment desorption chemical ionization mass spectrometry (DCI-MS) and triple quadrupole tandem mass spectrometry. It participates in the synthesis of novel ruthenium (II) bipyridine or terpyridine complexes bearing pyrene moiety. The reaction of 1-bromopyrene cation radical with water in acetonitrile has been analyzed using the electron transfer stopped-flow (ETSF) method.

1-Bromopyrene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromopyrene Suppliers

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View Lastest Price from 1-Bromopyrene manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
1-Bromopyrene 1714-29-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-05
Hebei Yanxi Chemical Co., Ltd.
Product
1-Bromopyrene 1714-29-0
Price
US $0.00/kg
Min. Order
1kg
Purity
98%?min
Supply Ability
20tons
Release date
2023-09-15
Henan Fengda Chemical Co., Ltd
Product
1-Bromopyrene 1714-29-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26

1714-29-0, 1-BromopyreneRelated Search:


  • 1-BROMOPYRENE
  • Pyrene, 1-bromo-
  • 2-Bromopyrene
  • 1-Pyrenyl bromide
  • 1-Bromopyene
  • 1-Bromopyrene 96%
  • 1-Bromopyrene &gt
  • 1-Bromopyrene, 95%, for synthesis
  • 1-Bromopyrene ISO 9001:2015 REACH
  • DK4994
  • 1714-29-0 1-Bromopyrene
  • Hlddsa(n-dodecylsuccinic anhydride)
  • 1-Bromopyrene in toluene
  • 1714-29-0
  • C16H9Br
  • C13 to C37+
  • Aryl
  • Building Blocks
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • Pyrenes
  • OLED materrials
  • OLED materials,pharm chemical,electronic
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis
  • OLED
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  • Pyrenes
  • Aryl
  • C13 to C37+
  • Halogenated Hydrocarbons
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