(R)-1-(3-Bromophenyl)ethylamine

Product Name: (R)-1-(3-Bromophenyl)ethylamine
CAS No.: 176707-77-0
Chemical Name: (R)-1-(3-Bromophenyl)ethylamine
Synonyms: (R)-1-(3-BROMOPHENYL)ETHANAMINE;(R)-1-(3-bromophenyl)ethan-1-amine;Albb-005066;?-1-(3-Bromophenyl)ethanamine;(R)-3-Bromo-α-methylbenzylamine;(R)-1-(3-BROMOPHENYL)ETHYLAMINE;[(1R)-1-(3-Bromophenyl)ethyl]amine;(R)-(+)-3-BROMO A-METHYLBENZYLAMINE;(R)-3-BROMO-ALPHA-METHYLBENZYLAMINE;(1R)-1-(3-bromophenyl)ethan-1-amine
CBNumber: CB8302375
Molecular Formula: C8H10BrN
Formula Weight: 200.08
MOL File: 176707-77-0.mol

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(R)-1-(3-Bromophenyl)ethylamine Property

Boiling point:: 96°C/4mm
Density: 1.33
Flash point:: 96°C/4mm
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 8.73±0.10(Predicted)
Appearance: Colorless to light yellow Liquid
optical activity: Consistent with structure
Sensitive: Air Sensitive

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Safety

Hazard Codes: C,N
Risk Statements: 34-51/53-43-22
Safety Statements: 26-36/37/39-61-45
RIDADR: 2735
HazardClass: 8
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H318Causes serious eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

AK Scientific

Product number: 9266AA
Product name: (R)-1-(3-Bromophenyl)ethanamine
Packaging: 100mg
Price: $65
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB116420
Product name: 1-(3-Bromophenyl)ethanamine
Packaging: 250mg
Price: $85
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB116420
Product name: 1-(3-Bromophenyl)ethanamine
Packaging: 500mg
Price: $150
Updated: 2021/12/16

Matrix Scientific

Product number: 167633
Product name: (R)-1-(3-Bromophenyl)ethanamine
Packaging: 1g
Price: $166
Updated: 2021/12/16

Matrix Scientific

Product number: 036917
Product name: 1-(3-Bromophenyl)ethanamine
Packaging: 500mg
Price: $252
Updated: 2021/12/16

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(R)-1-(3-Bromophenyl)ethylamine Chemical Properties,Usage,Production

Synthesis

24280-05-5

176707-77-0

The general procedure for the synthesis of (R)-1-(3-bromophenyl)ethylamine from 1-(3-bromophenyl)ethanone oxime is as follows: 1 equiv. of N-[1-(3-bromophenyl)ethylidene]hydroxylamine, 5 mol% of RuCl(Cymene)(S-tol-Binap)Cl catalyst, 5 equiv. of additives, and 70 vol. of methanol (relative to the amount of the oxime) are added to a glass vial. The glass vials were placed in a parallel autoclave, which was pressurized to 30 bar with hydrogen, then heated to 90 °C and kept for 24 hours. After completion of the reaction, the system was cooled to 20 °C. The reaction mixture was diluted with isopropyl alcohol. The reaction mixture was diluted with isopropanol and analyzed by chiral HPLC.

References

[1] Patent: WO2015/178847, 2015, A1. Location in patent: Page/Page column 7-8

(R)-1-(3-Bromophenyl)ethylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-1-(3-Bromophenyl)ethylamine Suppliers

China 73 France 1 Germany 3 India 2 United Kingdom 1 United States 15 Global 95

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176707-77-0, (R)-1-(3-Bromophenyl)ethylamineRelated Search:

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176707-77-0

API intermediates