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(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE

Product Name
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE
CAS No.
45791-36-4
Chemical Name
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE
Synonyms
(R)-1-(4-bromophenyl)ethan-1-amine;(R)-1-(4-BROMOPHENYL)ETHANAMINE;(R)-1-(4-BROMOPHENYL)ETHYLAMINE;4-broMo-a-Methyl-;(S)-(-)-1-(4-BromophenyL;(R)-α-Methyl-4-bromobenzylamine;(1R)-1-(4-bromophenyl)ethanamine;(1R)-1-(4-Bromophenyl)ethaneamine;(R)-(+)-1-(4-Bromopheyl)ethylamine;(1R)-1-(4-broMophenyl)ethan-1-aMine
CBNumber
CB3314115
Molecular Formula
C8H10BrN
Formula Weight
200.08
MOL File
45791-36-4.mol
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(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Property

Melting point:
-25°C
Boiling point:
140-145 °C (30 mmHg)
alpha 
20.5 º (C=3% IN MEOH)
Density 
1.390 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.566
Flash point:
>110°C
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
pka
8.82±0.10(Predicted)
form 
clear liquid
color 
Colorless to Almost colorless
optical activity
[α]20/D +20.5±1°, c = 3% in methanol
Sensitive 
Air Sensitive
BRN 
2412319
CAS DataBase Reference
45791-36-4(CAS DataBase Reference)
NIST Chemistry Reference
(+)-P-bromo-«alpha»-phenethylamine(45791-36-4)
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Safety

Hazard Codes 
C,N
Risk Statements 
34-51/53-22
Safety Statements 
26-28-36/37/39-45-61
RIDADR 
UN 2735 8/PG 3
WGK Germany 
3
10-23
HazardClass 
8
PackingGroup 
II
HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3672
Product name
(R)-(+)-1-(4-Bromophenyl)ethylamine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$54
Updated
2025/07/31
TCI Chemical
Product number
B3672
Product name
(R)-(+)-1-(4-Bromophenyl)ethylamine
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$272
Updated
2025/07/31
TRC
Product number
B807998
Product name
(R)-(+)-1-(4-Bromophenyl)ethylamine
Packaging
100mg
Price
$75
Updated
2021/12/16
Ark Pharm
Product number
AK-35249
Product name
(R)-1-(4-Bromophenyl)ethylamine
Purity
98%
Packaging
1g
Price
$5
Updated
2021/12/16
Chem-Impex
Product number
37528
Product name
(R)-(+)-1-(4-Bromophenyl)ethylamine,98%(GC)(T)
Purity
98%(GC)(T)
Packaging
1G
Price
$54.88
Updated
2021/12/16
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(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Synthesis

24358-62-1

24358-62-1

General procedure for the synthesis of 1-(4-bromophenyl)ethylamine from 1-(4-bromophenyl)ethylamine: 600 g of R-mandelic acid is added to a mixture of 2900 ml of isopropanol and 1500 ml of ethanol and heated to 60°C to dissolve completely. Subsequently 790 g of 4-bromophenethylamine is slowly added (note the exothermic reaction). After the reaction solution cooled naturally to room temperature, it was allowed to stand overnight with continuous stirring during the period. The solid product was collected by filtration and dried to give 660 g of crystals. The resulting crystals were dissolved in a mixture of 2000 ml of isopropanol and 1100 ml of ethanol, heated to 60°C to dissolve the crystals completely, and then cooled to room temperature. After standing overnight, the reaction mixture was stirred, the solid product was collected by filtration and washed with a small amount of acetone and dried to give 510 g of crystals. It was neutralized to basicity with 4M sodium hydroxide solution and subsequently extracted three times with dichloromethane. The organic phases were combined, dried and concentrated to give a final 260.7 g of colorless liquid product in 33% yield.

