(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE
- Product Name
- (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE
- CAS No.
- 45791-36-4
- Chemical Name
- (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE
- Synonyms
- (R)-1-(4-bromophenyl)ethan-1-amine;(R)-1-(4-BROMOPHENYL)ETHANAMINE;(R)-1-(4-BROMOPHENYL)ETHYLAMINE;4-broMo-a-Methyl-;(S)-(-)-1-(4-BromophenyL;(R)-α-Methyl-4-bromobenzylamine;(1R)-1-(4-bromophenyl)ethanamine;(1R)-1-(4-Bromophenyl)ethaneamine;(R)-(+)-1-(4-Bromopheyl)ethylamine;(1R)-1-(4-broMophenyl)ethan-1-aMine
- CBNumber
- CB3314115
- Molecular Formula
- C8H10BrN
- Formula Weight
- 200.08
- MOL File
- 45791-36-4.mol
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Property
- Melting point:
- -25°C
- Boiling point:
- 140-145 °C (30 mmHg)
- alpha
- 20.5 º (C=3% IN MEOH)
- Density
- 1.390 g/mL at 20 °C (lit.)
- refractive index
- n20/D 1.566
- Flash point:
- >110°C
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- pka
- 8.82±0.10(Predicted)
- form
- clear liquid
- color
- Colorless to Almost colorless
- optical activity
- [α]20/D +20.5±1°, c = 3% in methanol
- Sensitive
- Air Sensitive
- BRN
- 2412319
- CAS DataBase Reference
- 45791-36-4(CAS DataBase Reference)
- NIST Chemistry Reference
- (+)-P-bromo-«alpha»-phenethylamine(45791-36-4)
Safety
- Hazard Codes
- C,N
- Risk Statements
- 34-51/53-22
- Safety Statements
- 26-28-36/37/39-45-61
- RIDADR
- UN 2735 8/PG 3
- WGK Germany
- 3
- F
- 10-23
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29214990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B3672
- Product name
- (R)-(+)-1-(4-Bromophenyl)ethylamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $54
- Updated
- 2025/07/31
- Product number
- B3672
- Product name
- (R)-(+)-1-(4-Bromophenyl)ethylamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $272
- Updated
- 2025/07/31
- Product number
- B807998
- Product name
- (R)-(+)-1-(4-Bromophenyl)ethylamine
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- AK-35249
- Product name
- (R)-1-(4-Bromophenyl)ethylamine
- Purity
- 98%
- Packaging
- 1g
- Price
- $5
- Updated
- 2021/12/16
- Product number
- 37528
- Product name
- (R)-(+)-1-(4-Bromophenyl)ethylamine,98%(GC)(T)
- Purity
- 98%(GC)(T)
- Packaging
- 1G
- Price
- $54.88
- Updated
- 2021/12/16
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Synthesis
24358-62-1
24358-62-1
General procedure for the synthesis of 1-(4-bromophenyl)ethylamine from 1-(4-bromophenyl)ethylamine: 600 g of R-mandelic acid is added to a mixture of 2900 ml of isopropanol and 1500 ml of ethanol and heated to 60°C to dissolve completely. Subsequently 790 g of 4-bromophenethylamine is slowly added (note the exothermic reaction). After the reaction solution cooled naturally to room temperature, it was allowed to stand overnight with continuous stirring during the period. The solid product was collected by filtration and dried to give 660 g of crystals. The resulting crystals were dissolved in a mixture of 2000 ml of isopropanol and 1100 ml of ethanol, heated to 60°C to dissolve the crystals completely, and then cooled to room temperature. After standing overnight, the reaction mixture was stirred, the solid product was collected by filtration and washed with a small amount of acetone and dried to give 510 g of crystals. It was neutralized to basicity with 4M sodium hydroxide solution and subsequently extracted three times with dichloromethane. The organic phases were combined, dried and concentrated to give a final 260.7 g of colorless liquid product in 33% yield.
References
[1] Patent: CN106957255, 2017, A. Location in patent: Paragraph 0059-0061; 0073-0075; 0087-0089
[2] Chemical Communications, 2013, vol. 49, # 77, p. 8629 - 8631
[3] ChemCatChem, 2014, vol. 6, # 4, p. 992 - 995
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE manufacturers
- Product
- (R)-(+)-1-(4-Bromophenyl)Ethylamine 45791-36-4
- Price
- US $1.10-9.90/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 100kg
- Release date
- 2025-08-18
- Product
- (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE 45791-36-4
- Price
- US $0.00-0.00/kg
- Min. Order
- 0.10000000149011612kg
- Purity
- 99.0%min
- Supply Ability
- 200kg
- Release date
- 2023-06-12
- Product
- (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE 45791-36-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-09