ChemicalBook > CAS DataBase List > 3-BROMO-4-METHOXYTOLUENE

3-BROMO-4-METHOXYTOLUENE

Product Name
3-BROMO-4-METHOXYTOLUENE
CAS No.
22002-45-5
Chemical Name
3-BROMO-4-METHOXYTOLUENE
Synonyms
2-BROMO-4-METHYLANISOLE;m-Bromo-p-methoxytoluene;3-BROMO-4-METHOXYTOLUENE;2-Bromo-4-methylanisole 98%;3-Bromo-4-methoxytoluene 98%;3-Bromo-4-methoxytoluene >1-Bromo-2-methoxy-5-methylbenzene;2-Bromo-4-methyl-1-methoxybenzene;1-Methoxy-2-bromo-4-methylbenzene;2-bromo-1-methoxy-4-methyl-benzen
CBNumber
CB3336201
Molecular Formula
C8H9BrO
Formula Weight
201.06
MOL File
22002-45-5.mol
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3-BROMO-4-METHOXYTOLUENE Property

Melting point:
15.5 °C(lit.)
Boiling point:
124-125 °C20 mm Hg(lit.)
Density 
1.392 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.565(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
color 
Clear, dark yellow to brown
Specific Gravity
1.41
CAS DataBase Reference
22002-45-5(CAS DataBase Reference)
EPA Substance Registry System
2-Bromo-4-methylanisole (22002-45-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2909309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
480835
Product name
2-Bromo-4-methylanisole
Purity
97%
Packaging
10g
Price
$88.9
Updated
2024/03/01
TCI Chemical
Product number
B3032
Product name
3-Bromo-4-methoxytoluene
Purity
>98.0%(GC)
Packaging
5g
Price
$52
Updated
2024/03/01
TRC
Product number
B696958
Product name
2-Bromo-4-methylanisole
Packaging
500mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
2707-9-Y5
Product name
2-Bromo-4-methylanisole
Purity
98%
Packaging
50g
Price
$88
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB15453
Product name
2-Bromo-4-methylanisole
Packaging
250g
Price
$630
Updated
2021/12/16
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3-BROMO-4-METHOXYTOLUENE Chemical Properties,Usage,Production

Chemical Properties

Clear colourless to light yellow liquid

Uses

2-Bromo-4-methylanisole may be used in the synthesis of:

  • 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
  • 1,8-dimethoxy-4-methylanthra-quinone
  • ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.

Synthesis Reference(s)

Synthetic Communications, 23, p. 779, 1993 DOI: 10.1080/00397919308009839

General Description

2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).

3-BROMO-4-METHOXYTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-METHOXYTOLUENE Suppliers

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View Lastest Price from 3-BROMO-4-METHOXYTOLUENE manufacturers

Career Henan Chemical Co
Product
3-BROMO-4-METHOXYTOLUENE 22002-45-5
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-30

22002-45-5, 3-BROMO-4-METHOXYTOLUENERelated Search:

3-Bromo-4-methoxybenzaldehyde 3-BROMO-4-METHOXYPHENYLACETONITRILE 3-BROMO-4-METHOXYTOLUENE 4,4'-Isopropylidenebis[2-(2,6-dibromophenoxy)ethanol] Bromoxynil octanoate 3-BROMO-4-METHOXYBENZOIC ACID Tetrabromobisphenol A bis(dibromopropyl ether) 3-BROMO-4-METHOXYPHENYLACETIC ACID BROMOXYNIL-METHYL ETHER 5-BROMO-2-METHOXYTOLUENE 98+%,5-BROMO-2-METHOXYTOLUENE 1-Bromo-3-methoxy-5-methylbenzene 3-bromo-5-methoxytoluene,3-BROMO-5-METHOXYTOLUENE 2-BROMO-5-METHOXYTOLUENE,2-Bromo-5-methoxytoluene 98%,2-Bromo-5-methoxytoluene (4-bromo-3-methylanisole) 5-BROMO-2,4-DIMETHOXYBENZALDEHYDE BOC-3,5-DIBROMO-TYR(OBZL)-OH 3,5-DIBROMO-4-METHOXYBENZOIC ACID EOSIN DIACETATE 5-BROMOVERATRALDEHYDE 4-BROMO-2-METHOXYTOLUENE

  • 3-BROMO-4-METHOXYTOLUENE
  • 2-BROMO-4-METHYLANISOLE
  • 2-bromo-1-methoxy-4-methyl-benzen
  • Benzene, 2-bromo-1-methoxy-4-methyl-
  • 3-Bromo-4-methoxytoluene 98%
  • 1-Methoxy-2-bromo-4-methylbenzene
  • 2-Bromo-4-methyl-1-methoxybenzene
  • Methyl(2-bromo-4-methylphenyl) ether
  • 3-Bromo-4-methoxytoluene, 2-Bromo-1-methoxy-4-methylbenzene
  • 1-Bromo-2-methoxy-5-methylbenzene
  • m-Bromo-p-methoxytoluene
  • 2-Bromo-4-methylanisole 98%
  • 3-Bromo-4-methoxytoluene &gt
  • 3-BROMO-4-METHOXYTOLUENE ISO 9001：2015 REACH
  • 22002-45-5
  • BrCH3C6H3OCH3
  • Ethers
  • Oxygen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Anisole