Methyl 2-methyl-3-nitrobenzoate

Product Name: Methyl 2-methyl-3-nitrobenzoate
CAS No.: 59382-59-1
Chemical Name: Methyl 2-methyl-3-nitrobenzoate
Synonyms: DK835;Methyl 2-methyl-3-;Lenalidoide Ipurity 23;METHYL 3-NITRO-O-TOLUATE;2-Methyl-3-nitrobenzoate;METHYL 2-METHYL-3-NITROBENZOATE;Methyl 3-nitro-2-methylbenzoate;Methyl 2-Methyl-3-Nitro-Benzoatee;Methyl2-Methyl-3-nitrobenzoate>3-NITRO-0-TOLUIC ACID METHYL ESTER
CBNumber: CB3328974
Molecular Formula: C9H9NO4
Formula Weight: 195.17
MOL File: 59382-59-1.mol

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Methyl 2-methyl-3-nitrobenzoate Property

Melting point:: 62-65 °C (lit.)
Boiling point:: 286.6±20.0 °C(Predicted)
Density: 1?+-.0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: Soluble in methanol.
form: Solid
color: Pale Beige
BRN: 1964020
CAS DataBase Reference: 59382-59-1(CAS DataBase Reference)

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Safety

Safety Statements: 24/25
WGK Germany: 3
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 366765
Product name: Methyl 2-methyl-3-nitrobenzoate
Purity: 97%
Packaging: 25g
Price: $71.8
Updated: 2024/03/01

TCI Chemical

Product number: M2144
Product name: Methyl 2-Methyl-3-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $21
Updated: 2024/03/01

TCI Chemical

Product number: M2144
Product name: Methyl 2-Methyl-3-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $42
Updated: 2024/03/01

Alfa Aesar

Product number: H60242
Product name: Methyl 2-methyl-3-nitrobenzoate, 97%
Packaging: 5g
Price: $34.65
Updated: 2024/03/01

Alfa Aesar

Product number: H60242
Product name: Methyl 2-methyl-3-nitrobenzoate, 97%
Packaging: 25g
Price: $129.65
Updated: 2024/03/01

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Methyl 2-methyl-3-nitrobenzoate Chemical Properties,Usage,Production

Description

Methyl 2-methyl-3-nitrobenzoate is an important organic synthetic material and pharmaceutical intermediate compound. It can be used for the preparation of the anticancer drug lenalidomide as well as other organic compounds (e.g., indole-4-carboxylic acid methyl ester, 5-nitroisocoumarin, 5-aminoisoquinolin-1(2H)-one, etc.).

Chemical Properties

White crystalline powder

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of methyl indole-4-carboxylate, 5-aminoisoquinolin-1(2H)-one, 5-nitroisocoumarin and [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone. It may also be used in the preparation of substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO; and 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis.

Uses

Methyl 2-methyl-3-nitrobenzoate may be used in the synthesis of:

methyl indole-4-carboxylate
5-aminoisoquinolin-1(2H)-one
5-nitroisocoumarin
substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO
4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis
[2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone

Solubility in organics

Soluble in methanol.

Methyl 2-methyl-3-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-methyl-3-nitrobenzoate Suppliers

Americas 1 China 235 Europe 3 Germany 3 India 21 Japan 1 Slovakia 1 Switzerland 3 United Kingdom 9 United States 25 Global 302

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View Lastest Price from Methyl 2-methyl-3-nitrobenzoate manufacturers

Asia Chem I and E (Jiangsu) Co Ltd

Product: Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price: US $67.81/Kg/Drum
Min. Order: 5KG
Purity: 99.0%min
Supply Ability: 5tons/momth
Release date: 2022-01-11

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price: US $0.00-0.00/Kg/Drum
Min. Order: 1KG
Purity: 99%min
Supply Ability: 500kg
Release date: 2021-10-22

Career Henan Chemical Co

Product: Methyl 2-methyl-3-nitrobenzoate 59382-59-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98-100%
Supply Ability: 100KG
Release date: 2018-08-20

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DK835

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CH3C6H3NO2CO2CH3

Building Blocks

Carbonyl Compounds

C8 to C9

Esters

Organic Building Blocks

API intermediates

Aromatic Esters

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NitroCompounds