4-Bromo-3-methylphenol

Product Name: 4-Bromo-3-methylphenol
CAS No.: 14472-14-1
Chemical Name: 4-Bromo-3-methylphenol
Synonyms: AURORA 4271;4-BROMO-M-CRESOL;AKOS BBS-00008110;4-BROMO-3-METHYLPHENOL;Phenol, 4-bromo-3-methyl-;4-Bromo-3-methylphenol >4-Bromo-3-methylphenol,98%;4-BroMo-3-Methylphenol 98%;4-BROMO-3-METHYLPHENOLBRO7H7C;4-Bromo-3-methylphenol,4-Bromo-m-cresol
CBNumber: CB5289888
Molecular Formula: C7H7BrO
Formula Weight: 187.03
MOL File: 14472-14-1.mol

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4-Bromo-3-methylphenol Property

Melting point:: 59-61 °C (lit.)
Boiling point:: 142-145 °C/23 mmHg (lit.)
Density: 1.3839 (rough estimate)
refractive index: 1.5772 (estimate)
Flash point:: 142-145°C/23mm
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Methanol
form: Crystalline Powder or Chunks
pka: 9.51±0.18(Predicted)
color: White to off-white
BRN: 1859122
InChI: InChI=1S/C7H7BrO/c1-5-4-6(9)2-3-7(5)8/h2-4,9H,1H3
InChIKey: GPOQODYGMUTOQL-UHFFFAOYSA-N
SMILES: C1(O)=CC=C(Br)C(C)=C1
CAS DataBase Reference: 14472-14-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
HazardClass: IRRITANT
PackingGroup: III
HS Code: 29081990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 440884
Product name: 4-Bromo-3-methylphenol
Purity: 98%
Packaging: 5g
Price: $135
Updated: 2023/06/20

TCI Chemical

Product number: B3658
Product name: 4-Bromo-3-methylphenol
Purity: >98.0%(GC)
Packaging: 5g
Price: $46
Updated: 2025/07/31

TCI Chemical

Product number: B3658
Product name: 4-Bromo-3-methylphenol
Purity: >98.0%(GC)
Packaging: 25g
Price: $183
Updated: 2025/07/31

TRC

Product number: B687515
Product name: 4-Bromo-3-methylphenol
Packaging: 25g
Price: $250
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK346568
Product name: 4-Bromo-3-methylphenol
Purity: 98%
Packaging: 25g
Price: $283
Updated: 2021/12/16

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4-Bromo-3-methylphenol Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder or chunks

Uses

4-Bromo-3-methylphenol may be used in the synthesis of bromo[2-methyl-4-[2-(t-butyldimethylsilyloxy)ethyloxy]phenyl]bis(triphenylphopshine)nickel(II) (protected alcohol-functionalized initiator) and bromo-[2-methyl-4-[6-(t-butyldimethylsilyloxy)hexyloxy]phenyl] bis(triphenylphosphine) nickel.

General Description

4-Bromo-3-methylphenol is a brominated phenol. It participates in the total synthesis of 3-methylcalix[4]arene.

Synthesis

108-39-4

14472-14-1

General procedure for the synthesis of 4-bromo-3-methylphenol from m-cresol: (a) Preparation of 4-bromo-3-methylphenol: 80.0 g (740 mmol) of m-cresol and 400 mL of glacial acetic acid were added to a 2 L three-neck flask under nitrogen protection. The reaction mixture was cooled to 15 °C, 38 mL (742 mmol) of bromine was added slowly dropwise, and the reaction was stirred for 3 h at 15 °C maintaining the temperature. After completion of the reaction, the reaction solution was poured into 1 L of water and extracted with ether. The organic phase was separated and washed with water to neutral pH and subsequently dried with magnesium sulfate. The solvent was removed by evaporation under reduced pressure and the resulting residue was ground in heptane, filtered and dried to give 70 g (50% yield) of a white powdery product with a melting point of 55-56 °C.

References

[1] Letters in Organic Chemistry, 2018, vol. 15, # 8, p. 682 - 687
[2] Bulletin of the Chemical Society of Japan, 1987, vol. 60, # 11, p. 4187 - 4189
[3] Journal of Organic Chemistry, 2005, vol. 70, # 11, p. 4267 - 4271
[4] Synlett, 2011, # 15, p. 2265 - 2269
[5] Journal of Chemical Research - Part S, 2003, # 9, p. 597 - 598

4-Bromo-3-methylphenol Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-3-methylphenol Suppliers

Americas 1 Austria 1 Belgium 1 China 231 Europe 2 Germany 3 India 22 Japan 3 Switzerland 2 United Kingdom 14 United States 35 Global 315

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View Lastest Price from 4-Bromo-3-methylphenol manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 4-Bromo-3-methylphenol 14472-14-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-17

Honest Joy Holdings Limited

Product: 4-Bromo-3-methylphenol 14472-14-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100 tons
Release date: 2022-01-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-Bromo-3-methylphenol 14472-14-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

14472-14-1, 4-Bromo-3-methylphenolRelated Search:

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4-BROMO-3-METHYLPHENOL

4-BROMO-M-CRESOL

AKOS BBS-00008110

AURORA 4271

4-BROMO-3-METHYLPHENOLBRO7H7C

Phenol, 4-bromo-3-methyl-

4-Bromo-3-methylphenol,4-Bromo-m-cresol

4-BroMo-3-Methylphenol 98%

2-Bromo-5-hydroxytoluene, 4-Bromo-m-cresol

4-Bromo-3-methylphenol,98%

4-Bromo-3-methylphenol &gt

TIANFUCHEM--14472-14-1--4-Bromo-3-methylphenol

14472-14-1

BrC6H3CH3OH

Oxygen Compounds

Phenols

Organic Building Blocks

Building Blocks

Phenyls & Phenyl-Het

Aromatic Phenols

Benzene series

Phenyls & Phenyl-Het

Phenol&Thiophenol&Mercaptan