4-BROMO-2-METHYLANISOLE
- Product Name
- 4-BROMO-2-METHYLANISOLE
- CAS No.
- 14804-31-0
- Chemical Name
- 4-BROMO-2-METHYLANISOLE
- Synonyms
- Bromomethoxytoluene;Methyl-4-bromoanisole;2-METHYL-4-BROMOANISOLE;4-BROMO-2-METHYLANISOLE;5-BROMO-2-METHOXYTOLUENE;2-Methoxy-5-bromotoluene;4-Allyloxy BroMo Benzene;4-BROMO-2-METHYLANISOLE 98%;5-Bromo-2-methoxytoluene >5-BROMO-2-METHOXYTOLUENE 98+%
- CBNumber
- CB5672408
- Molecular Formula
- C8H9BrO
- Formula Weight
- 201.06
- MOL File
- 14804-31-0.mol
4-BROMO-2-METHYLANISOLE Property
- Melting point:
- 66-69 °C(lit.)
- Boiling point:
- 124-125°C 25mm
- Density
- 1.378±0.06 g/cm3 (20 ºC 760 Torr)
- Flash point:
- 124-125°C/25mm
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Light yellow
- BRN
- 208224
- CAS DataBase Reference
- 14804-31-0(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- 523054
- Product name
- 4-Bromo-2-methylanisole
- Purity
- 98%
- Packaging
- 25g
- Price
- $109
- Updated
- 2025/07/31
- Product number
- B1910
- Product name
- 5-Bromo-2-methoxytoluene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $52
- Updated
- 2025/07/31
- Product number
- B1910
- Product name
- 5-Bromo-2-methoxytoluene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $204
- Updated
- 2025/07/31
- Product number
- B696965
- Product name
- 4-Bromo-2-methylanisole
- Packaging
- 1g
- Price
- $55
- Updated
- 2021/12/16
- Product number
- B696965
- Product name
- 4-Bromo-2-methylanisole
- Packaging
- 2.5g
- Price
- $65
- Updated
- 2021/12/16
4-BROMO-2-METHYLANISOLE Chemical Properties,Usage,Production
Chemical Properties
colorless to light yellow liquid
Uses
4-Bromo-2-methylanisole may be used in the synthesis of 4-isopropyl-2-methylphenol and 4-methoxy-3-methylphenol.
General Description
4-Bromo-2-methylanisole can be prepared by the bromination of o-methylanisole (2-methylanisole). It can also be prepared via reaction between 1-butyl-3-methylimidazolium tribromide [(Bmim)Br3] and an activated aromatic compound. It participates as a substrate for the a-arylation of sulphonamide in a study.
Synthesis
578-58-5
14804-31-0
General procedure for the synthesis of 2-methyl-4-bromoanisole from 2-methylanisole: In a dry 45 mL reaction tube equipped with a magnetic stirrer (note: air was not removed from the reaction tube), 1 mL of [Bmim]NO3, 0.5 mmol of 2-methylanisole and 0.25 mmol of Br2 were added. The reaction tube was then sealed and the reaction was carried out at 80 °C for 24 hours. Upon completion of the reaction, the mixture was cooled to room temperature and the reaction was terminated by the addition of 3 mL of water. The target product 2-methyl-4-bromoanisole was extracted with dichloromethane (3 x 10 mL). The reaction mixture was analyzed by gas chromatography (GC) to determine the GC yield of the product. In another parallel experiment, the product was purified by column chromatography and structurally characterized using 1H NMR and 13C NMR.
References
[1] Helvetica Chimica Acta, 1983, vol. 66, # 4, p. 1068 - 1077
[2] Helvetica Chimica Acta, 1983, vol. 66, # 4, p. 1068 - 1077
[3] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[4] Chemistry - A European Journal, 2015, vol. 21, # 34, p. 11976 - 11979
[5] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999, vol. 38, # 5, p. 603 - 604
4-BROMO-2-METHYLANISOLE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-BROMO-2-METHYLANISOLE manufacturers
- Product
- 4-BROMO-2-METHYLANISOLE 14804-31-0
- Price
- US $1.00/EA
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- G/KG/T
- Release date
- 2019-12-23