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Methyl 2-methyl-3-nitrobenzoate

Product Name
Methyl 2-methyl-3-nitrobenzoate
CAS No.
59382-59-1
Chemical Name
Methyl 2-methyl-3-nitrobenzoate
Synonyms
DK835;Methyl 2-methyl-3-;Lenalidoide Ipurity 23;METHYL 3-NITRO-O-TOLUATE;2-Methyl-3-nitrobenzoate;METHYL 2-METHYL-3-NITROBENZOATE;Methyl 3-nitro-2-methylbenzoate;Methyl 2-Methyl-3-Nitro-Benzoatee;Methyl2-Methyl-3-nitrobenzoate>3-NITRO-0-TOLUIC ACID METHYL ESTER
CBNumber
CB3328974
Molecular Formula
C9H9NO4
Formula Weight
195.17
MOL File
59382-59-1.mol
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Methyl 2-methyl-3-nitrobenzoate Property

Melting point:
62-65 °C (lit.)
Boiling point:
286.6±20.0 °C(Predicted)
Density 
1?+-.0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in methanol.
form 
Solid
color 
Pale Beige
BRN 
1964020
CAS DataBase Reference
59382-59-1(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
366765
Product name
Methyl 2-methyl-3-nitrobenzoate
Purity
97%
Packaging
25g
Price
$71.8
Updated
2024/03/01
TCI Chemical
Product number
M2144
Product name
Methyl 2-Methyl-3-nitrobenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$21
Updated
2024/03/01
TCI Chemical
Product number
M2144
Product name
Methyl 2-Methyl-3-nitrobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$42
Updated
2024/03/01
Alfa Aesar
Product number
H60242
Product name
Methyl 2-methyl-3-nitrobenzoate, 97%
Packaging
5g
Price
$34.65
Updated
2024/03/01
Alfa Aesar
Product number
H60242
Product name
Methyl 2-methyl-3-nitrobenzoate, 97%
Packaging
25g
Price
$129.65
Updated
2024/03/01
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Methyl 2-methyl-3-nitrobenzoate Chemical Properties,Usage,Production

Description

Methyl 2-methyl-3-nitrobenzoate is an important organic synthetic material and pharmaceutical intermediate compound. It can be used for the preparation of the anticancer drug lenalidomide as well as other organic compounds (e.g., indole-4-carboxylic acid methyl ester, 5-nitroisocoumarin, 5-aminoisoquinolin-1(2H)-one, etc.).

Chemical Properties

White crystalline powder

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of methyl indole-4-carboxylate, 5-aminoisoquinolin-1(2H)-one, 5-nitroisocoumarin and [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone. It may also be used in the preparation of substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO; and 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis.

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of:

  • methyl indole-4-carboxylate
  • 5-aminoisoquinolin-1(2H)-one
  • 5-nitroisocoumarin
  • substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO
  • 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis
  • [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone

Solubility in organics

Soluble in methanol.

Methyl 2-methyl-3-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-methyl-3-nitrobenzoate Suppliers

Fuxin Kaituo Fine Chemical Technology Co., Ltd
Tel
15714082442
Email
3757845877@qq.com
Country
China
ProdList
346
Advantage
58
Jiangxi taisinor Co., Ltd.
Tel
13576915071
Email
taisinor@vip.163.com
Country
China
ProdList
27
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
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View Lastest Price from Methyl 2-methyl-3-nitrobenzoate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
99%min
Supply Ability
500kg
Release date
2021-10-22
Asia Chem I and E (Jiangsu) Co Ltd
Product
Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price
US $67.81/Kg/Drum
Min. Order
5KG
Purity
99.0%min
Supply Ability
5tons/momth
Release date
2022-01-11
Career Henan Chemical Co
Product
Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98-100%
Supply Ability
100KG
Release date
2018-08-20

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