ChemicalBook > CAS DataBase List > 3-BROMO-4-METHOXYTOLUENE

3-BROMO-4-METHOXYTOLUENE

Product Name
3-BROMO-4-METHOXYTOLUENE
CAS No.
22002-45-5
Chemical Name
3-BROMO-4-METHOXYTOLUENE
Synonyms
2-BROMO-4-METHYLANISOLE;m-Bromo-p-methoxytoluene;3-BROMO-4-METHOXYTOLUENE;2-Bromo-4-methylanisole 98%;3-Bromo-4-methoxytoluene 98%;3-Bromo-4-methoxytoluene >1-Bromo-2-methoxy-5-methylbenzene;2-Bromo-4-methyl-1-methoxybenzene;1-Methoxy-2-bromo-4-methylbenzene;2-bromo-1-methoxy-4-methyl-benzen
CBNumber
CB3336201
Molecular Formula
C8H9BrO
Formula Weight
201.06
MOL File
22002-45-5.mol
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3-BROMO-4-METHOXYTOLUENE Property

Melting point:
15.5 °C(lit.)
Boiling point:
124-125 °C20 mm Hg(lit.)
Density 
1.392 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.565(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
Specific Gravity
1.41
color 
Clear, dark yellow to brown
InChI
InChI=1S/C8H9BrO/c1-6-3-4-8(10-2)7(9)5-6/h3-5H,1-2H3
InChIKey
DHPUIKWBNXTXOB-UHFFFAOYSA-N
SMILES
C1(OC)=CC=C(C)C=C1Br
CAS DataBase Reference
22002-45-5(CAS DataBase Reference)
EPA Substance Registry System
2-Bromo-4-methylanisole (22002-45-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
TSCA 
TSCA listed
HazardClass 
IRRITANT
HS Code 
2909309090
Storage Class
10 - Combustible liquids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
480835
Product name
2-Bromo-4-methylanisole
Purity
97%
Packaging
10g
Price
$76.3
Updated
2025/07/31
TCI Chemical
Product number
B3032
Product name
3-Bromo-4-methoxytoluene
Purity
>98.0%(GC)
Packaging
5g
Price
$52
Updated
2025/07/31
TRC
Product number
B696958
Product name
2-Bromo-4-methylanisole
Packaging
500mg
Price
$45
Updated
2021/12/16
Apolloscientific
Product number
OR3050
Product name
2-Bromo-4-methylanisole
Purity
98%
Packaging
10g
Price
$27
Updated
2021/12/16
SynQuest Laboratories
Product number
2707-9-Y5
Product name
2-Bromo-4-methylanisole
Purity
98%
Packaging
10g
Price
$29
Updated
2021/12/16
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3-BROMO-4-METHOXYTOLUENE Chemical Properties,Usage,Production

Chemical Properties

Clear colourless to light yellow liquid

Uses

2-Bromo-4-methylanisole may be used in the synthesis of:

  • 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
  • 1,8-dimethoxy-4-methylanthra-quinone
  • ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.

Synthesis Reference(s)

Synthetic Communications, 23, p. 779, 1993 DOI: 10.1080/00397919308009839

General Description

2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).

3-BROMO-4-METHOXYTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-METHOXYTOLUENE Suppliers

Shanghai Jiuju Chemical Technology Co. LTD
Tel
021-54290889 18117093889
Email
1261932215@qq.com
Country
China
ProdList
399
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58
Shaanxi Renheng Yide Biotechnology Co., Ltd
Tel
15319940549 15319940549
Email
241757027@qq.com
Country
China
ProdList
128
Advantage
58
Shanghai Enong Biotechnology Co., LTD
Tel
+86-15821616017
Email
SARA@AGRIGE.COM
Country
China
ProdList
88
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
11777
Advantage
60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
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View Lastest Price from 3-BROMO-4-METHOXYTOLUENE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
3-BROMO-4-METHOXYTOLUENE 22002-45-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
97.0%
Supply Ability
10000KGS
Release date
2025-05-12
Career Henan Chemical Co
Product
3-BROMO-4-METHOXYTOLUENE 22002-45-5
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-30

22002-45-5, 3-BROMO-4-METHOXYTOLUENERelated Search:


  • 3-BROMO-4-METHOXYTOLUENE
  • 2-BROMO-4-METHYLANISOLE
  • 2-bromo-1-methoxy-4-methyl-benzen
  • Benzene, 2-bromo-1-methoxy-4-methyl-
  • 3-Bromo-4-methoxytoluene 98%
  • 1-Methoxy-2-bromo-4-methylbenzene
  • 2-Bromo-4-methyl-1-methoxybenzene
  • Methyl(2-bromo-4-methylphenyl) ether
  • 3-Bromo-4-methoxytoluene, 2-Bromo-1-methoxy-4-methylbenzene
  • 1-Bromo-2-methoxy-5-methylbenzene
  • m-Bromo-p-methoxytoluene
  • 2-Bromo-4-methylanisole 98%
  • 3-Bromo-4-methoxytoluene &gt
  • 3-BROMO-4-METHOXYTOLUENE ISO 9001:2015 REACH
  • 22002-45-5
  • BrCH3C6H3OCH3
  • Ethers
  • Oxygen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Anisole