Triphenylmethanol

Luminescence performance

Product Name: Triphenylmethanol
CAS No.: 76-84-6
Chemical Name: Triphenylmethanol
Synonyms: TRT-OH;TRIPHENYLCARBINOL;TRITYL ALCOHOL;Tritanol;Triphenylmethanol, (Triphenyl carbinol;Ih-Tetrazole;tirphenylmethanol;Triphenylmethanol ,99%;Triphenylmethyl alcohol;Triphenylmethanol(76-84-6)
CBNumber: CB3335936
Molecular Formula: C19H16O
Formula Weight: 260.33
MOL File: 76-84-6.mol

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Triphenylmethanol Property

Melting point:: 160-163 °C (lit.)
Boiling point:: 360 °C (lit.)
Density: d40 1.199
refractive index: 1.6220 (estimate)
Flash point:: 360-380°C
storage temp.: 2-8°C
solubility: dioxane: 0.1 g/mL, clear
pka: 12.73±0.29(Predicted)
form: Fine Crystalline Powder
color: White to light yellow
Water Solubility: INSOLUBLE
Merck: 14,9739
BRN: 1460837
Stability:: Stable. Combustible. Incompatible with oxidizing agents, acids, acid chlorides, acid anhydrides.
CAS DataBase Reference: 76-84-6(CAS DataBase Reference)
NIST Chemistry Reference: Benzenemethanol, «alpha»,«alpha»-diphenyl-(76-84-6)
EPA Substance Registry System: Benzenemethanol, .alpha.,.alpha.-diphenyl- (76-84-6)

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Safety

Hazard Codes: Xi
Risk Statements: 38-36/37/38
Safety Statements: 22-24/25-36-26
WGK Germany: 3
TSCA: Yes
HS Code: 29062900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.21196
Product name: Triphenylmethanol
Purity: for synthesis
Packaging: 50g
Price: $75.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.21196
Product name: Triphenylmethanol
Purity: for synthesis
Packaging: 250g
Price: $201
Updated: 2024/03/01

Sigma-Aldrich

Product number: 134848
Product name: Triphenylmethanol
Purity: 97%
Packaging: 50g
Price: $68.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 134848
Product name: Triphenylmethanol
Purity: 97%
Packaging: 250g
Price: $252
Updated: 2024/03/01

TCI Chemical

Product number: T0516
Product name: Triphenylmethanol
Purity: >99.0%(GC)
Packaging: 25g
Price: $38
Updated: 2024/03/01

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Triphenylmethanol Chemical Properties,Usage,Production

Luminescence performance

Triphenylmethanol (TPOH) is a non-fluorescent compound that emits strong fluorescence in an aggregate state or on a solid surface after irradiation by UV light at 254 nm (UV1). Interestingly, the photo-induced fluorescence of TPOH was quenched when irradiated by UV light at a longer wavelength of 365 nm (UV2) and further repeatable on and off by UV1 and UV2, respectively. The reversible activation and deactivation of fluorescence at a solid surface could be repeatable at least 5 times. TPOH is thus applied for rewritable photopatterning tuned by UV light[1].

Chemical Properties

white powder or colorless trisolated crystals. Soluble in alcohol, ether and benzene, dark yellow when dissolved in concentrated sulfuric acid, colorless when dissolved in glacial acetic acid, insoluble in water and petroleum ether. Distilled at 360-380℃ without decomposition.

Uses

Triphenylmethanol is used as a reagent in the research laboratory. It acts as an intermediate in the production of the commercially useful triarylmethane dyes. It is used in the preparation of triphenylmethane. It is also used as an antiproliferative agent. Further, it is used in the preparation of two-electron reduction product of pyrylogen. In addition to this, it reacts with triphenylphosphine oxide to form a 1:1 molecular complex. It serves as a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes.
Triphenylmethanol was used in the synthesis of of the two-electron reduction product of pyrylogen.
It undergoes reduction to triphenylmethane by 9, 10-dihydro-10-methylacridine in the presence of perchloric acid.