References

[1] Patent: CN106957255, 2017, A. Location in patent: Paragraph 0059-0061; 0073-0075; 0087-0089
[2] Chemical Communications, 2013, vol. 49, # 77, p. 8629 - 8631
[3] ChemCatChem, 2014, vol. 6, # 4, p. 992 - 995

(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE Suppliers

Yunnan Huapai Pharmaceutical Technology Co., Ltd.
Tel
0886-1313565-2018 18662190408
Email
275443226@qq.com
Country
China
ProdList
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Shanghai Yurlic Chemical S&T Co.Ltd.
Tel
021-37285141 15618858630
Fax
021-37285142
Email
yancf@yulibiotech.com
Country
China
ProdList
170
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J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
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China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
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24529
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
Country
China
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
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18207
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JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
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Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
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sales@chemreagents.com
Country
United States
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View Lastest Price from (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(R)-(+)-1-(4-Bromophenyl)Ethylamine 45791-36-4
Price
US $1.10-9.90/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kg
Release date
2025-08-18
Hangzhou ICH Biofarm Co., Ltd
Product
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE 45791-36-4
Price
US $0.00-0.00/kg
Min. Order
0.10000000149011612kg
Purity
99.0%min
Supply Ability
200kg
Release date
2023-06-12
Career Henan Chemical Co
Product
(R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE 45791-36-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-09

45791-36-4, (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINERelated Search:


  • Benzenemethanamine, 4-bromo-α-methyl-, (αR)-
  • (R)-(+)-1-(4-Bromophenyl)ethylamine, ChiPros, 98%, ee 98+%
  • (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE, 95%, 98% EE
  • (R)-(+)-1-(4-Bromophenyl)ethylamine, 98% ee
  • (1R)-1-(4-Bromophenyl)ethaneamine
  • (R)-α-Methyl-4-bromobenzylamine
  • (αR)-α-Methyl-4-bromobenzenemethanamine
  • [R,(+)]-p-Bromo-α-methylbenzenemethanamine
  • Benzenemethanamine, 4-bromo-.alpha.-methyl-, (.alpha.R)-
  • (R)-(+)-1-(4-Bromophenyl)ethylamine ,99% ee, 95%
  • 4-broMo-a-Methyl-
  • (R)-(-)-4-Bromo-alpha-phenylethylamine
  • R-(+)-1-aMino-1-(4-broMophenyl)-ethane
  • (1R)-1-(4-broMophenyl)ethan-1-aMine
  • (R)-(+)-1-(4-Bromophenyl)ethylamine >=96.0% (sum of enantiomers, GC)
  • Benzenemethanamine,4-bromo-a-methyl-, (aR)-
  • Benzenemethanamine, 4-bromo-alpha-methyl-, (R)-
  • R(+)-4-BROMO-ALPHA-METHYLBENZYLAMINE
  • (R)-(+)-4-BROMO A-METHYLBENZYLAMINE
  • (R)-1-(4-BROMOPHENYL)ETHANAMINE
  • (R)-(+)-1-(4-BROMOPHENYL)ETHYLAMINE
  • (R)-1-(4-BROMOPHENYL)ETHYLAMINE
  • (R)-(+)-P-BROMO-ALPHA-METHYLBENZYLAMINE
  • (R)(+)-P-BROMO-ALPHA-PHENETHYLAMINE
  • (R)-(+)-1-(4-Bromopheyl)ethylamine
  • (r)-(+)-1-(4-bromophenyl)ethylamine, chipros
  • (r)-(+)-4-bromo-α-methylbenzylamine
  • (r)-(+)-p-bromo-à-methylbenzylamine
  • (R)-(+)-1-(4-Bromophenyl)ethylamine, ChiPros, 99%, ee 98%
  • (R)-1-(4-bromophenyl)ethan-1-amine
  • (R)-(+)-1-(4-Bromophenyl)ethylamine &gt
  • (S)-(-)-1-(4-BromophenyL
  • (R)-(-)-4-Bromo-α-methylbenzylamine
  • (αR)-4-Bromo-α-methylbenzenemethanamine
  • (1R)-1-(4-bromophenyl)ethanamine
  • (<i>R</i>)-(+)-1-(4-Bromophenyl)ethylamine
  • methyl (S)-3-(1-amino-2-methylpropyl)benzoate
  • (alphaR)-4-Bromo-alpha-methylbenzenemethanamine
  • 45791-36-4
  • Asymmetric Synthesis
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  • Asymmetric Synthesis
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