Uses

Triphenylmethanol (Zidovudine EP Impurity D) is a triaryl methane derivative as antiproliferative agent.

Preparation

Triphenylmethanol synthesis: Triphenylmethanol was prepared by the action of benzene with carbon tetrachloride in the presence of Aluminum chloride, followed by acidification and hydrolysis.
Triphenylmethanol can also be prepared by the reaction of phenylmagnesium bromide with methyl benzoate (instead of benzophenone).
Synthesis of Triphenylmethanol

Reactions

The first one is the formation of the triphenylmethyl bromide from the reaction of triphenylmethanol with hydrobromic acid.
The second reaction is the formation of an ether from the reaction of triphenylmethanol with methanol in acidic conditions.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 3, p. 839, 1955
The Journal of Organic Chemistry, 57, p. 4555, 1992 DOI: 10.1021/jo00042a044

General Description

Triphenylmethanol forms 1:1 molecular complex with triphenylphosphine oxide. It is a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes. It undergoes reduction to triphenylmethane by 9, l0-dihydro-10-methylacridine in the presence of perchloric acid.

Purification Methods

Crystallise the carbinol from EtOH, MeOH, CCl4 (4mL/g), *benzene, hexane or pet ether (b 60-70o). Dry it at 90o. [Ohwada et al. J Am Chem Soc 108 3029 1986, Beilstein 6 IV 5014.]

References

[1] Zheng, Yue et al. “Photoactivatable aggregation-induced emission of triphenylmethanol?.” Chemical Communications 81 (2017): 11130–11133.

Triphenylmethanol Preparation Products And Raw materials

Raw materials

Acetyl chloride Carbon tetrachloride Aluminum chloride Benzene

Preparation Products

Fluotrimazol Boc-N-beta-Trityl-L-asparagine Triphenylmethyl bromide

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Triphenylmethanol Suppliers

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View Lastest Price from Triphenylmethanol manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Triphenylmethanol 76-84-6
Price: US $70.00-25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-05

Hebei Weibang Biotechnology Co., Ltd

Product: Triphenylmethanol 76-84-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-21

Hebei Chuanghai Biotechnology Co,.LTD

Product: Triphenylmethanol 76-84-6
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-22

76-84-6, TriphenylmethanolRelated Search:

Trimethyl orthobenzoate TRIPHENYL PHOSPHOROTHIONATE Triphenylsilanol Benzyl alcohol Ethyl acetate Triphenylphosphine oxide Benzhydrol ALPHA-NAPHTHOLBENZEIN Triphenylmethyl Chloride 4-Hydroxybenzyl alcohol TRIPHENYLBORANE 2-Nitrobenzyl alcohol Triphenylphosphine p-Naphtholbenzein 1,2,3-TRIPHENYLGUANIDINE ZIDOVUDINE IMPURITY A ZIDOVUDINE IMPURITY B (3S,3'S,5R,5'R)-3,3'-dihydroxy-.kappa.,.kappa.-carotene-6,6'-dione

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TriphenylMethanol, 97% 50GR

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BL 3756

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Zidovudine impurity I

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Fimasartan Impurity L

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Fimasartan-8

Losartan EP Impurity G: Losartan Impurity G

Enalapril impurity G CRS

Zidovudine impurity D CRS

Triphenylmethanol &gt

TRIPHENYLMETHANOL FOR SYNTHESIS

Benzenemethanol, α,α-diphenyl-

((S)-4-cyclohexyl-1-ethoxy-1-oxobutan-2-yl)-L-alanine

Irbesartan Triphenylmethanol Impurity (Losartan EP Impurity G/ Triphenylmethanol/ Trityl Alcohol/ Candesartan Trityl Alcohol Impurity/ Zidovudine EP Impurity D)